Hydrogeochemical characterisation and modelling of groundwaters in a potential geological repository for spent nuclear fuel in crystalline rocks (Laxemar, Sweden)

Applied Geochemistry

Volumn 45, Issue , 2014, Pages 50-71

  Gimeno, María J ^a   Auqué, Luis F ^a   Acero, Patricia ^a,b   Gómez, Javier B ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b UNIVERSITY OF LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINITY; CHEMICAL SPECIATION; COMPUTER SIMULATION; GROUNDWATER; MIXING; QUARTZ; RADIOACTIVE WASTES; SALINE WATER;

DISEQUILIBRIUM STATE; DISSOLUTION/PRECIPITATION; GEOCHEMICAL EVOLUTION; GROUNDWATER CHEMISTRY; SWEDISH NUCLEAR FUEL AND WASTE MANAGEMENTS; THERMODYNAMIC SIMULATIONS; WATER ROCK INTERACTION PROCESS; WATER ROCK INTERACTIONS;

HYDROCHEMISTRY;

ADVECTION-DIFFUSION EQUATION; CRYSTALLINE ROCK; GROUNDWATER RESOURCE; HYDROGEOCHEMISTRY; HYDROLOGICAL MODELING; MIXING; NUCLEAR POWER; RADIOACTIVE WASTE; REPOSITORY; WATER-ROCK INTERACTION;

FORSMARK; KALMAR [SWEDEN]; LAXEMAR; SWEDEN; UPPSALA [SWEDEN];

EID: 84897411016     PISSN: 08832927     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apgeochem.2014.03.003     Document Type: Article

References (93)

1. Andersson J., Skagius K., Winberg A., Lindborg T., Ström A. Site-descriptive modelling for a final repository for spent nuclear fuel in Sweden. Environ. Earth Sci. 2013, 69:1045-1060.
2. Andrews J.N., Hussain N., Youngman M.J. Atmospheric and radiogenic gases in groundwaters from the Stripa granite. Geochim. Cosmochim. Acta 1989, 53:1831-1841.
3. Appelo C.A.J., Postma D. Geochemistry, Groundwater & Pollution 2005, Balkema, Rotterdam, The Netherlands, 649p. second ed.
4. Auqué, L.F., Gimeno, M.J., Gómez, J., Puigdomènech, I., Smellie, J., Tullborg, E.-L., 2006. Groundwater Chemistry around A Repository for Spent Nuclear Fuel over a Glacial Cycle Evaluation for SR-Can. SKB Technical Report TR-06-31, Svensk Kärnbränslehantering AB, Stockholm, Sweden, 123p.
5. Auqué L.F., Gimeno M.J., Gómez J., Nilsson A.-C. Potentiometrically measured Eh in groundwaters from the Scandinavian Shield. Appl. Geochem. 2008, 23:1820-1833.
6. Auqué L.F., Arenas C., Osácar C., Pardo G., Sancho C., Vázquez-Urbez M. Tufa sedimentation in changing hydrological conditions: the River Mesa (Spain). Geol. Acta 2012, 11:85-102.
7. Ball, J.W., Nordstrom, D.K., 2001. User's Manual for WATEQ4F, With Revised Thermodynamic Data Base and Test Cases for Calculating Speciation of Major, Trace, and Redox Elements in Natural Waters. U.S. Geological Survey. Open File, Report 91-183, USA.
8. Bath, A., Milodowski, A., Ruotsalainen, P., Tullborg, E.-L., Cortés Ruiz, A., Aranyossy, J.-F., 2000. Evidences from Mineralogy and Geochemistry for the Evolution of Groundwater Systems during the Quaternary for Use in Radioactive Waste Repository Safety Assessment (EQUIP project). European Commission Nuclear Sciece and Technology Series EUR 19613 EN. Luxembourg Office for Official Publications of the European Communities.
9. Bennett P.C., Hiebert F.K., Robert-Rogers J. Microbial control of mineral-groundwater equilibria: macroscale to microscale. Hydrogeol. J. 2000, 8:47-62.
