Chemical state of complex uranium oxides

Physical Review Letters

Volumn 111, Issue 25, 2013, Pages

  Kvashnina, K O ^a   Butorin, S M ^b   Martin, P ^c   Glatzel, P ^a  

^a EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^b UPPSALA UNIVERSITY   (Sweden)

^c IRFM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC PHYSICS; PHYSICS;

BINARY OXIDES; CHEMICAL STATE; DIRECT OBSERVATIONS; GEOLOGICAL DISPOSALS; RECYCLING APPLICATIONS; U OXIDATIONS; URANIUM OXIDES; URANIUM SYSTEM;

URANIUM COMPOUNDS;

EID: 84890785741     PISSN: 00319007     EISSN: 10797114     Source Type: Journal    
DOI: 10.1103/PhysRevLett.111.253002     Document Type: Article

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39. I 2 configurations. The full multiplet structure due to 3 d - 5 f and 5 f - 5 f Coulomb, exchange, and spin-orbit interactions was also taken into account (note that for U(IV) and U(V), only the first two electronic configurations were included in the calculations for the ground and final state because the contribution of the third configuration is expected to be small). The spectra were calculated by obtaining the transition matrix elements from a chain of the modified programs from the TT-Multiplets package, http://www.esrf.eu/computing/scientific/exafs/ tt-multiplets.html.