-
1
-
-
0004181718
-
-
Oxford University Press, New York, For recent reviews of metal nitrosyl compounds, see:
-
G. B. Richter-Addo and G. B. Legzdins, Metal Nitrosyls, Oxford University Press, New York, 1992
-
(1992)
Metal Nitrosyls
-
-
Richter-Addo, G.B.1
Legzdins, G.B.2
-
6
-
-
33847055000
-
-
2(NO)Br. See:
-
G. Parkin, in Comprehensive Organometallic Chemistry III, ed., R. H. Crabtree, and, D. M. P. Mingos, vol. 1, ch. 1, Elsevier, Oxford, 2006
-
(2006)
Comprehensive Organometallic Chemistry III, Ed.
-
-
Parkin In, G.1
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8
-
-
24244456607
-
-
Three-coordinate terminal nickel nitrosyl compounds have also been synthesized. See, for example:
-
R. D. Feltham Inorg. Chem. 1964 3 116 119
-
(1964)
Inorg. Chem.
, vol.3
, pp. 116-119
-
-
Feltham, R.D.1
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18
-
-
0001051060
-
-
3] array, see:
-
D. J. Darensbourg T. J. Decuir N. W. Stafford J. B. Robertson J. D. Draper J. H. Reibenspies A. Kathó F. Joó Inorg. Chem. 1997 36 4218 4226
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(1997)
Inorg. Chem.
, vol.36
, pp. 4218-4226
-
-
Darensbourg, D.J.1
Decuir, T.J.2
Stafford, N.W.3
Robertson, J.B.4
Draper, J.D.5
Reibenspies, J.H.6
Kathó, A.7
Joó, F.8
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20
-
-
33847039066
-
-
But]NiNO. D. Rabinovich, personal communication and ref. 7(b)
-
L. S. Maffett, K. L. Gunter, K. A. Kreisel, G. P. A. Yap and D. Rabinovich, Abstracts of Papers, 231st ACS National Meeting, Atlanta, GA, United States, March 26-30, 2006, INOR-598
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(2006)
Abstracts of Papers, 231st ACS National Meeting
-
-
Maffett, L.S.1
Gunter, K.L.2
Kreisel, K.A.3
Yap, G.P.A.4
Rabinovich, D.5
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24
-
-
33847064963
-
-
note
-
Mes]NiNO [180.0°].
-
-
-
-
25
-
-
33847029051
-
-
note
-
Values for two crystallographically independent molecules.
-
-
-
-
26
-
-
33847039855
-
-
note
-
Mes]NiNO [1.156(5) Å] are also similar to other reported values.
-
-
-
-
28
-
-
33847030633
-
-
note
-
Mes]NiNO is a mononitrosyl, two ν(NO) bands are observed. Such splitting has been previously documented. See, for example, ref. 1. Alternatively, it is possible that the extra peak could correspond to an unidentified impurity.
-
-
-
-
30
-
-
0037924515
-
-
3NiNO have also been used to evaluate the relative electron donor properties of a series of phosphite ligands. See:
-
R. G. Bergman T. R. Cundari A. M. Gillespie T. B. Gunnoe W. D. Harman T. R. Klinckman M. D. Temple D. P. White Organometallics 2003 22 2331 2337
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(2003)
Organometallics
, vol.22
, pp. 2331-2337
-
-
Bergman, R.G.1
Cundari, T.R.2
Gillespie, A.M.3
Gunnoe, T.B.4
Harman, W.D.5
Klinckman, T.R.6
Temple, M.D.7
White, D.P.8
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33
-
-
33749827321
-
-
n configuration is the number of electrons that are housed in metal d orbitals that are either primarily nonbonding or have metal-ligand antibonding character. See ref. 3 and: R. S. Nyholm Pure Appl. Chem. 1968 17 1 19
-
(1968)
Pure Appl. Chem.
