Impact of pNIPAM microgel size on its ability to stabilize pickering emulsions

Langmuir

Volumn 30, Issue 7, 2014, Pages 1768-1777

  Destribats, Mathieu ^a,c   Eyharts, Mayalen ^a   Lapeyre, Véronique ^a   Sellier, Elisabeth ^a   Varga, Imre ^b   Ravaine, Valérie ^a   Schmitt, Véronique ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b EÖTVÖS LORÁND UNIVERSITY   (Hungary)

^c L ORÉAL RECHERCHE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC ACID RESIN; OIL; POLY N ISOPROPYLACRYLAMIDE; POLY-N-ISOPROPYLACRYLAMIDE; WATER;

ARTICLE; CHEMISTRY; EMULSION; GEL; PARTICLE SIZE; SURFACE PROPERTY;

ACRYLIC RESINS; EMULSIONS; GELS; OILS; PARTICLE SIZE; SURFACE PROPERTIES; WATER;

EID: 84894665177     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la4044396     Document Type: Article

References (48)

1. Pickering, S. U. CXCVI-Emulsions J. Chem. Soc., Trans. 1907, 91, 2001
2. Ramsden, W. Proc. R. Soc. 1903, 72, 156
3. Binks, B. P. Particles as Surfactants-Similarities and Differences Curr. Opin. Colloid Interface Sci. 2002, 7, 21
4. Leal-Calderon, F.; Schmitt, V. Solid-Stabilized Emulsions Curr. Opin. Colloid Interface Sci. 2008, 13, 217
5. Ngai, T.; Behrens, S. H.; Auweter, H. Novel Emulsions Stabilized By pH and Temperature Sensitive Microgels Chem. Commun. 2005, 331
6. Li, Z.; Ngai, T. Microgel Particles at The Fluid-Fluid Interfaces Nanoscale 2013, 5, 1399
7. Ngai, T.; Auweter, H.; Behrens, S. H. Environmental Responsiveness of Microgel Particles and Particle-Stabilized Emulsions Macromolecules 2006, 39, 8171
8. Geisel, K.; Isa, L.; Richtering, W. Unraveling The 3d Localization and Deformation of Responsive Microgels at Oil/Water Interfaces: A Step Forward in Understanding Soft Emulsion Stabilizers Langmuir 2012, 28, 15770
9. Richtering, W. Responsive Emulsions Stabilized by Stimuli-Sensitive Microgels: Emulsions with Special Non-Pickering Properties Langmuir 2012, 28, 17218
10. Brugger, B.; Rosen, B. A.; Richtering, W. Microgels as Stimuli-Responsive Stabilizers for Emulsions Langmuir 2008, 24, 12202
11. Brugger, B.; Richtering, W. Magnetic, Thermosensitive Microgels as Stimuli-Responsive Emulsifiers Allowing for Remote Control of Separability and Stability of Oil in Water-Emulsions Adv. Mater. 2007, 19, 2973
12. Schmidt, S.; Liu, T.; Rütten, S.; Phan, K.-H.; Moeller, M.; Richtering, W. Influence of Microgel Architecture and Oil Polarity on Stabilization of Emulsions by Stimuli-Sensitive Core-Shell Poly(N -isopropyl acrylamide- co -methacrylic acid) Microgels: Mickering versus Pickering Behavior? Langmuir 2011, 27, 9801
13. Brugger, B.; Richtering, W. Emulsions Stabilized by Stimuli-Sensitive Poly(N -isopropylacrylamide)- co -methacrylic Acid Polymers: Microgels Versus Low Molecular Weight Polymers Langmuir 2008, 24, 7769
14. Brugger, B.; Rütten, S.; Phan, K. H.; Möller, M.; Richtering, W. The Colloidal Suprastructure of Smart Microgels at Oil-Water Interfaces Angew. Chem., Int. Ed. 2009, 48, 3978
15. Tsuji, S.; Kawaguchi, H. Thermosensitive Pickering Emulsion Stabilized by Poly(N -isopropylacrylamide)-Carrying Particles Langmuir 2008, 24, 3300
16. Destribats, M.; Lapeyre, V.; Sellier, E.; Leal-Calderon, F.; Schmitt, V.; Ravaine, V. Water-In-Oil Emulsions Stabilized by Water-Dispersible Poly(N -isopropylacrylamide) Microgels: Understanding Anti-Finkle Behavior Langmuir 2011, 27, 14096
17. Destribats, M.; Lapeyre, V.; Wolfs, M.; Sellier, E.; Leal-Calderon, F.; Ravaine, V.; Schmitt, V. Soft Microgels as Pickering Emulsion Stabilisers: Role of Particle Deformability Soft Matter 2011, 7, 7689
18. Destribats, M.; Lapeyre, V.; Sellier, E.; Leal-Calderon, F.; Ravaine, V.; Schmitt, V. Origin and Control of Adhesion between Emulsion Drops Stabilized by Thermally Sensitive Soft Colloidal Particles Langmuir 2012, 28, 3744
19. Fujii, S.; Read, E. S.; Binks, B. P.; Armes, S. P. Stimulus-Responsive Emulsifiers Based on Nano-Composite Microgel Particles Adv. Mater. 2005, 17, 1014
20. Fujii, S.; Armes, S. P.; Binks, B. P.; Murakami, R. Stimulus-Responsive Particulate Emulsifiers Based on Lightly Cross-Linked Poly(4-vinylpyridine)- Silica Nanocomposite Microgels Langmuir 2006, 22, 6818
21. Nayak, S.; Lyon, L. A. Soft Nanotechnology with Soft Nanoparticles Angew. Chem., Int. Ed. 2005, 44, 7686
22. Pelton, R. Temperature-Sensitive Aqueous Microgels Adv. Colloid Interface Sci. 2000, 85, 1
