The influence of the phosphorus-based flame retardant on the flame retardancy of the epoxy resins

Polymer Degradation and Stability

Volumn 109, Issue , 2014, Pages 209-217

  Zhang, Wenchao ^a   He, Xiangdong ^a   Song, Tinglu ^a   Jiao, Qingjie ^a   Yang, Rongjie ^a  

^a BEIJING INSTITUTE OF TECHNOLOGY   (China)

Author keywords

Condensed phase; Epoxy resin; Flame retardant; Gas phase; Phosphorus

Indexed keywords

EPOXY RESINS; GASES; PHOSPHORUS; STRUCTURE (COMPOSITION); FLAME RETARDANTS;

AMMONIUM POLYPHOSPHATES; CONDENSED PHASE; CONE CALORIMETER; FLAME RETARDANCY; GASPHASE; PHOSPHORUS FLAME RETARDANTS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; VISUAL OBSERVATIONS;

FLAME RETARDANTS; EPOXY RESINS;

EID: 84907336022     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2014.07.023     Document Type: Article

References (35)

1. B. Schartel, A.I. Balabanovich, U. Braun, U. Knoll, J. Artner, and M. Ciesielski et al. Pyrolysis of epoxy resins and fire behavior of epoxy resin composites flame-retarded with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10- oxide Additives J Appl Polym Sci 104 2007 2260 2269 (Pubitemid 46581786)
2. X. Wang, Y. Hu, L. Song, W.Y. Xing, H.D. Lu, and P. Lv et al. Flame retardancy and thermal degradation mechanism of epoxy reisn composites based on a DOPO substituted organophosphorus oligomer Polymer 51 2010 2435 2445
3. H.Z. Liu, S.X. Zheng, and K.M. Nie Morphology and thermomechanical properties of organic-inorganic hybrid composites involving epoxy resin and an incompletely condensed polyhedral oligomeric silsesquioxane Macromolecules 38 2005 5088 5097
4. J. Brus, M. Urbanová, and A. Strachota Epoxy networks reinforced with polyhedral oligomeric silsesquioxane: structure and segmental dynamics as studied by solid-state NMR Macromolecules 41 2008 372 386 (Pubitemid 351212632)
5. R. Liu, and X.D. Wang Synthesis, characterization, thermal properties and flame retardancy of a novel nonflammable phosphazene-based epoxy resin Polym Degrad Stab 94 2009 617 624
6. J.-S. Wang, Y. Liu, H.-B. Zhao, J. Liu, D.-Y. Wang, and Y.-P. Song et al. Metal compound-enhanced flame retardancy of intumescent epoxy resins containing ammonium polyphosphate Polym Degrad Stab 94 2009 625 631
7. W.S. Chow, and S.S. Neoh Dynamic mechanical, thermal, and morphological properties of silane-treated montmorillonite reinforced polycarbonate nanocomposites J Appl Polym Sci 114 2009 3967 3975
8. L. Becker, D. Lenoir, G. Matuschek, and A. Kettrup Thermal degradation of halogen-free flame retardant epoxides and polycarbonate in air J Anal Appl Pyrolysis 60 2001 55 67 (Pubitemid 32408886)
9. C.J. Orme, J.R. Klaehn, M.K. Harrup, R.P. Lash, and F.F. Stewart Characterization of 2-(2-methoxyethoxy)ethanol-substituted phosphazene polymers using pervaporation, solubility parameters, and sorption studies J Appl Polym Sci 97 2005 939 945 (Pubitemid 41162191)
10. N. Lejeune, I. Dez, P.A. Jaffres, J.F. Lohier, P.J. Madec, and J. Sopkova-de Oliveira Santos Sythesis, crystal structure and thermal properties of phosphorylated cyclotriphosphazenes Eur J Inorg Chem 1 2008 138 143
11. U. Braun, B. Schartel, M.A. Fichera, and C. Jager Flame retardancy mechanisms of aluminium phosphinate in combination with melamine polyphosphate and zinc borate in glass-fibre reinforced polyamide 6.6 Polym Degrad Stab 92 2007 1528 1545 (Pubitemid 47176673)
12. H.F. Zhong, P. Wei, P.K. Jiang, and G.L. Wang Thermal degradation behaviors and flame retardancy of PC/ABS with novel silicon-containing flame retardant Fire Mater 31 2007 411 423 (Pubitemid 47603652)
13. S.Y. Lu, and I. Hamerton Recent developments in the chemistry of halogen-free flame retardant polymers Prog Polym Sci 27 2002 1661 1712 (Pubitemid 34811634)
14. B. Schartel, U. Braun, A.I. Balabanovich, J. Artner, M. Ciesielski, and M. Döring et al. Pyrolysis and fire behavior of epoxy systems containing a novel 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-(DOPO)-based diamino hardener Eur Polym J 44 2008 704 715