10. Blomqvist, R., Ruskeeniemi, T., Kaija, J., Ahonen, L., Paananen, M., Smellie, J., Grundfelt, G., Pedersen, K., Bruno, J., Pérez del Villar, L., Cera, E., Rasilainen, K., Pitkänen, P., Suksi, J., Casanova, J., Read, D., Frape, S., 2000. The Palmottu Natural Analogue Project. Phase II: Transport of Radionuclides in a Natural Flow System. European Commission, Final Report. European Commission Nuclear Science and Technology Series EUR 19611 EN. Luxembourg: Office for Official Publications of the European, Communities, 174 p.
11. Burke I.T., Kemp A.E.S. Microfabric analysis of Mn-carbonate laminae deposition and Mn-sulfide formation in the Gotland Deep, Baltic Sea. Geochim. Cosmochim. Acta 2002, 66:1589-1600.
12. Carman R., Rahm L. Early diagenesis and chemical characteristics of interstitial waters and sediments in the deep deposition bottoms of the Baltic Proper. J. Sea Res. 1997, 37:25-47.
13. Clark I., Fritz P. Environmental Isotopes in Hydrogeology 1997, CRC Press LLC, 328p.
14. Dandurand J.L., Gout R., Hoefs J., Menschel G., Schott J., Usdowski E. Kinetically controlled variations of major components and carbon and oxygen isotopes in a calcite-precipitating spring. Chem. Geol. 1982, 36:299-315.
15. Deutsch W.J. Groundwater Geochemistry. Fundamentals and Applications to Contamination 1997, Lewis Publishers, New York, 221p.
16. Drake, H., Tullborg, E.-L., 2009a. Fracture Mineralogy. Laxemar. Site Descriptive Modeling. SDM-Site Laxemar. SKB Report R-08-99. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 226p.
17. Drake H., Tullborg E.-L. Paleohydrogeological events recorded by stable isotopes, fluid inclusions and trace elements in fracture minerals in crystalline rock, Simpevarp area, SE Sweden. Appl. Geochem. 2009, 24:715-732.
18. Drake H., Tullborg E.-L., Annersten H. Red-staining of the wall rock and its influence on the reducing capacity around water conducting fractures. Appl. Geochem. 2008, 23(7):1898-1920.
19. Drake H., Tullborg E.-L., MacKenzie A.B. Detecting the near-surface redox front in crystalline bedrock using fracture mineral distribution, geochemistry and U-series disequilibrium. Appl. Geochem. 2009, 24:1023-1039.
20. Drake H., Tullborg E.-L., Page L. Distinguishing multiple events of fracture mineralisations related to far-field orogenic effects in Paleoproterozoic crystalline rocks, Simpevarp area, SE Sweden. Lithos 2009, 110:37-49.
21. Drake H., Tullborg E.-L., Hogmalm J., Åström M. Trace metal distribution and isotope variations in low-temperature calcite and groundwater in granitoid fractures down to 1km depth. Geochim. Cosmochim. Acta 2012, 84:217-238.
22. Drake H., Åström M., Tullborg E.-L., Whitehouse M.J., Fallick A.E. Variability of sulphur isotope ratios in pyrite and dissolved sulphate in granitoid fractures down to 1km depth - evidence for widespread activity of sulphur reducing bacteria. Geochim. Cosmochim. Acta 2013, 102:143-161.
23. Drake H., Heim C., Hogmalm K.J., Hansen B.T. Fracture zone-scale variation of trace elements and stable isotopes in calcite in a crystalline rock setting. Appl. Geochem. 2014, 40:11-24.
24. Drysdale R.N., Taylor M.P., Ihlenfeld C. Factors controlling the chemical evolution of travertine-depositing rivers of the Barkly karst, northern Australia. Hydrol. Process. 2002, 16:2941-2962.
25. Follin S., Stephens M.B., Laaksoharju M., Nilsson A.-C., Smellie J.A.T., Tullborg E.-L. Modelling the evolution of hydrochemical conditions in the Fennoscandian Shield during Holocen time using multidisciplinary information. Appl. Geochem. 2008, 23:2004-2020.
