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Volumn 91, Issue 6, 2014, Pages 807-816

Application of the covalent bond classification method for the teaching of inorganic chemistry

Author keywords

Analogies Transfer; Covalent Bonding; First Year Undergraduate General; Graduate Education Research; Inorganic Chemistry; Main Group Elements; Nonmetals; Organometallics; Second Year Undergraduate

Indexed keywords


EID: 84902151472     PISSN: 00219584     EISSN: 19381328     Source Type: Journal    
DOI: 10.1021/ed400504f     Document Type: Article
Times cited : (169)

References (62)
  • 1
    • 33646438134 scopus 로고    scopus 로고
    • Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts
    • The valence of an atom is the number of electrons that it has used in bonding. See
    • The valence of an atom is the number of electrons that it has used in bonding. See: Parkin, G. Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts J. Chem. Educ. 2006, 83, 791-799
    • (2006) J. Chem. Educ. , vol.83 , pp. 791-799
    • Parkin, G.1
  • 3
    • 0011243202 scopus 로고
    • The Chemical Bond
    • Lewis, G. N. The Chemical Bond J. Chem. Phys. 1933, 1, 17-28
    • (1933) J. Chem. Phys. , vol.1 , pp. 17-28
    • Lewis, G.N.1
  • 4
    • 0001902670 scopus 로고
    • Types of Valence
    • Langmuir, I. Types of Valence Science 1921, 54, 59-67
    • (1921) Science , vol.54 , pp. 59-67
    • Langmuir, I.1
  • 5
    • 3843134255 scopus 로고
    • The Structure of Atoms and the Octet Theory of Valence
    • Langmuir, I. The Structure of Atoms and the Octet Theory of Valence Proc. Natl. Acad. Sci. U. S. A. 1919, 5, 252-259
    • (1919) Proc. Natl. Acad. Sci. U. S. A. , vol.5 , pp. 252-259
    • Langmuir, I.1
  • 6
    • 0008301502 scopus 로고
    • Abegg, Lewis, Langmuir, and the Octet Rule
    • Jensen, W. B. Abegg, Lewis, Langmuir, and the Octet Rule J. Chem. Educ. 1984, 61, 191-200
    • (1984) J. Chem. Educ. , vol.61 , pp. 191-200
    • Jensen, W.B.1
  • 8
    • 77953289015 scopus 로고    scopus 로고
    • Non-innocent Ligands in Bioinorganic Chemistry-An Overview
    • Kaim, W.; Schwederski, B. Non-innocent Ligands in Bioinorganic Chemistry-An Overview Coord. Chem. Rev. 2010, 254, 1580-1588
    • (2010) Coord. Chem. Rev. , vol.254 , pp. 1580-1588
    • Kaim, W.1    Schwederski, B.2
  • 9
    • 84856041532 scopus 로고    scopus 로고
    • The Shrinking World of Innocent Ligands: Conventional and Non-Conventional Redox-Active Ligands
    • Kaim, W. The Shrinking World of Innocent Ligands: Conventional and Non-Conventional Redox-Active Ligands Eur. J. Inorg. Chem. 2012, 343-348
    • (2012) Eur. J. Inorg. Chem. , pp. 343-348
    • Kaim, W.1
  • 10
    • 84872982377 scopus 로고    scopus 로고
    • Redox-active Ligands in Catalysis
    • Luca, O. R.; Crabtree, R. H. Redox-active Ligands in Catalysis Chem. Soc. Rev. 2013, 42, 1440-1459
    • (2013) Chem. Soc. Rev. , vol.42 , pp. 1440-1459
    • Luca, O.R.1    Crabtree, R.H.2
  • 11
    • 80052443433 scopus 로고    scopus 로고
    • Manifestations of Noninnocent Ligand Behavior
    • Kaim, W. Manifestations of Noninnocent Ligand Behavior Inorg. Chem. 2011, 50, 9752-9765
    • (2011) Inorg. Chem. , vol.50 , pp. 9752-9765
    • Kaim, W.1
  • 12
    • 0001361495 scopus 로고
    • A New Approach to the Formal Classification of Covalent Compounds of the Elements
    • Green, M. L. H. A New Approach to the Formal Classification of Covalent Compounds of the Elements J. Organomet. Chem. 1995, 500, 127-148
    • (1995) J. Organomet. Chem. , vol.500 , pp. 127-148
    • Green, M.L.H.1
  • 13
    • 84902142860 scopus 로고
    • An Introduction to the Chemistry of Molybdenum
    • Braithwaite, E. R. Haber, J. Elsevier: Amsterdam, Chapter 2.
