Polyoxometalate cured epoxy resins with photochromic properties

Colloid and Polymer Science

Volumn 290, Issue 16, 2012, Pages 1683-1693

  Zhong, Xinhui ^a   Liu, Yi ^a   Tang, Xiaolin ^a   Wu, Qili ^a   Li, Liang ^a   Yu, Yingfeng ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

Cationic polymerization; Epoxy resin; Photochromism; Polyoxometalate

Indexed keywords

2D CORRELATION ANALYSIS; CURED EPOXY; CURED EPOXY RESINS; D-D TRANSITIONS; DUAL FUNCTION; ELECTRON MOVEMENT; ETHYLENE OXIDES; INITIAL STATE; INTERVALENCE CHARGE TRANSFER; KEGGIN-TYPE; PHOTOCHROMIC BEHAVIOR; PHOTOCHROMIC PROPERTIES; POLYOXOMETALATES; THERMOSETTING MATERIALS; TWODIMENSIONAL CORRELATION ANALYSIS; ULTRAVIOLET IRRADIATIONS; UV IRRADIATION;

CATIONIC POLYMERIZATION; CORRELATION METHODS; CURING; DIFFERENTIAL SCANNING CALORIMETRY; EPOXY RESINS; INFRARED SPECTROSCOPY; ORGANIC SOLVENTS; PHOTOCHROMISM; POLYETHYLENE OXIDES; RESINS; THERMOSETS; ULTRAVIOLET VISIBLE SPECTROSCOPY;

OXIDES;

CATION; EPOXY RESIN; MACROGOL; ORGANIC SOLVENT; PHOTOCHROMOPHORE; POLYMER; POLYOXOMETALATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL PARAMETERS; CORRELATION ANALYSIS; DIFFERENTIAL SCANNING CALORIMETRY; ELECTRICITY; ELECTRON TRANSPORT; INFRARED SPECTROSCOPY; PHOTOCHROMIC PROPERTY; POLYMERIZATION; PRIORITY JOURNAL; TEMPERATURE; THERMOREGULATION; THERMOSTABILITY; ULTRAVIOLET IRRADIATION; ULTRAVIOLET SPECTROSCOPY; ULTRAVIOLET VISIBLE SPECTROSCOPY;

EID: 84868212034     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-012-2688-9     Document Type: Article

References (33)