, vol.17
, pp. 1-19
-
-
Nyholm, R.S.1
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35
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-
12844261196
-
-
R. B. King, Wiley, New York, p. 961
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Encyclopedia of Inorganic Chemistry, ed., R. B. King, Wiley, New York, 1994, vol. 2, p. 961
-
(1994)
Encyclopedia of Inorganic Chemistry, Ed.
-
-
-
36
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-
84890738094
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-
Wiley, New York, 43
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R. H. Crabtree, The Organometallic Chemistry of the Transition Metals, 4th edn, Wiley, New York, 2005, p. 43
-
(2005)
The Organometallic Chemistry of the Transition Metals, 4th Edn
-
-
Crabtree, R.H.1
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37
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-
0003921230
-
-
Oxford University Press, New York, 299 For examples of linear NO ligands assigned a non-closed shell charge of -1, see:
-
D. M. P. Mingos, Essential Trends in Inorganic Chemistry, Oxford University Press, New York, 1998, p. 299
-
(1998)
Essential Trends in Inorganic Chemistry
-
-
Mingos, D.M.P.1
-
43
-
-
0008889329
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-
Wiley, New York, 155-215; see especially p. 158
-
R. D. Feltham and J. H. Enemark, in Topics in Inorganic and Organic Stereochemistry, Wiley, New York, 1981, vol. 12, pp. 155-215; see especially p. 158
-
(1981)
Topics in Inorganic and Organic Stereochemistry
, vol.12
-
-
Feltham, R.D.1
Enemark In, J.H.2
-
44
-
-
0001001584
-
-
Inorganic Electronic Structure and Spectroscopy, ed., A. B. P. Lever, and, E. I. Solomon, ch. 7
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B. L. Westcott and J. H. Enemark, in Inorganic Electronic Structure and Spectroscopy, ed., A. B. P. Lever, and, E. I. Solomon, Inorganic Electronic Structure and Spectroscopy, Volume II: Applications and Case Studies, 1999, ch. 7, pp. 403-450
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(1999)
Inorganic Electronic Structure and Spectroscopy, Volume II: Applications and Case Studies
, pp. 403-450
-
-
Westcott, B.L.1
Enemark, J.H.2
-
49
-
-
33847011248
-
-
note
-
yz orbitals due to poorer overlap for the former.
-
-
-
-
50
-
-
33847032019
-
-
note
-
n configuration is effectively modified if π-backbonding is significant.
-
-
-
-
52
-
-
0001466293
-
-
3-. While the former classification is more commonly encountered, it also results in unusual oxidation number assignments that do not correspond to the results of photoelectron spectroscopic and theoretical studies. See, for example:
-
X. Li J. S. Tse G. M. Bancroft R. J. Puddephatt K. H. Tan Inorg. Chem. 1996 35 2515 2523
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(1996)
Inorg. Chem.
, vol.35
, pp. 2515-2523
-
-
Li, X.1
Tse, J.S.2
Bancroft, G.M.3
Puddephatt, R.J.4
Tan, K.H.5
-
54
-
-
33847081618
-
-
note
-
0 complexes according to the Enemark-Feltham notation.
-
-
-
-
55
-
-
33847072986
-
-
note
-
1 correspond to XZ. See ref. 3.
-
-
-
-
56
-
-
33847049320
-
-
note
-
+ is a consequence of the fact that the N-O π* antibonding orbitals become fully occupied upon coordination.
-
-
-
-
57
-
-
33847051938
-
-
note
-
3 bond length for complexes listed in the Cambridge Structural Database (ref. 15)
-
-
-
-
64
-
-
0001614698
-
-
π-orbital. This situation is closely analogous to the differing M≈O bond orders in monooxo (3), cis-dioxo (2.5) and trans-dioxo (2) compounds. See, for example:
-
B. L. Westcott J. H. Enemark Inorg. Chem. 1997 36 5404 5405
-
(1997)
Inorg. Chem.
, vol.36
, pp. 5404-5405
-
-
Westcott, B.L.1
Enemark, J.H.2
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