A serendipitous one-step conversion of 3H-1,2-dithiole-3-thione to (E)-3-[1-(alkylthio)alkylidene]-3H-1,2-dithiole: An experimental and theoretical study

Molecular Diversity

Volumn 18, Issue 2, 2014, Pages 285-294

  Couto, Marcos ^a   Cabrera, Mauricio ^a   Echeverría, Gustavo A ^b   Piro, Oscar E ^b   González, Mercedes ^a   Cerecetto, Hugo ^a  

^a UNIVERSIDAD DE LA REPÚBLICA   (Uruguay)

^b Facultad de Ciencias Naturales e Instituto M Lillo   (Argentina)

Author keywords

(E) 3 Alkylidene 3 H 1, 2 dithiole; 3 H 1, 2 Dithiole 3 thione; DFT calculations; HSAB theory

Indexed keywords

1,2 DITHIOLE 3 THIONE DERIVATIVE; 3 ACYLMETHYLTHIO 5 (4 METHOXYPHENYL) 1,2 DITHIOLIUM IODIDE; 3 BENZOYLMETHYLTHIO 5 (4 METHOXYPHENYL) 1,2 DITHIOLIUM IODIDE; 3 [1 (ALKYLTHIO)ALKYLIDENE] 3H 1,2 DITHIOLE; 3H 1,2 DITHIOLE 3 THIONE; 5 (4 HYDROXYPHENYL) 3 [2 OXO 1 (2 OXO 2PHENYLETHYLTHIO) 2 PHENYLETHYLIDENE] 3H 1,2 DITHIOLE; 5 (4 METHOXYPHENYL) 3 [2 OXO 1 (2 OXO 2PHENYLETHYLTHIO) 2 PHENYLETHYLIDENE] 3H 1,2 DITHIOLE; 5 (4 METHOXYPHENYL) 3 [2 OXO 1 (2OXOPROPYLTHIO)PROPYLIDENE] 3H 1,2 DITHIOLE; 5 [4 (2 OXO 2 PHENYLETHYLOXY)PHENYL] 3H 1,2 DITHIOLE 3 THIONE; 5 [4 (2 OXOPROPYLOXY)PHENYL] 3 [2 OXO 1 (2OXOPROPYLTHIO)PROPYLIDENE] 3H 1,2 DITHIOLE; 5 [4 (2 OXOPROPYLOXY)PHENYL] 3H 1,2 DITHIOLE 3 THIONE; ANTINEOPLASTIC AGENT; ELECTROPHILE; NUCLEOPHILE; POTASSIUM IODIDE; THIOL DERIVATIVE; UNCLASSIFIED DRUG; 1,2-DITHIOL-3-THIONE; DITHIOL DERIVATIVE; THIOKETONE; THIOPHENE DERIVATIVE; TOLUENE;

ALKYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; DRUG SYNTHESIS; ELECTRON TRANSPORT; EXPERIMENTAL STUDY; MASS SPECTROMETRY; MICROWAVE COOKING; MICROWAVE IRRADIATION; NUCLEOPHILICITY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; THEORETICAL STUDY; X RAY DIFFRACTION; ANALOGS AND DERIVATIVES; CHEMICAL STRUCTURE; CHEMISTRY; CHEMOPROPHYLAXIS; CONFORMATION; QUANTUM THEORY;

CHEMOPREVENTION; MODELS, MOLECULAR; MOLECULAR CONFORMATION; QUANTUM THEORY; THIONES; THIOPHENES; TOLUENE;

EID: 84898792975     PISSN: 13811991     EISSN: 1573501X     Source Type: Journal    
DOI: 10.1007/s11030-013-9499-x     Document Type: Article

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