A novel catalyst-free process for producing hydrogen and carboxylate from biomass-derived alcohols

International Journal of Hydrogen Energy

Volumn 39, Issue 25, 2014, Pages 13136-13140

  Qu, Yan Chao ^a   Wei, Xin Lai ^a,b   Zuo, Yong ^a   Xu, Qing ^a   Yan, Shi Zhi ^a   Zhang, Ying ^a   Fu, Yao ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

^b HEFEI UNIVERSITY   (China)

Author keywords

Alcohols; Bio ethanol; Carboxylate; Dehydrogenation; Hydrogen

Indexed keywords

ALCOHOLS; BIOETHANOL; CARBOXYLATION; CATALYSTS; DEHYDROGENATION; ETHANOL; HYDROGEN;

BASIC CONDITIONS; BIO-ETHANOLS; CARBOXYLATE; ENVIRONMENTALLY BENIGN; ETHANOL WATER MIXTURES; NOVEL CATALYSTS; PRIMARY ALCOHOLS; REACTION CONDITIONS;

HYDROGEN PRODUCTION;

EID: 84905912694     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2014.06.145     Document Type: Conference Paper

References (21)

1. J. Goldemberg Ethanol for a sustainable energy future Science 315 2007 808 810
2. G.W. Huber, S. Iborra, and A. Corma Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering Chem Rev 106 2006 4044 4098
3. E.L. Kunkes, D.A. Simonetti, R.M. West, J.C. Serrano-Ruiz, C.A. Gärtner, and J.A. Dumesic Catalytic conversion of biomass to monofunctional hydrocarbons and targeted liquid-fuel classes Science 322 2008 417 421
4. A. Corma, S. Iborra, and A. Velty Chemical routes for the transformation of biomass into chemicals Chem Rev 107 2007 2411 2502
5. F. Barbir PEM fuel cells: theory and practice 2005 Elsevier Academic Press New York
6. R. Devanathan Recent developments in proton exchange membranes for fuel cells Energy Environ Sci 1 2008 101 119
7. N. Wagner, and E. Gülzow Change of electrochemical impedance spectra (EIS) with time during CO-poisoning of the Pt-anode in a membrane fuel cell J Power Sources 127 2004 341 347
8. 2 production from biomass-derived hydrocarbons Science 300 2003 2075 2077
9. 2-x at low temperature ChemSusChem 3 2010 1364 1366
10. M. Ni, D.Y.C. Leung, and M.K.H. Leung A review on reforming bio-ethanol for hydrogen production Int J Hydrogen Energy 32 2007 3238 3247
11. G.A. Deluga, J.R. Salge, L.D. Schmidt, and X.E. Verykios Renewable hydrogen from ethanol by autothermal reforming Science 303 2004 993 997
12. 2 production through ethanol steam reforming: tuning catalytic performance through metal-oxide interactions Angew Chem Int Ed 49 2010 9680 9684
13. A. Haryanto, S. Fernando, N. Murali, and S. Adhikari Current status of hydrogen production techniques by steam reforming of ethanol: a review Energy Fuels 19 2005 2098 2106
14. R.G. Lopez, R.M. Navarro, M.A. Pena, and J.L.G. Fierro Hydrogen production by oxidative ethanol reforming on Co, Ni and Cu ex-hydrotalcite catalysts Int J Hydrogen Energy 36 2010 1512 1523
15. 3 catalyst in a dense Pd-Ag membrane reactor to produce hydrogen for PEM fuel cells Int J Hydrogen Energy 34 2009 8558 8565
16. D.O. Christensen, P.L. Silveston, E. Croiset, and R.R. Hudgins Production of hydrogen from the noncatalytic partial oxidation of ethanol Ind Eng Chem Res 43 2004 2636 2642
17. M.K. Moharana, N.R. Peela, S. Khandekar, and D. Kunzru Distributed hydrogen production from ethanol in a microfuel processor: issues and challenges Renew Sustain Energ Rev 15 2011 524 533
18. Reichman B, Mays W. Production of hydrogen from hydrocarbons and oxygenated hydrocarbons. US Patent 2003/0044349 A1, 2003.
19. M. Nielsen, A. Kammer, D. Cozzula, H. Junge, S. Gladiali, and M. Beller Efficient hydrogen production from alcohols under mild reaction conditions Angew Chem Int Ed 50 2011 9593 9597
20. K.A. Graydon Enthalpy of dissociation and hydration number of methane hydrate from the Clapeyron equation J Chem Thermodyn 36 2004 1119 1127
21. J.A. Onwudili, and P.T. Williams Reaction of different carbonaceous materials in alkaline hydrothermal media for hydrogen gas production Green Chem 13 2011 2837 2843