Elucidating the effect of the nucleophilicity of the silyl group in the reduction of CO2 to CO mediated by silyl-copper(I) complexes

Chemistry - A European Journal

Volumn 20, Issue 30, 2014, Pages 9400-9408

  Tan, Gengwen ^a   Blom, Burgert ^a   Gallego, Daniel ^a   Irran, Elisabeth ^a   Driess, Matthias ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

N heterocyclic silylene; nucleophilicity; siloxyl copper(I); silyl copper(I)

Indexed keywords

CARBON DIOXIDE; CHEMICAL ACTIVATION; COPPER; FUNCTIONAL GROUPS; METAL COMPLEXES; SILICON; SILICON COMPOUNDS; SYNTHESIS (CHEMICAL);

ELECTRON WITHDRAWING GROUP; ELECTRON-DONATING GROUP; N-HETEROCYCLIC SILYLENE; NUCLEOPHILICITIES; REDUCTION REACTION; SILOXYL-COPPER(I); SILYL-COPPER(I); TRANSMETALLATION;

COPPER COMPOUNDS;

EID: 84904563128     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201402017     Document Type: Article

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