Mono- and dinuclear molybdenum complexes with sterically demanding cycloheptatrienyl ligands

Journal of the Chemical Society. Dalton Transactions

Volumn 4, Issue 3, 2004, Pages 482-491

  Tamm, Matthias ^a   Bannenberg, Thomas ^a   Fröhlich, Roland ^b   Grimme, Stefan ^b   Gerenkamp, Mareike ^b  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Cyclopentadienyl and related cycloalkenyl ligands; Density functional calculations; Electrochemistry, spectroelectrochemistry; Molybdenum; Organometallic

Indexed keywords

CYCLOHEPTANE DERIVATIVE; LIGAND; MOLYBDENUM; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; CYCLOHEPTANES; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

BENZENE; CALCULATIONS; CARBON MONOXIDE; COMPLEXATION; CYCLIC VOLTAMMETRY; FLUORINE COMPOUNDS; HYDRIDES; METHANE; OXIDATION; POSITIVE IONS; SALTS; SUBSTITUTION REACTIONS;

CYCLOHEPTATRIENYL LIGANDS; DIAZOMETHANE; HYDRIDE ABSTRACTION; MESITYLENE; MOLYBDENUM COMPLEXES; TRIPHENYLCARBENIUM TETRAFLUOROBORATE;

MOLYBDENUM COMPOUNDS;

EID: 1342327522     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b314347c     Document Type: Article

References (106)

