Lithium chloride-mediated stereoselective synthesis of cyclopropanecarboxamides from γ,δ-epoxy malonates through a domino cyclopropanation/lactonization/aminolysis process

Journal of Organic Chemistry

Volumn 79, Issue 10, 2014, Pages 4650-4658

  Marques, Marcelo V ^a   Sá, Marcus M ^a  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; ESTERS; FUNCTIONAL GROUPS; REACTION INTERMEDIATES; REACTION KINETICS; STEREOCHEMISTRY; STEREOSELECTIVITY;

COOPERATIVE CATALYSIS; CYCLOPROPANATION; DOMINO REACTIONS; MULTI-FUNCTIONALIZED; REACTION MECHANISM; STEREOGENIC CENTERS; STEREOSELECTIVE SYNTHESIS; SUBSTITUTION PATTERNS;

ORGANIC SOLVENTS;

AMIDE; CYCLOPROPANE DERIVATIVE; LACTONE; LITHIUM CHLORIDE; MALONIC ACID DERIVATIVE; AMINE; CYCLOPROPANECARBOXAMIDE; LEWIS ACID;

AMINOLYSIS; ARTICLE; ATOM; CATALYSIS; CYCLOPROPANATION; DIASTEREOISOMER; ENVIRONMENTAL TEMPERATURE; LACTONIZATION; RING OPENING; STEREOCHEMISTRY; SUBSTITUTION REACTION; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

AMIDES; AMINES; CATALYSIS; CYCLOPROPANES; LACTONES; LEWIS ACIDS; LITHIUM CHLORIDE; MALONATES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84900863940     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo500712t     Document Type: Article

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