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Volumn 2014, Issue 6, 2014, Pages 1327-1332

TBu3P-coordinated 2-phenylaniline-based palladacycle complexes as precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes by a C-H activation strategy

Author keywords

C C coupling; C H activation; Fluorine; Metallacycles; Palladium; Synthetic methods

Indexed keywords


EID: 84893834360     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201301272     Document Type: Article
Times cited : (23)

References (72)
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    • Precatalyst 1a was also found to be efficient for the room temperature cross-coupling reactions of arylboronic acids with 4-chlorobenzophenone and 4-chloroacetophenone (1 mol-% 1a, room temp., 8 h): 89 % yield for the reaction of phenylboronic acid with 4-chlorobenzophenone, 92 % yield for phenylboronic acid with 4-chloroacetophenone, 97 % yield for 2-methylphenylboronic acid with 4-chlorobenzophenone, 99 % yield for 2-methylphenylboronic acid with 4-chloroacetophenone, and 80 % yield for 4-methylphenylboronic acid with 4-chlorobenzophenone
    • Precatalyst 1a was also found to be efficient for the room temperature cross-coupling reactions of arylboronic acids with 4-chlorobenzophenone and 4-chloroacetophenone (1 mol-% 1a, room temp., 8 h): 89 % yield for the reaction of phenylboronic acid with 4-chlorobenzophenone, 92 % yield for phenylboronic acid with 4-chloroacetophenone, 97 % yield for 2-methylphenylboronic acid with 4-chlorobenzophenone, 99 % yield for 2-methylphenylboronic acid with 4-chloroacetophenone, and 80 % yield for 4-methylphenylboronic acid with 4-chlorobenzophenone.
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    • For recent reports on such polymerization, see
    • For recent reports on such polymerization, see


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.