1. Comprehensive Organometallic Chemistry, ed. G. Wilkinson, F.G.A. Stone and E.W. Abel, Pergamon Press, Oxford, (1982)
2. Comprehensive Organometallic Chemistry II, ed. E.W. Abel, F.G.A. Stone and G. Wilkinson, Chapman and Hall, Oxford, (1995)
3. Metallocenes, ed. A. Togni and R.L. Halterman, Wiley-VCH, Weinheim, (1998)
4. Special Issue: 50th Anniversary of the Discovery of Ferrocene, ed. R.D. Adams, J. Organomet. Chem., (2001), 637–639, 1.
5. C. Janiak, H. Schumann: Adv. Organomet. Chem. (1991), 33: 331.
6. J. Okuda: Top. Curr. Chem. (1991), 160: 99.
7. N.J. Coville, K.E. du Plooy, W. Pickl: Coord. Chem. Rev. (1992), 116: 1.
8. R.L. Halterman: Chem. Rev. (1992), 92: 965.
9. M.L. Hays, T.P. Hanusa: Adv. Organomet. Chem. (1996), 40: 117.
10. S. Brydges, L.E. Harrington, M.J. McGlinchey: Coord. Chem. Rev. (2002), 233–234: 75.
11. Applied Homogeneous Catalysis with Organometallic Compounds, ed. B. Cornils and W.A. Herrmann, Wiley-VCH, Weinheim, (1996)
12. W.A. Herrmann, B. Cornils: Angew. Chem. (1997), 109: 1074.
13. W.A. Herrmann, B. Cornils: Angew. Chem., Int. Ed. Engl. (1997), 36: 1048.
14. G.J.P. Britovsek, V.C. Gibson, D.F. Wass: Angew. Chem. (1999), 111: 448.
15. G.J.P. Britovsek, V.C. Gibson, D.F. Wass: Angew. Chem., Int. Ed. (1999), 38: 428.
16. Frontiers in Metal-Catalyzed Polymerisation, ed. J.A. Gladysz, Chem. Rev., (2000), 100(4)
17. L.S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules, University Science, California, (1994)
18. Transition Metals for Organic Synthesis, ed. M. Beller and C. Bolm, Wiley-VCH, Weinheim, (1998)
19. Inorganic Materials, ed. D.W. Bruce and D. O’Hare, Wiley, Chichester, (1992)
20. A.S. Abd-El-Aziz: Coord. Chem. Rev. (2002), 233–234: 177.
21. A.S. Abd-El-Aziz, S. Bernardin: Coord. Chem. Rev. (2000), 203: 219.
22. R.D. Pike, D. A Sweigart: Coord. Chem. Rev. (1999), 187: 183.
23. M.L.H. Green, D.K.P. Ng: Chem. Rev. (1995), 95: 439.
24. M. Tamm, B. Dreßel, R. Fröhlich: J. Org. Chem. (2000), 65: 6795.
25. M. Tamm, B. Dreßel, R. Fröhlich, K. Bergander: Chem. Commun. (2000), 1731.
26. M. Tamm, T. Bannenberg, B. Dreßel, R. Fröhlich, D. Kunz: Organometallics (2001), 20: 900.
27. M. Tamm, T. Bannenberg, B. Dreßel, R. Fröhlich, C. Holst: Inorg. Chem. (2002), 41: 47.
28. M. Tamm, K. Baum, T. Lügger, R. Fröhlich, K. Bergander: Eur. J. Inorg. Chem. (2002), 918.
29. M. Tamm, B. Dreßel, V. Urban, T. Lügger: Inorg. Chem. Commun. (2002), 5: 837.
30. M. Tamm, B. Dreßel, T. Lügger, R. Fröhlich, S. Grimme: Eur. J. Inorg. Chem. (2003), 1088.
31. M. Tamm, B. Dreßel, K. Baum, T. Lügger, T. Pape: J. Organomet. Chem. (2003), 677: 1.
32. M. Tamm, B. Dreßel, T. Lügger: J. Organomet. Chem. (2003), 684: 322.
33. J.T. Miller, C.W. Dekock: J. Organomet. Chem. (1981), 216: 39.
34. J.J. Bahl, R.B. Bates, W.A. Beavers, C.R. Launer: J. Am. Chem. Soc. (1977), 99: 6126.
35. J.C. Green, N. Kaltsoyannis, K.H. Sze, M. MacDonald: J. Am. Chem. Soc. (1994), 116: 1994.
36. N. Kaltsoyannis: J. Chem. Soc., Dalton Trans. (1995), 3729.
37. F.T. Edelmann, D.M.M. Freckmann, H. Schumann: Chem. Rev. (2002), 102: 1851.
38. P.W. Roesky: Eur. J. Inorg. Chem. (2001), 1653.