    • Green, M. L. H. An Introduction to the Chemistry of Molybdenum. In Molybdenum: An Outline of its Chemistry and Uses; Braithwaite, E. R.; Haber, J., Eds.; Elsevier: Amsterdam, 1994; Chapter 2.
    • (1994) Molybdenum: An Outline of Its Chemistry and Uses
    • Green, M.L.H.1
  • 14
    • 84902194395 scopus 로고    scopus 로고
    • Classification of Organotransition Metal Compounds
    • Crabtree, R. H. Mingos, D. M. P. Elsevier: Oxford, Vol. Chapter 1.
    • Parkin, G. Classification of Organotransition Metal Compounds. In Comprehensive Organometallic Chemistry III; Crabtree, R. H.; Mingos, D. M. P., Eds.; Elsevier: Oxford, 2007; Vol. 1, Chapter 1.
    • (2007) Comprehensive Organometallic Chemistry III , vol.1
    • Parkin, G.1
  • 15
    • 84868379215 scopus 로고    scopus 로고
    • The Occurrence and Representation of Three-Centre Two-Electron Bonds in Covalent Inorganic Compounds
    • Green, J. C.; Green, M. L. H.; Parkin, G. The Occurrence and Representation of Three-Centre Two-Electron Bonds in Covalent Inorganic Compounds Chem. Commun. 2012, 48, 11481-11503
    • (2012) Chem. Commun. , vol.48 , pp. 11481-11503
    • Green, J.C.1    Green, M.L.H.2    Parkin, G.3
  • 16
    • 84902197696 scopus 로고    scopus 로고
    • Covalent Bond Classification.
    • Covalent Bond Classification. http://www.covalentbondclass.org/.
  • 18
    • 0003621450 scopus 로고
    • Freeman: San Francisco
    • Pauling, L. General Chemistry; Freeman: San Francisco, 1947; p 173.
    • (1947) General Chemistry , pp. 173
    • Pauling, L.1
  • 19
    • 0343744035 scopus 로고
    • The Modern Theory of Valency
    • Pauling, L. The Modern Theory of Valency J. Chem. Soc. 1948, 1461-1467
    • (1948) J. Chem. Soc. , pp. 1461-1467
    • Pauling, L.1
  • 20
    • 33845559423 scopus 로고
    • Assigning Oxidation-States to Some Metal Dioxygen Complexes of Biological Interest
    • Summerville, D. A.; Jones, R. D.; Hoffman, B. M.; Basolo, F. Assigning Oxidation-States to Some Metal Dioxygen Complexes of Biological Interest J. Chem. Educ. 1979, 56, 157-162
    • (1979) J. Chem. Educ. , vol.56 , pp. 157-162
    • Summerville, D.A.1    Jones, R.D.2    Hoffman, B.M.3    Basolo, F.4
  • 21
    • 0002774980 scopus 로고
    • The Stabilization of Oxidation States of the Transition Metals
    • Nyholm, R. S.; Tobe, M. L. The Stabilization of Oxidation States of the Transition Metals Adv. Inorg. Chem. Radiochem. 1963, 5, 1-40
    • (1963) Adv. Inorg. Chem. Radiochem. , vol.5 , pp. 1-40
    • Nyholm, R.S.1    Tobe, M.L.2
  • 22
    • 0040835877 scopus 로고
    • Metal-Metal Bonds in Transition Metal Complexes
    • Lewis, J.; Nyholm, R. S. Metal-Metal Bonds in Transition Metal Complexes Sci. Prog. (London) 1964, 52, 557-580
    • (1964) Sci. Prog. (London) , vol.52 , pp. 557-580
    • Lewis, J.1    Nyholm, R.S.2
  • 23
    • 33749827321 scopus 로고
    • Magnetism, Bonding and Structure of Coordination Compounds