23. Liu, R.; Fraylich, M.; Saunders, B. R. Thermoresponsive Copolymers: From Fundamental Studies to Applications Colloid Polym. Sci. 2009, 287, 627
24. Schmitt, V.; Ravaine, V. Surface Compaction Versus Stretching in Pickering Emulsions Stabilised by Microgels Curr. Opin. Colloid Interface Sci. 2013, 29, 12367
25. Sorrell, C. D.; Lyon, L. A. Deformation Controlled Assembly of Binary Microgel Thin Films Langmuir 2008, 24, 7216
26. Schmidt, S.; Motschmann, H.; Hellweg, T.; Von Klitzing, R. Thermoresponsive Surfaces By Spin-Coating of PNIPAM- co -PAA Microgels: A Combined AFM and Ellipsometry Study Polymer 2008, 49, 749
27. Horecha, M.; Senkovskyy, V.; Synytska, A.; Stamm, M.; Chervanyov, A. I.; Kiriy, A. Ordered Surface Structures from PNIPAM-Based Loosely Packed Microgel Particles Soft Matter 2010, 6, 5980
28. Brugger, B.; Vermant, J.; Richtering, W. Interfacial Layers of Stimuli-Responsive Poly(N -isopropylacrylamide- co -methacrylic acid) (PNIPAM- co -MAA) Microgels Characterized by Interfacial Rheology and Compression Isotherms Phys. Chem. Chem. Phys. 2010, 12, 14573
29. Pelton, R. H.; Chibante, P. Preparation of Aqueous Latices with N -Isopropylacrylamide Colloids Surf. 1986, 20, 247
30. Wu, X.; Pelton, R. H.; Hamielec, A. E.; Woods, D. R.; Mcphee, W. Kinetics of Poly(N -isopropylacrylamide) Microgel Latex Formation Colloid Polym. Sci. 1994, 272, 467
31. Acciaro, R.; Gilanyi, T.; Varga, I. Preparation of Monodisperse Poly(N -isopropylacrylamide) Microgel Particles with Homogenous Cross-Link Density Distribution Langmuir 2011, 27, 7917
32. Lele, A. K.; Hirve, M. M.; Badiger, M. V.; Mashelkar, R. A. Predictions of Bound Water Content in Poly(N -isopropylacrylamide) Gel Macromolecules 1997, 30, 157
33. Leal-Calderon, F.; Schmitt, V.; Bibette, J. Emulsion Science. Basic Principles, 2 nd ed.; Springer: New York, 2007.
34. Poulin, P.; Bibette, J. Wetting of Emulsions Droplets: From Macroscopic to Colloidal Scale Phys. Rev. Lett. 1997, 79, 3290
35. Aronson, M. P.; Princen, H. M. Contact Angles in Oil-in-Water Emulsions Stabilized By Ionic Surfactants Colloids Surf. 1982, 4, 173
36. Whitesides, T. H.; Ross, D. S. Experimental and Theoretical Analysis of the Limited Coalescence Process: Stepwise Limited Coalescence J. Colloid Interface Sci. 1995, 169, 48
37. Arditty, S.; Whitby, C. P.; Binks, B. P.; Schmitt, V.; Leal-Calderon, F. Some General Features of Limited Coalescence in Solid-Stabilized Emulsions Eur. Phys. J. E 2003, 11, 273
38. Arditty, S.; Schmitt, V.; Giermanska-Kahn, J.; Leal-Calderon, F. Materials Based on Solid-Stabilized Emulsions J. Colloid Interface Sci. 2004, 275, 659
39. Varga, I.; Gilanyi, T.; Meszaros, R.; Filipcsei, G.; Zrinyi, M. Effect of Cross-Link Density on the Internal Structure of Poly(N -isopropylacrylamide) Microgels J. Phys. Chem. B 2001, 105, 9071
40. Saunders, B. R. On the Structure of Poly(N -isopropylacrylamide) Microgel Particles Langmuir 2004, 20, 3925
41. Stieger, M.; Richtering, W.; Pedersen, J. S.; Lindner, P. Small-Angle Neutron Scattering Study of Structural Changes in Temperature Sensitive Microgel Colloids J. Chem. Phys. 2004, 120, 6197
42. Arleth, L.; Xia, X.; Hjelm, R. P.; Wu, J.; Zhibinc, H. U. Volume Transition and Internal Structures of Small Poly(N -isopropylacrylamide) Microgels J. Polym. Sci., Part B 2005, 43, 849
43. Andersson, M.; Maunu, S. L. Structural Studies of Poly(N -isopropylacrylamide) Microgels: Effect of SDS Surfactant Concentration in the Microgel Synthesis J. Polym. Sci., Part B 2006, 44, 3305
44. 2-PNIPAAM Core-Shell Particles at Interfaces Chem.-Eur. J. 2013, 19, 5586
45. Monteux, C.; Marliére, C.; Paris, P.; Pantoustier, N.; Sanson, N.; Perrin, P. Poly(N -isopropylacrylamide) Microgels at the Oil-Water Interface: Interfacial Properties as a Function of Temperature Langmuir 2010, 26, 13839
46. Poulin, P.; Bibette, J. Adhesion between Pure and Mixed Surfactant Layers Langmuir 1999, 15, 4731
47. Zhang, J.; Pelton, R. Poly(N -isopropylacrylamide) Microgels at the Air-Water Interface Langmuir 1999, 15, 8032
48. Destribats, M.; Wolfs, M.; Pinaud, F.; Lapeyre, V.; Sellier, E.; Ravaine, V.; Schmitt, V. Pickering Emulsions Stabilized by Soft Microgels: Influence of the Emulsification Process on Particle Interfacial Organization and Emulsion Properties Langmuir 2013, 29, 12367-12374