Zn2+ doped ormosil–phosphotungstate hybrid films with enhanced photochromic response

Journal of Sol-Gel Science and Technology

Volumn 72, Issue 2, 2014, Pages 290-300

  Ferreira Neto, Elias Paiva ^a   Ullah, Sajjad ^a   Ysnaga, Orlando Armando Elguera ^a   Rodrigues Filho, Ubirajara Pereira ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Hybrid materials; Ormosil; Phosphotungstic acid; Photochromism; Zn2+

Indexed keywords

AGGLOMERATION; CHROMOGENICS; DOSIMETERS; FILMS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYBRID MATERIALS; IONS; IRRADIATION; NANOSENSORS; PHOTOCHROMISM; SOLS; SPECTRUM ANALYSIS; ULTRAVIOLET SPECTROSCOPY; X RAY ABSORPTION; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY; ZINC;

ENERGY DISPERSIVE X-RAY; MICRO X-RAY FLUORESCENCE; ORGANIC FUNCTIONALITIES; ORMOSIL; PHOSPHOTUNGSTIC ACID; PHOTO-CHROMIC MATERIALS; POSSIBLE MECHANISMS; X RAY ABSORPTION NEAR EDGE STRUCTURE;

FILM PREPARATION;

EID: 84910133454     PISSN: 09280707     EISSN: 15734846     Source Type: Journal    
DOI: 10.1007/s10971-014-3404-7     Document Type: Article

References (44)

