Invisible structures in the X-ray absorption spectra of actinides

Journal of Electron Spectroscopy and Related Phenomena

Volumn 194, Issue , 2014, Pages 88-93

  Kvashnina, Kristina O ^a   De Groot, Frank M F ^b  

^a EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Actinides; Resonant Inelastic X ray Scattering; Uranium; X ray absorption spectroscopy

Indexed keywords

ABSORPTION SPECTRA; ELECTRONIC STRUCTURE; EMISSION SPECTROSCOPY; URANIUM; X RAY ABSORPTION SPECTROSCOPY; X RAY SCATTERING;

BEAM-LINES; CHARGE TRANSFER THEORY; CRYSTAL FIELD THEORY; RESONANT INELASTIC X-RAY SCATTERING; SINGLE PEAK; SPECTRAL SHAPES; X-RAY ABSORPTION SPECTRUM; X-RAY EMISSION SPECTRA;

ACTINIDES;

EID: 84902536131     PISSN: 03682048     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elspec.2014.03.012     Document Type: Article

References (32)

1. K.T. Moore, and G. van der Laan Nature of the 5f states in actinide metals Rev. Mod. Phys. 81 2009 235
2. R.D. Cowan The Theory of Atomic Structure and Spectra 1981 Univ. Calif. Press Berkeley
3. G. van de Laan Hitchhiker's guide to multuplet calcuations Lect. Notes Phys. 697 2006 143 199
4. F. de Groot, and A. Kotani Core Level Spectroscopy of Solids 2008 CRC Press
5. G. Kalkowski, G. Kaindl, W. Brewer, and W. Krone Near-edge X-ray-absorption fine structure in uranium compounds Phys. Rev. B 35 1987 2667 2677
6. H.J. Nilsson, T. Tyliszczak, R.E. Wilson, L. Werme, and D.K. Shuh Soft X-ray scanning transmission X-ray microscopy (STXM) of actinide particles Anal. Bioanal. Chem. 383 2005 41 47 (Pubitemid 41549240)
7. J.G. Tobin, S.-W. Yu, and B.W. Chung Splittings, satellites and fine structure in the soft X-ray spectroscopy of the actinides Top. Catal. 56 2013 1104 1111
8. A. Kotani, and Y. Toyozawa Photoelectron spectra of core electrons in metals with an incomplete shell J. Phys. Soc. Jpn. 37 1974 912 919
9. A. Kotani, and H. Ogasawara Theory of core-level spectroscopy in actinide systems Physica B 186-188 1993 16 20
10. n+1 multiplets of the lanthanides Phys. Rev. B 32 1985 5107 5118
11. J. Goedkoop, B. Thole, G. van der Laan, G. Sawatzky, F. de Groot, and J. Fuggle Calculations of magnetic X-ray dichroism in the 3d absorption spectra of rare-earth compounds Phys. Rev. B 37 1988 2086 2093
12. 2 Surf. Sci. 602 2008 1114 1121
13. H.J. Elmers, A. Chernenkaya, K. Medjanik, M. Emmel, G. Jakob, and G. Schönhense et al. Exchange coupling in the correlated electronic states of amorphous GdFe films Phys. Rev. B 88 2013 174407
14. F.M.F. de Groot X-ray absorption and dichroism of transition metals and their compounds J. Electron Spectrosc. Relat. Phenom. 67 1994 529 622
15. F. de Groot Multiplet effects in X-ray spectroscopy Coord. Chem. Rev. 249 2005 31 63
16. C.K. Jorgensen Spectroscopy of Transition-Group Complexes Advanced in Chemical Physics vol. 5 1963 John Wiley & Sons, Inc. Hoboken, NJ, USA (Chapter 2)
17. A.B.P. Lever, and E.I. Solomon Ligand Field Theory and the Properties of Transition Metal Complexes Inorganic Electronic Structure and Spectroscopy vol. 1 1999 Wiley
18. K. Hämäläinen, D.P. Siddons, J.B. Hastings, and L.E. Berman Elimination of the inner-shell lifetime broadening in X-ray-absorption spectroscopy Phys. Rev. Lett. 67 1991 2850 2853
19. S.M. Butorin Resonant inelastic X-ray scattering as a probe of optical scale excitations in strongly electron-correlated systems: quasi-localized view J. Electron Spectrosc. Relat. Phenom. 110-111 2000 213 233
20. S.M. Butorin, D.K. Shuh, K. Kvashnina, I.L. Soroka, K. Ollila, and K.E. Roberts et al. Resonant inelastic soft X-ray scattering studies of U(VI) reduction on iron surfaces MRS Proc. 807 2004 1 6
21. S.M. Butorin, D.K. Shuh, K.O. Kvashnina, J. Guo, L. Werme, and J. Nordgren Chemical reduction of actinides probed by resonant inelastic X-ray scattering Anal. Chem. 85 2013 11196 11200
22. K. Kvashnina, S. Butorin, D. Shuh, J.-H. Guo, L. Werme, and J. Nordgren Resonant inelastic X-ray scattering of curium oxide Phys. Rev. B 75 2007 115107
23. S.M. Butorin Resonant inelastic soft X-ray scattering spectroscopy of light-actinide materials S.N. Kalmykov, M.A Denecke, Actinide Nanoparticles Research 2011 Springer Science
24. P. Glatzel, T.-C. Weng, K. Kvashnina, J. Swarbrick, M. Sikora, and E. Gallo et al. Reflections on hard X-ray photon-in/photon-out spectroscopy for electronic structure studies J. Electron Spectrosc. Relat. Phenom. 188 2013 17 25
25. M. Kavčič, M. Budnar, A. Mühleisen, F. Gasser, M. Žitnik, and K. Bučar et al. Design and performance of a versatile curved-crystal spectrometer for high-resolution spectroscopy in the tender X-ray range Rev. Sci. Instrum. 83 2012 033113
26. P. Glatzel, and U. Bergmann High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes - electronic and structural information Coord. Chem. Rev. 249 2005 65 95 (Pubitemid 40023313)
27. T. Vitova, K. Kvashnina, G. Nocton, G. Sukharina, M. Denecke, and S. Butorin et al. High energy resolution X-ray absorption spectroscopy study of uranium in varying valence states Phys. Rev. B 82 2010 235118
28. K.O. Kvashnina, Y.O. Kvashnin, and S.M. Butorin Role of resonant inelastic X-ray scattering in high-resolution core-level spectroscopy of actinide materials J. Electron Spec. 2014 (in press)
29. M.A. Denecke, M. Borchert, R.G. Denning, W. De Nolf, G. Falkenberg, and S. Honing et al. Highly resolved synchrotron-based investigations related to nuclear waste disposal MRS Proc. 1444 2012 12
30. T. Vitova, M.A. Denecke, J. Göttlicher, K. Jorissen, J.J. Kas, and K. Kvashnina et al. Actinide and lanthanide speciation with high-energy resolution X-ray techniques J. Phys. Conf. Ser. 430 2013 012117
31. S. Butorin, D. Mancini, J.-H. Guo, N. Wassdahl, J. Nordgren, and M. Nakazawa et al. Resonant X-ray fluorescence spectroscopy of correlated systems: a probe of charge-transfer excitations Phys. Rev. Lett. 77 1996 574 577 (Pubitemid 126625549)
32. K.O. Kvashnina, S.M. Butorin, P. Martin, and P. Glatzel Chemical state of complex uranium oxides Phys. Rev. Lett. 111 2013 253002