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Volumn 112, Issue 13, 2014, Pages

Continuous self-energy of ions at the dielectric interface

Author keywords

[No Author keywords available]

Indexed keywords

ATOMISTIC SIMULATIONS; CHARGE POLARIZATION; DIELECTRIC INTERFACE; INTRINSIC PARAMETERS; SPECIFIC ION EFFECTS; UNIFIED DESCRIPTION; WATER OIL INTERFACE; WATER-AIR INTERFACE;

EID: 84898080685     PISSN: 00319007     EISSN: 10797114     Source Type: Journal    
DOI: 10.1103/PhysRevLett.112.136101     Document Type: Article
Times cited : (38)

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    • For this large ion, the cavity energy is proportional to its surface area [20]: (Equation presented), where (Equation presented) and (Equation presented) are, respectively, the ion-water and ion-oil interfacial energy. We estimate (Equation presented) and (Equation presented) in two ways. Taking the ion as a cavity (vacuum), these two surface energies can be approximated by the surface tension of water (Equation presented) and the oil (1,2-dichloroethane [9]) (Equation presented). This yields (Equation presented). If we take the hydrophobic ion to be of the same material as the oil, then (Equation presented). (Equation presented), where (Equation presented) is the interfacial tension between water and 1,2-Dichloroethane [9]. This estimate gives (Equation presented).
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