1. Katsoulis DE (1998) A survey of applications of polyoxometalates. Chem Rev 98:359–387
2. Pope MT, Muller A (1991) Polyoxometalate chemistry: an old field with new dimensions in several disciplines. Angew Chem Int Ed 30:34–48
3. Liu S, Tang Z (2010) Polyoxometalate-based functional nanostructured films: current progress and future prospects. Nano Today 5:267–281
4. Sivakumara R, Thomasa J, Yoona M (2012) Polyoxometalate-based molecular/nano composites: advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion. J Phochem Photobiol C: Photochem Rev 13:277–298
5. Papaconstantinou E (1989) Photochemistry of polyoxometallates of molybdenum and tungsten and-or vanadium. Chem Soc Rev 18:1–31
6. Yamase T (1998) Photo- and-electrochromism of polyoxometalates and related materials. Chem Rev 98:307–326
7. Livage J, Sanchez C, Babonneau F (1998) Molecular precursor route to inorganic solids. Chemistry of advanced materials. Wiley-VCH Inc, New York, pp 389–445
8. José NM, De Almeida Prado LAS (2005) Materiais híbridos orgânico-inorgânicos: preparação e algumas aplicações. Quím Nova 28:281–288
9. Benvenutti EV, Moro CC, Costa TMH, Gallas MR (2009) Materiais híbridos à base de sílica obtidos pelo método sol-gel. Quím Nova 32:1926–1933
10. Sanchez C, Belleville P, Popall M, Nicole L (2011) Applications of advanced hybrid organic–inorganic nanomaterials: from laboratory to market. Chem Soc Rev 40:696–753
11. Avnir D (1995) Organic chemistry ceramic matrixes: doped sol–gel materials. Acc Chem Res 28:328–334
12. Pagliaro M (2009) Silica-based materials for advanced applications. RSC Publishing, Cambridge, p 192
13. Pardo R, Zayat M, Levy D (2011) Photochromic organic–inorganic hybrid materials. Chem Soc Rev 40:672–687
14. De Oliveira Jr M, de Souza AL, Schneider J, Rodrigues-Filho UP (2011) Local structure and photochromic response in ormosils containing dodecatungstophosphoric acid. Chem Mater 23:953–963
15. He T, Yao J (2006) Photochromism in composite and hybrid materials based on transition-metal oxides and polyoxometalates. Prog Mater Sci 51:810–879
16. Ferreira-Neto EP, Carvalho FLS, Ullah S et al (2013) Surface structure and reactivity study of phosphotungstic acid-nitrogenated ormosils. J Sol–Gel Sci Technol 66:363–371
17. Mills A, Mcfarlane M, Schneider S (2006) A viologen-based UV indicator and dosimeter. Anal Bioanal Chem 386:299–305
18. Matsumura Y, Ananthaswamy HN (2004) Toxic effects of ultraviolet radiation on the skin. Toxicol Appl Pharmacol 195:298–308
19. Ichihashi M, Ueda M, Budiyanto A, Bito T, Oka M, Fukunaga M, Tsuru K, Horikawa T (2003) UV-induced skin damage. Toxicology 189:21–39
20. Ronto G, Grof P, Gaspar S (1995) Biological UV dosimetry—a comprehensive problem. J Photochem Photobio B: Biol 31(1):51–56
21. Wright CY, Reeder AI (2005) Youth solar ultraviolet radiation exposure, concurrent activities and sun-protective practices: a review. Photochem Photobiol 81(6):1331–1342
22. Webb AR (1995) Measuring UV radiation: a discussion of dosimeter properties, uses and limitations. Photochem Photobio B: Biol 31(1–2):9–13
23. Barth J, Knuschke P (1994) Personal monitoring of UV-radiation. In: Proceedings of SPIE vol 2100 Cell and Biotissue Optics. doi:10.1117/12.179024
24. Etienne P, Denape J, Paris JY, Phalippou J, Sempere R (1996) Tribological properties of ormosil coatings. J Sol–Gel Sci Technol 6:287–297
25. Oliveira HFN, Trinca RB, Gushikem Y (2009) Síntese e estudo de ortossilicatos de zinco luminescentes com aplicação da técnica sol–gel. Quim Nova 32:1346–1349
26. Kalinko A, Kuzmin A (2009) Raman and photoluminescence spectroscopy of zinc tungstate powders. J Lumin 129:1144–1147
27. Donley C, Dunphy D, Paine D, Carter C, Nebesny K, Lee P, Alloway D, Armstring NR (2002) Characterization of indium–tin oxide interfaces using X-ray photoelectron spectroscopy and redox processes of a chemisorbed probe molecule: effect of surface pretreatment conditions. Langmuir 18:450–457
28. Socrates G (2001) Infrared characteristic group frequencies: tables and charts, 3rd edn. Wiley, England, pp 278–323
29. Bridgeman AJ (2003) Density functional study of the vibrational frequencies of alpha Keggin heteropolyanions. Chem Phys 287:55–69
30. Feng W, Ding Y, Liu Y, Lu R (2006) The photochromic process of polyoxometalate-based nanocomposite thin film by in situ AFM and spectroscopy. Mater Chem Phys 98:347–352
31. Carls JC, Argitis P, Helle A (1992) Deep ultraviolet photoresist based on tungsten polyoxometalates and poly(vinyl alcohol) for bilayer photolithography. J Electrochem Soc 139:786–793
32. Smith BJ, Patrick VA (2004) Quantitative determination of aqueous dodecatungstophosphoric acid speciation by NMR spectroscopy. Aust J Chem 57:261–268
33. Lica GC, Browne KP, Tong Y (2006) Interactions between Keggin-type lacunary polyoxometalates and Ag nanoparticles: a surface-enhanced Raman scattering spectroscopic investigation. J Clust Sci 17:349–359
34. Waychunas GA, Fuller CC, Davis JA, Rehr JJ (2003) Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite: II. XANES analysis and simulation. Geochim Cosmochim Acta 67:1031–1043
35. McKeown D, Muller I (2000) Local environment of Zn in zirconium borosilicate glasses determined by X-ray absorption spectroscopy. J Non-Cryst Solids 261:155–162
36. Moss RM, Neel EAA, Pickup DM et al (2010) The effect of zinc and titanium on the structure of calcium–sodium phosphate based glass. J Non Cryst Solids 356:1319–1324
37. Miyanaga T, Watanabe I, Ikeda S, Tashiro K, Fujiwara T (1988) XANES of aqua complexes of 3d transition metals in solid and solution. Bull Chem Soc Jpn 61:2303–3199
38. Mioè U (2003) Structure and proton conductivity in a magnesium salt of 12-tungstophosphoric acid. Solid State Ionics 162–163:217–223
39. Marcus Y (1991) Thermodynamics of solvation of ions. J Chem Soc Faraday Trans 87:2995–2999
40. Brinker CJ, Frye GC, Hurd AJ, Ashley CS (1991) Fundamentals of sol–gel dip coating. Thin Solid Films 201:97–108
41. Lee CH, Lu Y, Shen AQ (2006) Evaporation induced self assembly and rheology change during sol–gel coating. Phys Fluids 18:052105
42. Huang Y, Pan QY, Dong XW, Cheng ZX (2006) Synthesis and photochromism of a novel organic–inorganic hybrid film embedded with polyoxometalates. Mater Chem Phys 97(2–3):431–436
43. Zhang TR, Feng W, Lu R, Bao YB, Li TJ, Zhao YY, Yao JN (2003) Preparation of photochromic sol–gel composite films containing dodecaphosphotungstic acid. Mater Chem Phys 78:380–384
44. Zhong X, Liu Y, Tang X, Wu Q, Li L, Yu Y (2012) Polyoxometalate cured epoxy resins with photochromic properties. Colloid Polym Sci 290:1683–1693