39. T. Arliguie, M. Lance, M. Nierlich, J. Vigner, M. Ephrikithine: Chem. Commun. (1995), 183.
40. T. Arliguie, M. Lance, M. Nierlich, M. Ephrikithine: J. Chem. Soc., Dalton Trans. (1997), 2501.
41. P. Jutzi, in The Chemistry of Organic Silicon Compounds, ed. Z. Rappoport and Y. Apeloig, J. Wiley & Sons Ltd., London, (1998), vol. 2-3, p. 2129.
42. P. Jutzi, R. Sauer: J. Organomet. Chem. (1973), 50: C29.
43. P. Jutzi, E. Schlueter, S. Pohl, W. Saak: Chem. Ber. (1985), 118: 1959.
44. B.A. Keay, in Science of Synthesis, ed. I. Fleming and S.V. Ley, Georg Thieme Verlag, Stuttgart, (2002), vol. 4:, p. 685.
45. T. Kitagawa, A. Miyabo, H. Fujii, T. Okazaki, T. Mori, M. Matsudou, T. Sugie, K. Takeuchi: J. Org. Chem. (1997), 62: 888.
46. K. Kaomatsu, K. Takeuchi, M. Arima, Y. Waki, S. Shirai, Okamoto: Bull. Chem. Soc. Jpn. (1982), 55: 3257.
47. K. Okamoto, K. Takeuchi, K. Komatsu, Y. Kubota, R. Ohara, M. Arima, K. Takahashi, Y. Waki, S. Shirai: Tetrahedron (1983), 39: 4011.
48. E. Müller, H. Kessler, H. Fricke, W. Kiedaisch: Liebigs Ann. Chem. (1964), 675: 63.
49. A. de Meijere, D. Faber, M. Noltemeyer, R. Boese, T. Haumann, T. Müller, M. Bendikov, E. Matzner, Y. Apeloig: J. Org. Chem. (1996), 61: 8564.
50. E.W. Colvin, Silicon Reagents in Organic Synthesis, Academic Press, London, (1988)
51. A.R. Bassindale and P.P. Gaspar, Frontiers of Organosilicon Chemistry, The Royal Society of Chemistry, Cambridge, (1991)
52. Y. Apeloig, in The Chemistry of Organosilicon Compounds ed. S. Patai and Z. Rappoport, J. Wiley & Sons Ltd., London, (1989), vol. 1:, p. 57.
53. J.B. Lambert: Tetrahedron (1990), 46: 2677.
54. Y. Apeloig, A. Stanger: J. Org. Chem. (1982), 47: 1462.
55. M.L. Morrell, G. Vincow: J. Am. Chem. Soc. (1969), 91: 6389.
56. G. Vincow, M.L. Morrell, F.R. Hunter, H.J. Dauben, Jr.: J. Chem. Phys. (1968), 48: 2876.
57. S.P. Solodovnikov, E.A. Chernyshev: Zh. Strukt. Khim. (1962), 3: 665.
58. F. Gerson, J. Heinzer, H. Bock, A. Alt, H. Seidl: Helv. Chim. Acta (1968), 51: 707.
59. H. Bock, H. Alt: J. Am. Chem. Soc. (1970), 92: 1569.
60. H.J. Sipe, R. West: J. Organomet. Chem. (1974), 70: 353.
61. G.R. Clark, G.J. Palenik: J. Organomet. Chem. (1973), 50: 185.
62. G.M. Aston, S. Badriya, R.D. Farley, R.W. Grime, S.J. Ledger, F.E. Mabbs, E.J.L. McInnes, H.W. Morris, A. Ricalton, C.C. Rowlands, K. Wagner, M.W. Whiteley: J. Chem. Soc., Dalton Trans. (1999), 4379.
63. R.L. Beddoes, R.W. Grime, Z.I. Hussain, M.W. Whiteley: J. Chem. Soc., Dalton Trans. (1996), 3893.
64. R. Beddoes, C. Bitcon, R. Grime, A. Ricalton, M.W. Whiteley: J. Chem. Soc., Dalton Trans. (1995), 2873.
65. M.L.H. Green, D.K.P. Ng: J. Chem. Soc., Dalton Trans. (1993), 17.
66. A. Roberts, M.W. Whiteley: J. Organomet. Chem. (1993), 458: 131.
67. C. Bitcon, R. Breeze, P.F. Miller, M.W. Whiteley: J. Organomet. Chem. (1989), 364: 181.
68. J.S. Adams, C. Bitcon, J.R. Brown, D. Collison, M. Cunningham, M.W. Whiteley: J. Chem. Soc., Dalton Trans. (1987), 3049.
69. M.L.H. Green, R.B.A. Pardy: Polyhedron (1985), 4: 1035.
70. M.L.H. Green, D.K.P. Ng, R.C. Tovey, A.N. Chernega: J. Chem. Soc., Dalton Trans. (1993), 3203.
