The alkaline hydrolysis of sulfonate esters: Challenges in interpreting experimental and theoretical data

Journal of Organic Chemistry

Volumn 79, Issue 7, 2014, Pages 2816-2828

  Duarte, Fernanda ^a   Geng, Ting ^a   Marloie, Gaël ^a   Al Hussain, Adel O ^b   Williams, Nicholas H ^b   Kamerlin, Shina Caroline Lynn ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; ESTERIFICATION; ESTERS; HYDROLYSIS;

ALKALINE HYDROLYSIS; COMPUTATIONAL STUDIES; CONCERTED MECHANISM; EXPERIMENTAL EVIDENCE; HAMMETT CORRELATION; LINEAR CORRELATION; N-METHYLPYRIDINIUM; THERMODYNAMICALLY STABLE;

BROMINE COMPOUNDS;

NUCLEOPHILE; PYRIDINIUM DERIVATIVE; SULFONIC ACID DERIVATIVE; 1-METHYLPYRIDINIUM; ALKALOID; AMINE OXIDE; BENZENESULFONIC ACID DERIVATIVE; ESTER; MESYLIC ACID DERIVATIVE; PYRIDINE DERIVATIVE; PYRIDINE-3-YL BENZENE SULFONATE;

ARTICLE; CONFORMATIONAL TRANSITION; CONTROLLED STUDY; DECOMPOSITION; ENERGY; GEOMETRY; HYDROLYSIS; REACTION ANALYSIS; SURFACE PROPERTY; THEORETICAL STUDY; THERMODYNAMICS; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; THEORETICAL MODEL;

ALKALOIDS; BENZENESULFONATES; CYCLIC N-OXIDES; ESTERS; HYDROLYSIS; KINETICS; MESYLATES; MODELS, THEORETICAL; MOLECULAR STRUCTURE; PYRIDINES; PYRIDINIUM COMPOUNDS;

EID: 84893835841     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo402420t     Document Type: Article

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