Pickering emulsions stabilized by soft microgels: Influence of the emulsification process on particle interfacial organization and emulsion properties

Langmuir

Volumn 29, Issue 40, 2013, Pages 12367-12374

  Destribats, Mathieu ^a,b   Wolfs, Mélanie ^a,c   Pinaud, Florent ^a   Lapeyre, Véronique ^a   Sellier, Elisabeth ^a   Schmitt, Véronique ^a   Ravaine, Valérie ^a  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b L ORÉAL RECHERCHE   (France)

^c UNIVERSITÉ CÔTE D'AZUR   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DENSE MONOLAYERS; EMULSIFICATION PROCESS; EMULSION PROPERTIES; END-USE PROPERTIES; INTERFACIAL ORGANIZATION; OIL WATER INTERFACES; PICKERING EMULSIONS; SURFACE COVERAGES;

CHEMICAL MODIFICATION; CROSSLINKING; EMULSIFICATION; EMULSIONS; PHASE INTERFACES; SHEAR DEFORMATION;

GELS;

EID: 84885417464     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la402921b     Document Type: Article

References (34)

1. Ramsden, W. Separation of solids in the surface-layers of solutions and 'suspensions' (observations on surface-membranes, bubbles, emulsions, and mechanical coagulation). - Preliminary account Proc. R. Soc. London 1903, 72, 156-164
2. Pickering, S. U. CXCVI.-Emulsions J. Chem. Soc., Trans. 1907, 91, 2001
3. Ngai, T.; Behrens, S. H.; Auweter, H. Novel emulsions stabilized by pH and temperature sensitive microgels Chem. Commun. 2005, 331
4. Ngai, T.; Auweter, H.; Behrens, S. H. Environmental responsiveness of microgel particles and particle-stabilized emulsions Macromolecules 2006, 39, 8171
5. Fujii, S.; Armes, S. P.; Binks, B. P.; Murakami, R. Stimulus-responsive particulate emulsifiers based on lightly cross-linked poly(4-vinylpyridine)- Silica nanocomposite microgels Langmuir 2006, 22, 6818
6. Fujii, S.; Read, E. S.; Binks, B. P.; Armes, S. P. Stimulus-responsive emulsifiers based on nanocomposite microgel particles Adv. Mater. (Weinheim, Ger.) 2005, 17, 1014
7. Brugger, B.; Rosen, B. A.; Richtering, W. Microgels as stimuli-responsive stabilizers for emulsions Langmuir 2008, 24, 12202
8. Schmidt, S.; Liu, T.; Rütten, S.; Phan, K.-H.; Moeller, M.; Richtering, W. Influence of microgel architecture and oil polarity on stabilization of emulsions by stimuli-sensitive core-shell poly(N-isopropyl acrylamide-co-methacrylic acid)/P(NiPAM-co-MAA) microgels: Mickering vs. Pickering behavior? Langmuir 2011, 27, 9801
9. Brugger, B.; Richtering, W. Emulsions stabilized by stimuli-sensitive poly(N-isopropylacrylamide)-co- methacrylic acid polymers: Microgels versus low molecular weight polymers Langmuir 2008, 24, 7769
10. Brugger, B.; Rütten, S.; Phan, K. H.; Möller, M.; Richtering, W. The colloidal suprastructure of smart microgels at oil-water interfaces Angew. Chem., Int. Ed. 2009, 48, 3978
11. Destribats, M.; Lapeyre, V.; Sellier, E.; Leal-Calderon, F.; Schmitt, V.; Ravaine, V. Water-in-oil emulsions stabilized by water-dispersible poly(N-isopropylacrylamide) microgels: Understanding anti-Finkle behavior Langmuir 2011, 27, 14096-14107
12. Destribats, M.; Lapeyre, V.; Wolfs, M.; Sellier, E.; Leal-Calderon, F.; Ravaine, V.; Schmitt, V. Soft microgels as Pickering emulsion stabilisers: role of particle deformability Soft Matter 2011, 7, 7689-7698
13. Destribats, M.; Lapeyre, V.; Sellier, E.; Leal-Calderon, F.; Ravaine, V.; Schmitt, V. Origin and control of adhesion between emulsion drops stabilized by thermally sensitive soft colloidal particles Langmuir 2012, 28, 3744-3755