71. E.F. Ashworth, J.C. Green, M.L.H. Green, J. Knight, R.B.A. Pardy, N.J. Wainwright: J. Chem. Soc., Dalton Trans. (1977), 1693.
72. M. Bochmann, M. Green, H.P. Kirsch, F.G.A. Stone: J. Chem. Soc., Dalton Trans. (1977), 714.
73. M. Bochmann, M. Cooke, M. Green, H.P. Kirsch, F.G.A. Stone, A.J. Welch: J. Chem. Soc., Chem. Commun. (1976), 381.
74. M.B. Hossain, D. van der Helm: Inorg. Chem. (1978), 17: 2893.
75. D. Astruc: Acc. Chem. Res. (2000), 33: 287.
76. H. Brunner, J. Klankermayer, M. Zabel: Eur. J. Inorg. Chem. (2002), 2494.
77. H. Brunner, J. Klankermeyer, M. Zabel: Organometallics (2002), 21: 5746.
78. J.C. Green, R.A. Grieves, J. Mason: J. Chem. Soc., Dalton Trans. (1986), 1313.
79. R.L. Beddoes, M.S. Elwell, F.E. Mabbs, E.J.L. McInnes, A. Roberts, M.F. Sarwar, M.W. Whiteley: J. Chem. Soc., Dalton Trans. (2000), 4669.
80. R.L. Beddoes, A. Roberts, M.W. Whiteley, E.J.L. McInnes: J. Chem. Soc., Dalton Trans. (1996), 4035.
81. D.A. Brown, J.C. Burns, C. Mock-Knoblauch, W.K. Glass: Organometallics (1997), 16: 139.
82. H. Adams, N.A. Bailey, D.G. Willett, M.J. Winter: J. Organomet. Chem. (1987), 333: 61.
83. M. Wieser, K. Sünkel, C. Robl, W. Beck: Chem. Ber. (1992), 125: 1369.
84. J.D. Dunitz, P. Pauling: Helv. Chim. Acta (1960), 43: 2188.
85. C. Couldwell, K. Prout: Acta Crystallogr., Ser. B (1978), 34: 2439.
86. N.W. Alcock: Acta Crystallogr., Ser. B (1977), 33: 2943.
87. R. Bowerbank, M. Green, H.P. Kirsch, A. Morteux, L.E. Smart, F.G.A. Stone: Chem. Commun. (1977), 245.
88. P.J. Fagan, M.D. Ward, J.C. Calabrese: J. Am. Chem. Soc. (1989), 111: 1698.
89. H.J. Dauben, L.R. Lewis, R. Honnen, K.M. Harmon: J. Org. Chem. (1960), 25: 1442.
90. E.A. Werner: J. Chem. Soc. (1919), 1093.
91. F. Arndt, H. Scholz: Angew. Chem. (1933), 46: 47.
92. P. Boudjouk, C.A. Kapfer: J. Organomet. Chem. (1985), 296: 339.
93. W. Strohmeier: Chem. Ber. (1961), 94: 3337.
94. R.H. Blessing: Acta Crystallogr., Ser. A (1995), 51: 33.
95. R.H. Blessing: J. Appl. Crystallogr. (1997), 30: 421.
96. SMART, Bruker AXS, Madison, WI, 2000.
97. G.M. Sheldrick, SHELXS-97, Program for solution of crystal structures, University of Göttingen, Germany, (1997)
98. G.M. Sheldrick: Acta Crystallogr., Ser. A (1990), 46: 467.
99. G.M. Sheldrick, SHELXL-97, Program for refinement of crystal structures, University of Göttingen, Germany, (1997)
100. M.N. Burnett and C.K. Johnson, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations, Report ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, TN, USA, (1996)
101. L.J. Farrugia, ORTEP-3, University of Glasgow, (1999)
102. R. Ahlrichs, M. Bär, H.-P. Baron, R. Bauernschmitt, S. Böcker, M. Ehrig, K. Eichkorn, S. Elliott, F. Furche, F. Haase, M. Häser, H. Horn, C. Huber, U. Huniar, M. Kattannek, C. Kölmel, M. Kollwitz, K. May, C. Ochsenfeld, H. Öhm, A. Schäfer, U. Schneider, O. Treutler, M. von Arnim, F. Weigend, P. Weis and H. Weiss, TURBOMOLE (ver. 5.3), Universität Karlsruhe, (2000)
103. A.D. Becke: Phys. Rev. A (1988), 38: 3098.
104. J.P. Perdew: Phys. Rev. B (1986), 33: 8822.
105. A. Schäfer, C. Huber, R. Ahlrichs: J. Chem. Phys. (1994), 100: 5829.
106. D. Andrae, U. Häussermann, M. Dolg, H. Stoll, H. Preuss: Theor. Chim. Acta (1990), 77: 123.