Diphenylprolinol silyl ether catalyzed asymmetric Michael reaction of nitroalkanes and β,β-disubstituted α,β-unsaturated aldehydes for the construction of all-carbon quaternary stereogenic centers

Chemistry - A European Journal

Volumn 20, Issue 38, 2014, Pages 12072-12082

  Hayashi, Yujiro ^a   Kawamoto, Yuya ^a   Honda, Masaki ^a   Okamura, Daichi ^a   Umemiya, Shigenobu ^a   Noguchi, Yuka ^a   Mukaiyama, Takasuke ^a   Sato, Itaru ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

asymmetric synthesis; enantioselectivity; isomerization; Michael addition; organocatalysis

Indexed keywords

ADDITION REACTIONS; ALDEHYDES; CARBON; CATALYSIS; ETHERS; ISOMERIZATION; ISOMERS; NITROGEN REMOVAL; PARAFFINS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ASYMMETRIC SYNTHESIS; MICHAEL ADDITIONS; ORGANOCATALYSIS; REACTION MECHANISM; RETRO-MICHAEL REACTION; STEREOGENIC CENTERS; SYNTHETIC EQUIVALENTS; UNSATURATED ALDEHYDES;

ENANTIOSELECTIVITY;

EID: 84912563672     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201403588     Document Type: Article

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