1. Mizuno N, Misono M (1997) Heteropolyacid catalysts. Curr Opin Solid St M 2:84-89
2. Corma A (1995) Inorganic solid acids and their use in acid-catalyzed hydrocarbon reactions. Chem Rev 95:559-614
3. Misono M (1987) Heterogeneous catalysis by heteropoly compounds of molybdenum and tungsten. Catal Rev 29:269-321
4. Izumi Y, Matsuo K, Urabe K (1983) Efficient homogeneous acid catalysis of heteropoly acid and its characterization through ether cleavage reactions. J Mol Catal 18:299-314
5. Zhang LZ, Gu W, Dong ZL, Liu X, Li B, Liu ML (2009) Syntheses, structures and properties of a series of photochromic hybrids based on Keggin tungstophosphates. J Solid State Chem 182:1040-1044
6. Sun DH, Zhang HJ, Zhang JL, Zheng GL, Yu JB, Gao SY (2007) Synthesis, structure and photochromic properties of a novel 1,6-hexanediamine trimolybdate supramolecular compound. J Solid State Chem 180:393-399
7. Chen J, Ai LM, Feng W, Xiong DQ, Liu Y, Cai WM (2007) Preparation and photochromism of nanocomposite thin film based on polyoxometalate and polyethyleneglycol. Mater Lett 61:5247-5249
8. Feng W, Ding YS, Liu Y, Lu R (2006) The photochromic process of polyoxometalate-based nanocomposite thin film by in situ AFM and spectroscopy. Mater Chem Phys 98:347-352
9. Yang GC, Pan Y, Gao FM, Gong J, Cui XJ, Shao CG, Guo YH, Qu LY (2005) A novel photochromic PVA fiber aggregates contained H4SiW12O40. Mater Lett 59:450-455
10. Feng W, Zhang TR, Wei L, Lu R, Bai YB, Li TJ, Zhao YY, Yao JN (2002) Photochromic behavior and mechanism of thin films in H3PW12O40/polyacrylamide system. Mater Lett 54:309-313
11. Yao JN, Loo BH, Hashimoto K, Fujishima A (1990) Photochromic and electrochromic behavior of electrodeposited MoO3 thin-films. J Electroanal Chem 290:263-267
12. Xu BB, Xu L, Gao GG, Jin YN (2007) Nanosized multilayer films with concurrent photochromism and electrochromism based on Dawson-type polyoxometalate. Appl Surf Sci 253:3190-3195
13. Gao GG, Xu L, Wang WJ, An WJ, Qiu YF, Wang ZQ, Wang EB (2005) Electrochromic multilayer films of tunable color by combination of copper or iron complex and monolacunary Dawsontype polyoxometalate. J Phys Chem B 109:8948-8953
14. Liu SQ, Kurth DG, Mohwald H, Volkmer D (2002) A thin-film electrochromic device based on a polyoxometalate cluster. Adv Mater 14:225-228
15. Chiang MH, Dzielawa JA, Dietz ML, Antonio MR (2004) Redox chemistry of the Keggin heteropolyoxotungstate anion in ionic liquids. J Electroanal Chem 567:77-84
16. Gomez-Romero P, Chojak M, Cuentas-Gallegos K, Asensio JA, Kulesza PJ, Casan-Pastor N, Lira-Cantu M (2003) Hybrid organicinorganic nanocomposite materials for application in solid state electrochemical supercapacitors. Electrochem Commun 5:149-153
17. Yamase T, Ikawa T, Kokado H, Inoue E (1973) Photochromism of dimethylammonium molybdate. Chem Lett 6:615-616
18. Qin B, Chen HY, Liang H, Fu L, Liu XF, Qiu XH, Liu SQ, Song R, Tang ZY (2010) Reversible photoswitchable fluorescence in thin films of inorganic nanoparticle and polyoxometalate assemblies. J Am Chem Soc 132:2886-2888
19. Zhang GJ, Chen ZH, He T, Ke HH, Ma Y, Shao K, Yang WS, Yao JN (2004) Construction of self-assembled ultrathin polyoxometalate/1,10-decanediamine photochromic films. J Phys Chem B 108:6944-6948
20. Zhang TR, Feng W, Lu R, Bao CY, Zhang XT, Li TJ, Zhao YY, Yao JN (2003) Self-assembled 18-molybdophosphate/dioctadecyldimethylammonium composite superlattice thin films with photochromic properties. Mater Chem Phys 78:116-121
21. Qi W, Wu LX (2009) Polyoxometalate/polymer hybrid materials: fabrication and properties. Polym Int 58:1217-1225
22. Wang ZL, Zhang RL, Ma Y, Zheng LD, Peng A, Fu HB, Yao JN (2010) Transparent and flexible phosphomolybdate-agarose composite thin films with visible-light photochromism. J Mater Chem 20:1107-1111
23. Feng W, Zhang TR, Liu Y, Lu R, Zhao YY, Li TJ, Yao JN (2002) Sonochemical preparation of photochromic nanocomposite thin film based on polyoxometalates well dispersed in polyacrylamide. J Solid State Chem 169:1-5
24. Jiang M, Wang E, Xu L, Kang ZH, Lian SY (2004) The first example of multilayer films with thermochromic properties. J Solid State Chem 177:1776-1779
25. Bednarek M, Brzezinska K, Stasinski J, Kubisa P, Penczek S (1989) Heteropolyacids - new efficient initiators of cationic polymerization. Macromol Chem Physic 190:929-938
26. Zhang A, Zhang GL, Zhang HZ (1999) Studies on mechanism of tetrahydrofuran polymerization initiated by a heteropolyacid. Macromol Chem Physic 200:1846-1853
27. Wu Q, Li L, Yu YF, Tang XL (2008) The linear relations and living feature in cationic ring-opening copolymerization of epoxy/THF system. Colloid Polym Sci 286:761-767
28. Yu YF, Zhong XH, Su HH, Serra A (2010) Simultaneous cationic polymerization and esterification of epoxy/anhydride system in the presence of polyoxometalate catalyst. Polymer 51:1563-1571
29. Selektor SL, Semyachkin MY, Arslanov VV (2003) A composite hardener for epoxy adhesives. Russ J Appl Chem 76:1331-1336
30. Tackie M, Martin GC (1993) The polymerization mechanism and kinetics of DGEBA with BF3-MEA. J Appl Polym Sci 48:793-808
31. Li YS, Li MS, Chang FC (1999) Kinetics and curing mechanism of epoxy and boron trifluoride monoethyl amine complex system. J Polym Sci Pol Chem 37:3614-3624
32. Wen WY (1993) Motion of sorbed gases in polymers. Chem Soc Rev 22:117-126
33. Gao Y, Baca AM, Wang B, Ogilby PR (1994) Activation barriers for oxygen diffusion in polystyrene and polycarbonate glasses: effects of low molecular weight additives. Macromolecules 27:7041-7048