Fluorination of graphene: A Spectroscopic and microscopic study

ACS Nano

Volumn 8, Issue 2, 2014, Pages 1862-1870

  Wang, Bei ^a   Wang, Junjie ^a   Zhu, Jun ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

charge transport; chemical vapor deposition; conductive AFM; fluorographene; graphene fluoride; XPS

Indexed keywords

EID: 84894619018     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn406333f     Document Type: Article

References (43)

1. Zhu, Y. W.; Murali, S.; Cai, W. W.; Li, X. S.; Suk, J. W.; Potts, J. R.; Ruoff, R. S. Graphene and Graphene Oxide: Synthesis, Properties, and Applications Adv. Mater. 2010, 22, 3906-3924
2. Sofo, J. O.; Chaudhari, A. S.; Barber, G. D. Graphane: A Two-Dimensional Hydrocarbon Phys. Rev. B 2007, 75, 153401
3. Charlier, J. C.; Gonze, X.; Michenaud, J. P. First-Principles Study of Graphite Monofluoride (CF) n Phys. Rev. B 1993, 47, 16162
4. Klintenberg, M.; Lebegue, S.; Katsnelson, M. I.; Eriksson, O. Theoretical Analysis of the Chemical Bonding and Electronic Structure of Graphene Interacting with Group IA and Group VIIA Elements Phys. Rev. B 2010, 81, 085433
5. Leenaerts, O.; Peelaers, H.; Hernandez-Nieves, A.; Partoens, B.; Peeters, F. First-Principles Investigation of Graphene Fluoride and Graphane Phys. Rev. B 2010, 82, 195436
6. Robinson, J. T.; Burgess, J. S.; Junkermeier, C. E.; Badescu, S. C.; Reinecke, T. L.; Perkins, F. K.; Zalalutdniov, M. K.; Baldwin, J. W.; Culbertson, J. C.; Sheehan, P. E. et al. Properties of Fluorinated Graphene Films Nano Lett. 2010, 10, 3001-3005
7. Kita, Y.; Watanabe, N.; Fujii, Y. Chemical Composition and Crystal Structure of Graphite Fluoride J. Am. Chem. Soc. 1979, 101, 3832-3841
8. Touhara, H.; Okino, F. Property Control of Carbon Materials by Fluorination Carbon 2000, 38, 241-267
9. Cheng, S. H.; Zou, K.; Okino, F.; Gutierrez, H.; Gupta, A.; Shen, N.; Eklund, P.; Sofo, J.; Zhu, J. Reversible Fluorination of Graphene: Evidence of a Two-Dimensional Wide Bandgap Semiconductor Phys. Rev. B 2010, 81, 205435
10. Nair, R. R.; Ren, W. C.; Jalil, R.; Riaz, I.; Kravets, V. G.; Britnell, L.; Blake, P.; Schedin, F.; Mayorov, A. S.; Yuan, S. J. et al. Fluorographene: A Two-Dimensional Counterpart of Teflon Small 2010, 6, 2877-2884
11. Withers, F.; Russo, S.; Dubois, M.; Craciun, M. Tuning the Electronic Transport Properties of Graphene through Functionalisation with Fluorine Nanoscale Res. Lett. 2011, 6, 526
12. Martins, S.; Withers, F.; Dubois, M.; Craciun, M. F.; Russo, S. Tuning the Transport Gap of Functionalized Graphene via Electron Beam Irradiation New J. Phys. 2013, 15, 033024
13. Withers, F.; Dubois, M.; Savchenko, A. K. Electron Properties of Fluorinated Single-Layer Graphene Transistors Phys. Rev. B 2010, 82, 073403
14. Withers, F.; Bointon, T. H.; Dubois, M.; Russo, S.; Craciun, M. F. Nanopatterning of Fluorinated Graphene by Electron Beam Irradiation Nano Lett. 2011, 11, 3912-3916
15. Roche, S.; Leconte, N.; Ortmann, F.; Lherbier, A.; Soriano, D.; Charlier, J.-C. QuantumTransport in Disordered Graphene: A Theoretical Perspective Solid State Commun. 2012, 152, 1404-1410
16. Jeon, K.-J.; Lee, Z.; Pollak, E.; Moreschini, L.; Bostwick, A.; Park, C.-M.; Mendelsberg, R.; Radmilovic, V.; Kostecki, R.; Richardson, T. J. et al. Fluorographene: A Wide Bandgap Semiconductor with Ultraviolet Luminescence ACS Nano 2011, 5, 1042-1046
17. Wang, B.; Sparks, J. R.; Gutierrez, H. R.; Okino, F.; Hao, Q.; Tang, Y.; Crespi, V. H.; Sofo, J. O.; Zhu, J. Photoluminescence from Nanocrystalline Graphite Monofluoride Appl. Phys. Lett. 2010, 97, 141915
18. Li, X. S.; Cai, W. W.; An, J. H.; Kim, S.; Nah, J.; Yang, D. X.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E. et al. Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Science 2009, 324, 1312-1314
19. Huang, P. Y.; Ruiz-Vargas, C. S.; van der Zande, A. M.; Whitney, W. S.; Levendorf, M. P.; Kevek, J. W.; Garg, S.; Alden, J. S.; Hustedt, C. J.; Zhu, Y. et al. Grains and Grain Boundaries in Single-Layer Graphene Atomic Patchwork Quilts Nature 2011, 469, 389-393
20. Kim, K.; Lee, Z.; Regan, W.; Kisielowski, C.; Crommie, M. F.; Zettl, A. Grain Boundary Mapping in Polycrystalline Graphene ACS Nano 2011, 5, 2142-2146