26. Frape S.K., Fritz P. Geochemical trends for groundwaters from the Canadian Shield. Saline Water and Gases in Crystalline Rocks, Paper 33 1987, 19-38. Geological Association of Canada, Memorial University, Newfoundland. P. Fritz, S.K. Frape (Eds.).
27. Fritz P., Fontes J.-C.H., Frape S.K., Louvat D., Michelot J.-L., Balderer W. The isotope geochemistry of carbon in groundwater at Stripa. Geochim. Cosmochim. Acta 1989, 53:1765-1775.
28. Gascoyne M. Hydrogeochemistry, groundwater ages and sources of salts in a granitic batholith on the Canadian Shield, southeastern Manitoba. Appl. Geochem. 2004, 19:519-560.
29. Gimeno, M.J., Auqué, L.F., Gómez, J., 2006. Mass balance modelling. In: SKB (Ed.), Hydrogeochemical Evaluation. Preliminary Site Description. Laxemar Subarea, version 2.1. SKB Report R-06-70, Appendix 3. Svensk Kärnbränslehantering AB, Stockholm, Sweden, pp. 175-210.
30. Gimeno, M.J., Auqué, L.F., Gómez, J., Acero, P., 2008. Water-rock Interaction Modelling and Uncertainties of Mixing Modelling. SDM-Site Forsmark. SKB Report R-08-86. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 212p.
31. Gimeno, M.J., Auqué, L.F., Gómez, J., Acero, P., 2009. Water-rock Interaction Modelling and Uncertainties of Mixing Modelling. SDM-Site Laxemar. SKB Report R-08-110. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 372p.
32. Glynn, P.D., Voss, C.I., 1999. SITE-94. Geochemical Characterization of Simpevarp Ground Waters near the Äspö Hard Rock Laboratory. SKI Report 96-29. SKI, Stockholm, Sweden, 210p.
33. Gómez J.B., Gimeno M.J., Auqué L.F., Acero P. Characterisation and modelling of mixing processes in groundwaters of a potential Geological Repository for Nuclear Wastes in crystalline rocks of Sweden. Sci. Total Environ. 2014, 468-469:791-803.
34. Grimaud D., Beaucaire C., Michard G. Modelling of the evolution of ground waters in a granite system at low temperature: the Stripa ground waters, Sweden. Appl. Geochem. 1990, 5:515-525.
35. 0 in the range of 0 to 350°C at Psat. Geochim. Cosmochim. Acta 2000, 64:2295-2307.
36. Hallbeck, L., Pedersen, K., 2008a. Explorative Analysis of Microbes, Colloids and Gases. SDM-Site Laxemar. SKB Report R-08-109. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 72p.
37. Hallbeck L., Pedersen K. Characterization of microbial processes in deep aquifers of the Fennoscandian Shield. Appl. Geochem. 2008, 23:1796-1819.
38. Hedin, A., 1997. Spent Nuclear Fuel-How Dangerous is it? A Report from the Project "Description of risk". SKB Technical Report TR-97-13. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 60p.
39. Heim C., Lausmaa J., Sjövall P., Toporski J., Dieing T., Simon K., Hansen B.T., Kronz A., Arp G., Reitner J., Thiel V. Ancient microbial activity recorded in fracture fillings from granitic rocks (Äspö Hard Rock Laboratory, Sweden). Geobiology 2012, 10:280-297.
40. Helgeson H.C. Thermodynamics of hydrothermal systems at elevated temperatures. Am. J. Sci. 1969, 267:729-804.
41. Helgeson H.C., Delany J.M., Nesbitt H.W., Bird D.K. Summary and critique of thermodynamic properties of rock forming minerals. Am. J. Sci. 1978, 278-A.
42. Hunter F.M.I., Hartley L.J., Hoch A., Jackson C.P., McCarthy R., Marsic N., Gylling B. Calibration of regional palaeohydrogeology and sensitivity analysis using hydrochemistry data in site investigations. Appl. Geochem. 2008, 23:1982-2003.
43. Iwatsuki T., Furue R., Mie H., Ioka S., Mizuno T. Hydrochemical baseline condition of groundwater at the Mizunami underground research laboratory (MIU). Appl. Geochem. 2005, 20:2283-2302.