    • Nyholm, R. S. Magnetism, Bonding and Structure of Coordination Compounds Pure Appl. Chem. 1968, 17, 1-19
    • (1968) Pure Appl. Chem. , vol.17 , pp. 1-19
    • Nyholm, R.S.1
  • 28
    • 0000166776 scopus 로고
    • Cycloheptatriene and -enyl Complexes of the Early Transition Metals
    • Green, M. L. H.; Ng, D. K. P. Cycloheptatriene and -enyl Complexes of the Early Transition Metals Chem. Rev. 1995, 95, 439-473
    • (1995) Chem. Rev. , vol.95 , pp. 439-473
    • Green, M.L.H.1    Ng, D.K.P.2
  • 31
    • 33947461085 scopus 로고
    • π-Tropenium-Molybdenum-Tricarbonyl Fluoroborate
    • Dauben, H. J.; Honnen, L. R. π-Tropenium-Molybdenum-Tricarbonyl Fluoroborate J. Am. Chem. Soc. 1958, 80, 5570-5571
    • (1958) J. Am. Chem. Soc. , vol.80 , pp. 5570-5571
    • Dauben, H.J.1    Honnen, L.R.2
  • 32
    • 0001218647 scopus 로고
    • π-Cyclopentadienyl-π-Cycloheptatrienyl Vanadium
    • King, R. B.; Stone, F. G. A. π-Cyclopentadienyl-π-Cycloheptatrienyl Vanadium J. Am. Chem. Soc. 1959, 81, 5263-5264
    • (1959) J. Am. Chem. Soc. , vol.81 , pp. 5263-5264
    • King, R.B.1    Stone, F.G.A.2
  • 33
    • 0000234013 scopus 로고
    • He(I) and He(II) Photoeletron Spectra of Some Mixed Sandwich Compounds of Titanium, Zirconium and Hafnium
    • Andréa, R. R.; Terpstra, A.; Oskam, A.; Bruin, P.; Teuben, J. H. He(I) and He(II) Photoeletron Spectra of Some Mixed Sandwich Compounds of Titanium, Zirconium and Hafnium J. Organomet. Chem. 1986, 307, 307-317
    • (1986) J. Organomet. Chem. , vol.307 , pp. 307-317
    • Andréa, R.R.1    Terpstra, A.2    Oskam, A.3    Bruin, P.4    Teuben, J.H.5
  • 35
    • 2342429059 scopus 로고    scopus 로고
    • Charge Transfer Excitation of Organometallic Compounds Spectroscopy and photochemistry
    • Vogler, A.; Kunkely, H. Charge Transfer Excitation of Organometallic Compounds Spectroscopy and photochemistry Coord. Chem. Rev. 2004, 248, 273-278
    • (2004) Coord. Chem. Rev. , vol.248 , pp. 273-278
    • Vogler, A.1    Kunkely, H.2
  • 37
    • 84870486596 scopus 로고    scopus 로고
    • The Organometallic Chemistry of Cycloheptatrienyl Zirconium Complexes
    • Glockner, A.; Tamm, M. The Organometallic Chemistry of Cycloheptatrienyl Zirconium Complexes Chem. Soc. Rev. 2013, 42, 128-142
    • (2013) Chem. Soc. Rev. , vol.42 , pp. 128-142
    • Glockner, A.1    Tamm, M.2
  • 38
    • 46249085390 scopus 로고    scopus 로고
    • Synthesis and Reactivity of Functionalized Cycloheptatrienyl- Cyclopentadienyl Sandwich Complexes
    • Tamm, M. Synthesis and Reactivity of Functionalized Cycloheptatrienyl- Cyclopentadienyl Sandwich Complexes Chem. Commun. 2008, 3089-3100
    • (2008) Chem. Commun. , pp. 3089-3100
    • Tamm, M.1
  • 39
    • 1342327522 scopus 로고    scopus 로고
    • Mono- and Dinuclear Molybdenum Complexes with Sterically Demanding Cycloheptatrienyl Ligands
    • Tamm, M.; Bannenberg, T.; Frohlich, R.; Grimme, S.; Gerenkamp, M. Mono- and Dinuclear Molybdenum Complexes with Sterically Demanding Cycloheptatrienyl Ligands Dalton Trans. 2004, 482-491
