Direct α-siladifluoromethylation of lithium enolates with ruppert-prakash reagent via Cï-F bond activation

Chemistry - A European Journal

Volumn 20, Issue 10, 2014, Pages 2750-2754

  Hashimoto, Ryota ^a   Iida, Toshiaki ^a   Aikawa, Kohsuke ^a   Ito, Shigekazu ^a   Mikami, Koichi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

C F activation; difluoromethylation; lithium enolate; Ruppert Prakash reagent; umpolung

Indexed keywords

CARBON; FLUORINE; OLEFINS; POSITIVE IONS;

DIFLUOROMETHYLATION; LITHIUM ENOLATES; QUATERNARY CARBON; RUPPERT-PRAKASH REAGENT; STRONG INTERACTION; TRIFLUOROMETHYL; TRIFLUOROMETHYLATION; UMPOLUNG;

LITHIUM;

EID: 84897663572     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201304473     Document Type: Article

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