The rationale for the optimum efficiency of columns packed with new 1.9μm fully porous Titan-C18 particles-A detailed investigation of the intra-particle diffusivity

Journal of Chromatography A

Volumn 1355, Issue , 2014, Pages 164-178

  Gritti, Fabrice ^a   Guiochon, Georges ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

Author keywords

Column efficiency; Internal obstruction factor; Intra particle diffusivity; Particle size distribution; Pore size distribution

Indexed keywords

ACETONITRILE; DIFFUSION; PARTICLE SIZE ANALYSIS; PORE SIZE; POROUS MATERIALS;

ACCURATE MEASUREMENT; COLUMN EFFICIENCY; HEIGHT EQUIVALENT TO A THEORETICAL PLATES; INTERNAL OBSTRUCTION FACTOR; INVERSE SIZE EXCLUSION CHROMATOGRAPHY; LONGITUDINAL DIFFUSIONS; NARROW SIZE DISTRIBUTIONS; RELATIVE STANDARD DEVIATIONS;

POROUS PLATES;

ACETOPHENONE; BUTYROPHENONE; CHEMICALS AND DRUGS; HEPTANOPHENONE; HEXANOPHENONE; OCTANOPHENONE; PROPIOPHENONE; THIOUREA; TOLUENE; UNCLASSIFIED DRUG; VALEROPHENONE; ACETONITRILE; ACETONITRILE DERIVATIVE; SOLVENT;

ARTICLE; DIFFUSION COEFFICIENT; DISPERSION; ELUTION; FLOW RATE; GEL PERMEATION CHROMATOGRAPHY; MEASUREMENT ACCURACY; MEASUREMENT PRECISION; MOLECULAR WEIGHT; PARTICLE SIZE; PERMEABILITY; POROSITY; PRIORITY JOURNAL; PROCESS OPTIMIZATION; REVERSED PHASE LIQUID CHROMATOGRAPHY; CHEMISTRY; DEVICES; DIFFUSION; GEL CHROMATOGRAPHY; PROCEDURES;

ACETONITRILES; CHROMATOGRAPHY, GEL; DIFFUSION; POROSITY; SOLVENTS;

EID: 84904368909     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2014.05.076     Document Type: Article

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