44. Jacobson R.L., Usdowski E. Geochemical controls on a calcite precipitating spring. Contrib. Mineral. Petrol. 1975, 51:65-74.
45. Kloppmann W., Girard J.-P., Négrel P. Exotic stable isotope compositions of saline waters and brines from the crystalline basement. Chem. Geol. 2002, 184:49-70.
46. Konhauser K. Introduction to Geomicrobiology 2007, 425p. Blackwell Publishing.
47. Laaksoharju, M., Wallin, B. (Eds.), 1997. Evolution of the groundwater chemistry at the Äspö Hard Rock Laboratory. In: Proceedings of the Second Äspö International Geochemistry Workshop. SKB 97-04. Svensk Kärnbränslehantering AB, Stockholm, Sweden. Äspö, Sweden, June 6-7, 1995.
48. Laaksoharju M., Tullborg E.-L., Wikberg P., Wallin B., Smellie J. Hydrogeochemical conditions and evolution at the Äspö HRL, Sweden. Appl. Geochem. 1999, 14:835-859.
49. Laaksoharju, M., Smellie, J., Tullborg, E.-L., Gimeno, M., Hallbeck, L., Molinero, J., Waber, N., 2008a. Bedrock Hydrogeochemistry, Forsmark. Site Descriptive Modelling. SDM-Site Forsmark. Svensk Kärnbränslehantering AB, Stockholm, Sweden. SKB Report R-08-47, 158p.
50. Laaksoharju M., Smellie J., Tullborg E.-L., Gimeno M., Molinero J., Gurban I., Hallbeck L. Hydrogeochemical evaluation and modelling performed within the Swedish site investigation programme. Appl. Geochem. 2008, 23:1761-1795.
51. Laaksoharju, M., Smellie, J., Tullborg, E.-L., Wallin, B., Drake, H., Gascoyne, M., Gimeno, M., Gurban, I., Hallbeck, L., Molinero, J., Nilsson, A.-C., Waber, N., 2009. Bedrock Hydrogeochemistry Laxemar. Site Descriptive Model, SDM-Site Laxemar. Svensk Kärnbränslehantering AB, Stockholm, Sweden. SKB Report R-08-93, 201p.
52. Langmuir D. Aqueous Environmental Geochemistry 1997, 600p. Prentice Hall.
53. Langmuir D., Melchior D. The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin, Texas. Geochim. Cosmochim. Acta 1985, 49:2423-2432.
54. Louvat D., Michelot J.L., Aranyossy J.F. Origin and residence time of salinity in the Äspö groundwater system. Appl. Geochem. 1999, 14:917-925.
55. Malusa J., Overby S.T., Parnell R.A. Potential for travertine formation: fossil Creek, Arizona. Appl. Geochem. 2003, 18:1081-1093.
56. Mathurin F.A., Åström M.E., Laaksoharju M., Kalinowski B.E., Tullborg E.-L. Effect of tunnel excavation on source and mixing of groundwater in a coastal granitoidic fracture network. Environ. Sci. Technol. 2012, 46:12779-12786.
57. Milodowski, A.E., Tullborg, E.-L., Buil, B., Gomez, P., Turrero, M.J., Haszeldine, S., England, G., Gillespie, M.R., Torres, T., Ortiz, J., Zacharias, E., Silar, J., Chvatal, M., Strand, L., Sebek, O., Bouch, J., Chenery, S.R., Chenery, C., Sheperd, T.J., Mc Kervey, J.A., 2005. Application of Mineralogical, Petrological and Geochemical Tools for Evaluating the Palaeohydrogeological Evolution of the PADAMOT Study Sites. PADAMOT Project Technical, Report WP2.
58. Molinero, J., Salas, J., Arcos, D., Duro, L., 2008. Integrated hydrogeological and geochemical modelling of the Laxemar-Simpevarp area during the recent Holocene (last 8000years). In: Kalinowski, B. (Ed.), Background Complementary Hydrogeochemical Studies. SKB Report R-08-111. Svensk Kärnbränslehantering AB, Stockholm, Sweden, pp. 47-78.
