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Volumn 53, Issue 2, 2014, Pages 370-374

Dative bonds in main-group compounds: A case for fewer arrows!

Author keywords

coordinative bonds; covalent bonds; dative bonds; p block coordination compounds

Indexed keywords

ELECTRONIC STRUCTURE;

EID: 84891775244     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201300461     Document Type: Review
Times cited : (200)

References (67)
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    • [8] (weak, long bond with little charge transfer) are listed. In contrast, in the entry on coordinate bonds it is noted that the synomous term dative bond is obsolete. It is noted that it is irrelevant whether the bonding electrons of the CCl bond in chloromethane are formally represented by two radicals or as arising from a methyl cation and a chloride anion. We think it is sensible to separate the terms and their notation.
    • [8] (weak, long bond with little charge transfer) are listed. In contrast, in the entry on coordinate bonds it is noted that the synomous term dative bond is obsolete. It is noted that it is irrelevant whether the bonding electrons of the CCl bond in chloromethane are formally represented by two radicals or as arising from a methyl cation and a chloride anion. We think it is sensible to separate the terms and their notation.
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    • 3 with a penta- and a tetracoordinate P atom: CCDC854540 (J. Gelhaar, C. Knapp, H. Scherer, R. Uzun) contains the supplementary crystallographic data, which can be obtained free of charge from The Cambridge Crystallographic Data Centre
    • 3 with a penta- and a tetracoordinate P atom: CCDC854540 (J. Gelhaar, C. Knapp, H. Scherer, R. Uzun) contains the supplementary crystallographic data, which can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/ cif.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.