14. Tsuji, S.; Kawaguchi, H. Thermosensitive pickering emulsion stabilized by poly(N- isopropylacrylamide)-carrying particles Langmuir 2008, 24, 3300
15. Pelton, R. Temperature-sensitive aqueous microgels Adv. Colloid Interface Sci. 2000, 85, 1
16. Binks, B. P. Particles as surfactants-Similarities and differences Curr. Opin. Colloid Interface Sci. 2002, 7, 21
17. Leal-Calderon, F.; Schmitt, V. Solid-stabilized emulsions Curr. Opin. Colloid Interface Sci. 2008, 13, 217
18. Brugger, B.; Vermant, J.; Richtering, W. Interfacial layers of stimuli-responsive poly-(N-isopropylacrylamide-co-methacrylicacid) (PNIPAM-co-MAA) microgels characterized by interfacial rheology and compression isotherms Phys. Chem. Chem. Phys. 2010, 12, 14573-14578
19. Monteux, C.; Marliére, C.; Paris, P.; Pantoustier, N.; Sanson, N.; Perrin, P. Poly(N-isopropylacrylamide) microgels at the oil-water interface: Interfacial properties as a function of temperature Langmuir 2010, 26, 13839-13846
20. Wu, X.; Pelton, R. H.; Hamielec, A. E.; Woods, D. R.; McPhee, W. Kinetics of poly(N-isopropylacrylamide) microgel latex formation Colloid Polym. Sci. 1994, 272, 467
21. Pelton, R. H.; Chibante, P. Preparation of aqueous lattices with N-isopropylacrylamide Colloids Surf. 1986, 20, 247
22. Lele, A. K.; Hirve, M. M.; Badiger, M. V.; Mashelkar, R. A. Predictions of bound water content in poly(N-isopropylacrylamide) gel Macromolecules 1997, 30, 157
23. Arditty, S.; Schmitt, V.; Giermanska-Kahn, J.; Leal-Calderon, F. Materials based on solid-stabilized emulsions J. Colloid Interface Sci. 2004, 275, 659
24. The CRC Handbook of Chemistry and Physics; Lide, D. R, Ed.; CRC Press: Boca Raton, FL, 1994; Vol. 124.
25. Suzuki, H.; Wang, B.; Yoshida, R.; Kokufuta, E. Potentiometric titration behaviors of a polymer and gel consisting of N-isopropylacrylamide and acrylic acid Langmuir 1999, 15, 4283-4288
26. Kratz, K.; Hellweg, T.; Eimer, W. Influence of charge density on the swelling of colloidal poly(N-isopropylacrylamide-co-acrylic acid) microgels Colloids Surf., A 2000, 170, 137-149
27. McPhee, W.; Tam, K. C.; Pelton, R. Poly(N-isopropylacrylamide) latices prepared with sodium dodecyl sulfate J. Colloid Interface Sci. 1993, 156, 24-30
28. Geisel, K.; Isa, L.; Richtering, W. Unraveling the 3D localization and deformation of responsive microgels at oil/water interfaces: A step forward in understanding soft emulsion stabilizers Langmuir 2012, 28, 15770-15776
29. Zhang, J.; Pelton, R. Poly(N-isopropylacrylamide) microgels at the air-water interface Langmuir 1999, 15, 8032-8036
30. Destribats, M.; Lapeyre, V.; Sellier, E.; Eyhart, M.; Ravaine, V.; Schmitt, V. Impact of pNIPAM microgel size on their ability to stabilize thermally-sensitive emulsions. Manuscript in preparation.
31. Suzuki, D.; Tsuji, S.; Kawaguchi, H. Janus microgels prepared by surfactant-free Pickering emulsion-based modification and their self-assembly J. Am. Chem. Soc. 2007, 129, 8088-+
32. Umeda, Y.; Kobayashi, T.; Hirai, T.; Suzuki, D. Effects of pH and temperature on assembly of multiresponsive Janus microgels Colloid Polym. Sci. 2011, 289, 729-737
33. Hong, L.; Jiang, S.; Granick, S. Simple method to produce Janus colloidal particles in large quantity Langmuir 2006, 22, 9495-9499
34. Perro, A.; Meunier, F.; Schmitt, V.; Ravaine, S. Production of large quantities of ″Janus″ nanoparticles using wax-in-water emulsions Colloids Surf., A 2009, 332, 57-62