59. Nilsson, A.-C., 2009. Laxemar site investigation: quality of hydrochemical analyses (DF version 2.3). In: Kalinowski, B. (Ed.), Background Complementary Hydrogeochemical Studies. SKB Report R-08-111. Svensk Kärnbränslehantering AB, Stockholm, Sweden, pp. 131-148.
60. Nordstrom D.K., Ball J.W. Mineral saturation states in natural waters and their sensitivity to thermodynamic and analytical errors. Sci. Geol. Bull. 1989, 42:269-280.
61. Nordstrom, D.K., Andrews, J.N., Carlsson, L., Fontes, J.C., Fritz, P., Moser, H., Olsson, T., 1985. Hydrogeological and Hydrochemical Investigations in Boreholes. Final Report of the Phase I Geochemical Investigations of the Stripa Groundwaters. Stripa Project Technical Report 85-06. Svensk Kärnbränslehantering AB, Stockholm, Sweden.
62. Nordstrom D.K., Ball J.W., Donahoe R.J., Whittemore D. Groundwater chemistry and water-rock interactions at Stripa. Geochim. Cosmochim. Acta 1989, 53:1727-1740.
63. Parkhurst, D.L., Appelo, C.A.J., 1999. User's Guide to PHREEQC (Version 2), A Computer Program for Speciation, Batch-reaction, One-dimensional Transport, and Inverse Geochemical Calculations. Water Resources Research Investigations, Report 99-4259, 312p.
64. Pedersen K., Ekendahl S., Tullborg E.-L., Furnes H., Thorseth I.-G., Tumyr O. Evidence of ancient life at 207m depth in a granitic aquifer. Geology 1997, 25:827-830.
65. Pitkänen, P., Luukkonen, A., Ruotsalainen, P., Leino-Forsman, H., Vuorinen, U., 1999. Geochemical Modelling of Groundwater Evolution and Residence Time at the Olkiluoto Site. Posiva report 98-10. Posiva Oy, Eurajoki, Finland, 184p.
66. Pitkänen, P., Partamies, S., Luukkonen, A., 2004. Hydrogeochemical Interpretation of Baseline Groundwater Conditions at the Olkiluoto Site. Posiva report 2003-07. Posiva Oy, Eurajoki, Finland, 159p.
67. Plummer L.N., Busby J.F., Lee R.W., Hanshaw B.B. Geochemical modelling of the Madison Aquifer in parts of Montana, Wyoming and South Dakota. Water Resour. Res. 1990, 26:1981-2014.
68. Postma D.E., Larsen F., Thi Minh Hue N., Duc M.T., Hung Viet.P., Quy Nhan.P., Jessen S. Arsenic in groundwater of the Red River floodplain, Vietnam: controlling geochemical processes and reactive transport modeling. Geochim. Cosmochim. Acta 2007, 71:5054-5071.
69. Puigdomènech, I. (Ed.), 2001. Hydrochemical Stability of Groundwaters Surrounding a Spent Nuclear Fuel Repository in a 100,000year Perspective. SKB Technical Report TR-01-28. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 83p.
70. Rezaei M., Sanz E., Raeisi E., Ayora C., Vazquez-Sune E., Carrera J. Reactive transport modeling of calcite dissolution in the fresh-salt water mixing zone. J. Hydrol. 2005, 311(1-4):282-298.
71. Rhén, I., Hartley, L., 2009. Bedrock Hydrogeolology Laxemar. Site Descriptive Modelling SDM-Site Laxemar. SKB Report R-08-92. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 185p.
72. Rhén, I., Forsmark, T., Hartley, L., Jackson, P., Roberts, D., Swan, D., Gylling, B., 2008. Hydrogeological Conceptualisation and Parameterisation. Site Descriptive Modelling SDM-Site Laxemar. SKB Report R-08-78. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 306p.
73. Rhén, I., Forsmark, T., Hartley, L., Jackson, P., Roberts, D., Swan, D., Gylling, B., Marsic, N., 2009. Bedrock Hydrogeolology Model Testing and Synthesis. Site Descriptive Modelling SDM-Site Laxemar. SKB Report R-08-91. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 415p.
