Mechanism, reactivity, and selectivity in palladium-catalyzed redox-relay heck arylations of alkenyl alcohols

Journal of the American Chemical Society

Volumn 136, Issue 5, 2014, Pages 1960-1967

  Xu, Liping ^a   Hilton, Margaret J ^b   Zhang, Xinhao ^a   Norrby, Per Ola ^c,d   Wu, Yun Dong ^a   Sigman, Matthew S ^b   Wiest, Olaf ^a,e  

^a PEKING UNIVERSITY   (China)

^b UNIVERSITY OF UTAH   (United States)

^c UNIVERSITY OF GOTHENBURG   (Sweden)

^d ASTRAZENECA R AND D   (Sweden)

^e UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; ENANTIOSELECTIVITY; HYDROCARBONS; ISOMERS; PALLADIUM; POTENTIAL ENERGY; QUANTUM CHEMISTRY;

CARBONYL-GROUP TRANSFORMATIONS; CHIRAL BUILDING BLOCKS; COMPUTATIONAL PREDICTIONS; MIGRATORY INSERTION; QUANTITATIVE AGREEMENT; RELATIVE REACTIVITIES; THERMODYNAMIC SINKS; UNSATURATED ALCOHOLS;

CATALYSIS;

ALCOHOL; ALKENE; ALKENYL GROUP; CARBONYL DERIVATIVE; PALLADIUM;

ARTICLE; ARYLATION; CALCULATION; CATALYSIS; CHEMICAL REACTION KINETICS; DENSITY FUNCTIONAL THEORY; DIPOLE; ELECTRIC POTENTIAL; ELECTRONICS; ENANTIOSELECTIVITY; HECK REACTION; ISOMER; POLARIZATION; PREDICTION; REACTION ANALYSIS; REDOX STRESS;

ALCOHOLS; ALKENES; CATALYSIS; CHEMISTRY TECHNIQUES, SYNTHETIC; MODELS, CHEMICAL; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM; STEREOISOMERISM;

EID: 84893790795     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4109616     Document Type: Article

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