15. J. Artner, M. Ciesielski, O. Walter, M. Döring, R.M. Perez, and J.K.W. Sandler et al. A novel DOPO-based diamine as hardener and flame retardant for epoxy resin systems Macromol Mater Eng 293 2008 503 514
16. X. Wang, Y. Hu, L. Song, W.Y. Xing, and H.D. Lu Thermal degradation behaviors of epoxy resin/POSS hybrids and phosphorus-silicon synergism of flame retardancy J Polym Sci Pol Phys 48 2010 693 705
17. H.T. Lin, C.H. Lin, Y.M. Hu, and W.C. Su An approach to develop high-Tg epoxy resins for halogen-free copper clad laminates Polymer 50 2009 5685 5692
18. W.S. Liu, Z.G. Wang, L. Xiong, and L.N. Zhao Phosphorus-containing liquid cycloaliphatic epoxy resins for reworkable environment-friendly electronic packaging materials Polymer 51 2010 4776 4783
19. 2 nanocomposites Eur Polym J 43 2007 725 742 (Pubitemid 46273426)
20. X.D. Qian, L. Song, Y. Hu, R.K.K. Yuen, and L.J. Chen Combustion and thermal degradation mechanism of a novel intumescent flame retardant for epoxy acrylate containing phosphorus and nitrogen Ind Eng Chem Res 50 2011 1881 1892
21. S. Bourbigot, B.M. Le, S. Duquesne, and M. Rochery Recent advances for intumescent polymers Macromol Mater Eng 289 2004 499 511
22. B.B. Wang, Q.L. Tai, S.B. Nie, K.Q. Zhou, Q.B. Tang, and Y. Hu et al. Electron beam irradiation cross linking of halogen-free flame retardant ethylene vinyl acetate (EVA) copolymer by silica gel microencapsulated ammonium polyphosphate and char-forming agent Ind Eng Chem Res 50 2011 596 605
23. G. Camino, L. Costa, and G. Martinasso Intumescent fire-retardant systems Polym Degrad Stab 23 1989 359 376
24. X. Li, Y.X. Ou, and Y.S. Shi Combustion behavior and thermal degradation properties of epoxy resins with a curing agent containing a caged bicyclic phosphate Polym Degrad Stab 77 2002 383 390 (Pubitemid 35382191)
25. X. Wang, Y. Hu, L. Song, W.Y. Xing, H.D. Lu, and P. Lv et al. Effect of a triazine ring-containing charing agent on fire retardancy and thermal degradation of intumescent flame retardant epoxy resins Polym Adv Technol 22 2011 2480 2487
26. W.C. Zhang, X.M. Li, and R.J. Yang Novel flame retardancy effects of DOPO-POSS on epoxy resins Polym Degrad Stab 96 2011 2167 2173
27. W.C. Zhang, X.M. Li, L.M. Li, and R.J. Yang Study of the synergistic effect of silicon and phosphorus on the blowing-out effect of epoxy resin composites Polym Degrad Stab 97 2012 1041 1048
28. Li LM, Li XM, Yang RJ. Mechanical, thermal properties, and flame retardancy of PC/ultrafine octaphenyl-POSS composites. J Appl Polym Sci. http://dx.doi.org/10.1002/app.35443.
29. M. Spontón, J.C. Ronda, M. Galià, and V. Cádiz Cone calorimetry studies of benzoxazine-epoxy systems flame retarded by chemically bonded phosphorus or silicon Polym Degrad Stab 94 2009 102 106
30. J.W. Gilman, and T. Kashiwagi Nanocomposites: a revolutionary new flame retardant approach SAMPE J 33 1997 40 46 (Pubitemid 127631170)
31. W.C. Zhang, X.M. Li, and R.J. Yang Pyrolysis and fire behavior of epoxy resin composites based on a phosphorus-containing polyhedral oligomeric silsesquioxane (DOPO-POSS) Polym Degrad Stab 96 2011 1821 1832
32. Q.B. Tang, B.B. Wang, Y.Q. Shi, L. Song, and Y. Hu Microencapsulated ammonium polyphosphate with glycidyl methacrylate shell: application to flame retardant epoxy reisn Ind Eng Chem Res 52 2013 5640 5647
33. J.S. Wang, D.Y. Wang, Y. Liu, X.G. Ge, and Y.Z. Wang Polyamide-enhanced flame retardancy of ammonium polyphosphate on epoxy resin J Appl Polym Sci 108 2008 2644 2653 (Pubitemid 351613330)
34. S. Bourbigot, M.L. Bras, R. Delobel, and L. Gengembre XPS study of an intumescent coating II. Application to the ammonium polyphosphate/ pentaerythritol/ethylenic terpolymer fire retardant system with and without synergistic agent Appl Surf Sci 120 1997 15 29 (Pubitemid 127435038)
35. W.C. Zhang, X.M. Li, H.B. Fan, and R.J. Yang Study on mechanism of phosphorusesilicon synergistic flame retardancy on epoxy resins Polym Degrad Stab 97 2012 2241 2248