An unusual example of hypervalent silicon: A five-coordinate silyl group bridging two palladium or nickel centers through a nonsymmetrical four-center two-electron bond

Angewandte Chemie - International Edition

Volumn 53, Issue 4, 2014, Pages 1103-1108

  Nova, Ainara ^a,b   Suh, Hee Won ^c   Schmeier, Timothy J ^c   Guard, Louise M ^c   Eisenstein, Odile ^a,d   Hazari, Nilay ^c   Maseras, Feliu ^b,e  

^a UNIVERSITY OF OSLO   (Norway)

^b INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^c YALE UNIVERSITY   (United States)

^d UNIVERSITÉ DE MONTPELLIER   (France)

^e UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

electronic structure; four center two electron bonds; hypervalent silicon; nickel; palladium

Indexed keywords

CRYSTALLOGRAPHIC CHARACTERIZATION; DFT CALCULATION; HYPERVALENT SILICON; METAL CENTERS; NATURAL BOND ORBITAL ANALYSIS; NBO ANALYSIS; SILYL GROUP; SQUARE-PYRAMIDAL GEOMETRY;

ATOMS; ELECTRONIC STRUCTURE; ELECTRONS; GEOMETRY; LIGANDS; NICKEL; PALLADIUM; PHOSPHORUS COMPOUNDS;

SILICON;

EID: 84893292711     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201307618     Document Type: Article

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