21. Shen, N.; Sofo, J. O. Dispersion of Edge States and Quantum Confinement of Electrons in Graphene Channels Drawn on Graphene Fluoride Phys. Rev. B 2011, 83, 245424
22. 4 Plasma J. Appl. Phys. 2008, 104, 113529
23. Hong, X.; Cheng, S. H.; Herding, C.; Zhu, J. Colossal Negative Magnetoresistance in Dilute Fluorinated Graphene Phys. Rev. B 2011, 83, 085410
24. Hong, X.; Zou, K.; Wang, B.; Cheng, S. H.; Zhu, J. Evidence for Spin-Flip Scattering and Local Moments in Dilute Fluorinated Graphene Phys. Rev. Lett. 2012, 108, 226602
25. Ferrari, A.; Robertson, J. Interpretation of Raman Spectra of Disordered and Amorphous Carbon Phys. Rev. B 2000, 61, 14095-14107
26. Lucchese, M. M.; Stavale, F.; Ferreira, E. H. M.; Vilani, C.; Moutinho, M. V. O.; Capaz, R. B.; Achete, C. A.; Jorio, A. Quantifying Ion-Induced Defects and Raman Relaxation Length in Graphene Carbon 2010, 48, 1592-1597
27. Prasai, D.; Tuberquia, J. C.; Harl, R. R.; Jennings, G. K.; Bolotin, K. I. Graphene: Corrosion-Inhibiting Coating ACS Nano 2012, 6, 1102-1108
28. Bittencourt, C.; Van Lier, G.; Ke, X.; Suarez-Martinez, I.; Felten, A.; Ghijsen, J.; Van Tendeloo, G.; Ewels, C. Spectroscopy and Defect Identification for Fluorinated Carbon Nanotubes ChemPhysChem 2009, 10, 920-925
29. Tressaud, A.; Durand, E.; Labrugre, C.; Kharitonov, A. P.; Kharitonova, L. N. Modification of Surface Properties of Carbon-Based and Polymeric Materials through Fluorination Routes: From Fundamental Research to Industrial Applications J. Fluorine Chem. 2007, 128, 378-391
30. Nanse, G.; Papirer, E.; Fioux, P.; Moguet, F.; Tressaud, A. Fluorination of Carbon Blacks: An X-ray Photoelectron Spectroscopy Study 0.1. A Literature Review of XPS Studies of Fluorinated Carbons. XPS Investigation of Some Reference Compounds Carbon 1997, 35, 175-194
31. Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.; Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Synthesis of Graphene-Based Nanosheets via Chemical Reduction of Exfoliated Graphite Oxide Carbon 2007, 45, 1558-1565
32. Dreyer, D. R.; Park, S.; Bielawski, C. W.; Ruoff, R. S. The Chemistry of Graphene Oxide Chem. Soc. Rev. 2010, 39, 228-240
33. 2 Phys. Rev. B 2001, 63, 115409
34. Li, X.; Magnuson, C. W.; Venugopal, A.; Tromp, R. M.; Hannon, J. B.; Vogel, E. M.; Colombo, L.; Ruoff, R. S. Large-Area Graphene Single Crystals Grown by Low-Pressure Chemical Vapor Deposition of Methane on Copper J. Am. Chem. Soc. 2011, 133, 2816-2819
35. Wood, J. D.; Schmucker, S. W.; Raasch, R. T.; Doidge, G. P.; Nienhaus, L.; Damhorst, G. L.; Lyons, A. S.; Gruebele, M.; Bashir, R.; Pop, E.; Lyding, J. W. Improved Graphene Growth and Fluorination on Cu with Clean Transfer to Surfaces, 12th IEEE Conference on Nanotechnology, 2012.
36. Ni, G. X.; Zheng, Y.; Bae, S.; Kim, H. R.; Pachoud, A.; Kim, Y. S.; Tan, C. L.; Im, D.; Ahn, J. H.; Hong, B. H. Quasi-Periodic Nanoripples in Graphene Grown by Chemical Vapor Deposition and Its Impact on Charge Transport ACS Nano 2012, 6, 1158-1164
37. Zhang, W.; Dubois, M.; Guerin, K.; Bonnet, P.; Kharbache, H. Effect of Curvature on C-F Bonding in Fluorinated Carbons: From Fullerene and Derivatives to Graphite Phys. Chem. Chem. Phys. 2010, 12, 1388-1398
38. Vlassiouk, I.; Regmi, M.; Fulvio, P.; Dai, S.; Datskos, P.; Eres, G.; Smirnov, S. Role of Hydrogen in Chemical Vapor Deposition Growth of Large Single-Crystal Graphene ACS Nano 2011, 5, 6069-6076
39. Han, Z.; Kimouche, A.; Allain, A.; Arjmandi-Tash, H.; Reserbat-Plantey, A.; Pairis, S.; Reita, V.; Bendiab, N.; Coraux, J.; Bouchiat, V. Suppression of Multilayer Graphene Patches during CVD Graphene Growth on Copper. arXiv:1205.1337 2012.
40. Kang, J.; Shin, D.; Bae, S.; Hong, B. Graphene Transfer: Key for Applications Nanoscale 2012, 4, 5527-5537
41. Britnell, L.; Gorbachev, R.; Jalil, R.; Belle, B.; Schedin, F.; Mishchenko, A.; Georgiou, T.; Katsnelson, M.; Eaves, L.; Morozov, S. Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures Science 2012, 335, 947-950
42. http://www.casaxps.com/.
43. Mak, K. F.; Sfeir, M. Y.; Wu, Y.; Lui, C. H.; Misewich, J. A.; Heinz, T. F. Measurement of the Optical Conductivity of Graphene Phys. Rev. Lett. 2008, 101, 196405