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Formation of material of high polarity which we tentatively attributed to polymerization of the substrate was also observed under the reaction conditions. For iron-catalyzed polymerization of olefins
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We thank an anonymous reviewer for suggesting the experiment with 2e
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We thank an anonymous reviewer for suggesting the experiment with 2e.
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For a similar mechanistic hypothesis of a nickel-catalyzed reductive cyclization of 1,6-enynes, see: Chen, M.; Weng, Y.; Guo, M.; Zhang, H.; Lei, A. Angew. Chem., Int. Ed. 2008, 47, 2279-2282.
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The following aldehydes (3 equiv) were used as the electrophile: 4-trifluoromethylbenzaldehyde, 4-methoxybenzaldehyde, and hydrocinnamaldehyde
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The following aldehydes (3 equiv) were used as the electrophile: 4-trifluoromethylbenzaldehyde, 4-methoxybenzaldehyde, and hydrocinnamaldehyde.
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