74. Rimstidt D.D. Quartz solubility at low temperatures. Geochim. Cosmochim. Acta 1997, 61:2553-2558.
75. Salas, J., Gimeno, M.J., Auqué, L., Molinero, J., Gómez, J., Juárez, I., 2011. SR-Site - Hydrogeochemical Evolution of the Forsmark Site. SKB Technical Report TR-10-58. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 172p.
76. Sandström B., Tullborg E.-L. Episodic fluid migration in the Fennoscandian Shield recorded by stable isotopes, rare earth elements and fluid inclusions in fracture minerals at Forsmark, Sweden. Chem. Geol. 2009, 266:135-151.
77. SKB, 2001. Site Investigations: Investigation Methods and General Execution Programme. SKB Technical Report TR-01-29. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 264p.
78. SKB, 2007. RD&D Programme 2007. Programme for Research, Development and Demonstration of Methods for the Management and Disposal of Nuclear Waste. SKB Technical Report TR-07-12. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 509p.
79. SKB, 2008. Site Description of Forsmark at Completion of the Site Investigation Phase. SDM-Site Forsmark. SKB Technical Report TR-08-05. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 545p.
80. SKB, 2009. Site Description of Laxemar at Completion of the Site Investigation Phase. SDM-Site Laxemar. SKB Technical Report TR-09-01. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 644p.
81. SKB, 2010. Geosphere Process Report for the Safety Assessment SR-Site. SKB Technical Report TR-10-48. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 276p.
82. Smellie, J., Tullborg, E.-L., 2009. Quality assurance and categorisation of groundwater samples from the Laxemar-Simpevarp area. In: Kalinowski (Ed.), Background Complementary Hydrogeochemical Studies. SKB Report R-08-111. Svensk Kärnbränslehantering AB, Stockholm, Sweden, pp. 163-347.
83. Smellie, J., Tullborg, E.-L., Nilsson, A.-C., Sandström, B., Waber, N., Gimeno, M., Gascoyne, M., 2008. Explorative Analysis of Major Components and Isotopes. SDM-Site Forsmark. SKB Report R-08-84. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 287p.
84. Stefánsson A. Dissolution of primary minerals of basalt in natural waters I. Calculation of mineral solubilities from 0°C to 350°C. Chem. Geol. 2001, 172:225-250.
85. Stenberg, L., Winberg, A., 2008. Geoscientific understanding of the Laxemar-Simpevarp site. In: Abstracts, 33rd International Geologial Congress, August 6-14, Oslo, Norway, 2008.
86. Ström A., Andersson J., Skagius K., Winberg A. Site descriptive modelling during characterization for a geological repository for nuclear waste in Sweden. Appl. Geochem. 2008, 23:1747-1760.
87. Suarez D.L. Calcite supersaturation and precipitation kinetics in lower Colorado River, All American canal and east highland canal. Water Resour. Res. 1983, 19:653-661.
88. Trotignon L., Beaucaire C., Louvat D., Aranyossy J.F. Equilibrium geochemical modelling of Äspö groundwaters: a sensitivity study of thermodynamic equilibrium constants. Appl. Geochem. 1999, 14:907-916.
89. Tullborg E.-L., Drake H., Sandstrom B. Palaeohydrogeology: a methodology based on fracture mineral studies. Appl. Geochem. 2008, 23(7):1881-1897.
90. Tullborg, E.-L., Smellie, J., Nilsson, A.-C., Gimeno, M.J., Auqué, L.F., Wallin, B., Brüchert, V., Molinero, J., 2010. SR-Site - Sulphide Content in the Groundwater at Laxemar. SKB Report R-10-62. Svensk Kärnbränslehantering AB, Stockholm, Sweden, 187p.
91. Waber H.N., Gimmi T., Smellie J.A.T. Reconstruction of palaeoinfiltration during the Holocene using porewater data (Laxemar, Sweden). Geochim. Cosmochim. Acta 2012, 94:109-127.
92. Wallin B., Peterman Z. Calcite fracture fillings as indicators of paleohydrology at Laxemar at the Äspö Hard Rock Laboratory, southern Sweden. Appl. Geochem. 1999, 14:953-962.
93. Wigley T.M.L., Plummer L.N. Mixing of carbonate waters. Geochim. Cosmochim. Acta 1976, 40:989-995.