    • (2004) Dalton Trans. , pp. 482-491
    • Tamm, M.1    Bannenberg, T.2    Frohlich, R.3    Grimme, S.4    Gerenkamp, M.5
  • 40
    • 53249084414 scopus 로고    scopus 로고
    • Bis(cycloheptatrienyl) Derivatives of the First-Row Transition Metals: Variable Hapticity of the Cycloheptatrienyl Ring
    • Wang, H. Y.; Xie, Y. M.; King, R. B.; Schaefer, H. F. Bis(cycloheptatrienyl) Derivatives of the First-Row Transition Metals: Variable Hapticity of the Cycloheptatrienyl Ring Eur. J. Inorg. Chem. 2008, 3698-3708
    • (2008) Eur. J. Inorg. Chem. , pp. 3698-3708
    • Wang, H.Y.1    Xie, Y.M.2    King, R.B.3    Schaefer, H.F.4
  • 44
    • 0012304032 scopus 로고
    • Facile Formation of the Cycloheptatrienyl Trianion by Lanthanide Andactinide Ions
    • Miller, J. T.; Dekock, C. W. Facile Formation of the Cycloheptatrienyl Trianion by Lanthanide Andactinide Ions J. Organomet. Chem. 1981, 216, 39-48
    • (1981) J. Organomet. Chem. , vol.216 , pp. 39-48
    • Miller, J.T.1    Dekock, C.W.2
  • 48
    • 0037894928 scopus 로고    scopus 로고
    • Nomenclature of organometallic compounds of the transition elements (IUPAC Recommendations 1999)
    • Salzer, A. Nomenclature of organometallic compounds of the transition elements (IUPAC Recommendations 1999) Pure Appl. Chem. 1999, 71, 1557-1585
    • (1999) Pure Appl. Chem. , vol.71 , pp. 1557-1585
    • Salzer, A.1
  • 55
    • 84902183866 scopus 로고    scopus 로고
    • reference 10.
    • reference 10.
  • 56
    • 84989514941 scopus 로고
    • Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
    • Haaland, A. Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction Angew. Chem., Int. Ed. Engl. 1989, 28, 992-1007
    • (1989) Angew. Chem., Int. Ed. Engl. , vol.28 , pp. 992-1007
    • Haaland, A.1
  • 57
    • 33847034094 scopus 로고    scopus 로고
    • 3] Donor Ancillary Ligands: Structural and Computational Evidence that a Linear Nitrosyl is a Trivalent Ligand
    • 3] Donor Ancillary Ligands: Structural and Computational Evidence that a Linear Nitrosyl is a Trivalent Ligand Dalton Trans. 2007, 820-824
    • (2007) Dalton Trans. , pp. 820-824
    • Landry, V.K.1    Pang, K.2    Quan, S.M.3    Parkin, G.4
  • 58
    • 84902154581 scopus 로고    scopus 로고
    • z] classification of molecules is presently available on the World Wide Web at http://winter.group.shef.ac.uk/chemputer/mlxz.html.
  • 59
    • 13244295338 scopus 로고    scopus 로고
    • Zirconate Complexes: Multifaceted Reagents
    • Majoral, J. P.; Zablocka, M. Zirconate Complexes: Multifaceted Reagents New J. Chem. 2005, 29, 32-41
    • (2005) New J. Chem. , vol.29 , pp. 32-41
    • Majoral, J.P.1    Zablocka, M.2
  • 61
    • 0009316715 scopus 로고    scopus 로고
    • Oxidation Numbers
    • Calzaferri, G. Oxidation Numbers J. Chem. Educ. 1999, 76, 362-363
    • (1999) J. Chem. Educ. , vol.76 , pp. 362-363
    • Calzaferri, G.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.