Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones

Journal of the American Chemical Society

Volumn 136, Issue 1, 2014, Pages 377-382

  Chen, Wenyong ^a   Hartwig, John F ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC SUBSTITUTION; CATION EFFECTS; DIASTEREO-SELECTIVITY; ENANTIOSELECTIVE; HYDROXY ACIDS; IRIDIUM COMPLEX; MAGNESIUM ENOLATES; TERTIARY ALCOHOLS;

CATALYSIS; ENANTIOSELECTIVITY; IRIDIUM; IRIDIUM COMPOUNDS; OLEFINS; POSITIVE IONS; STEREOSELECTIVITY; SUBSTITUTION REACTIONS;

ALLYLATION;

2 HYDROXYACID; ALCOHOL DERIVATIVE; ALLYL COMPOUND; CATION; IRIDIUM COMPLEX; MAGNESIUM; OXAZOLE DERIVATIVE; SULFIDE; THIAZOLE DERIVATIVE; ZINC;

ALLYLATION; ARTICLE; CATALYSIS; CHEMICAL PARAMETERS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONTROLLED STUDY; ENANTIOSELECTIVITY; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS;

ALCOHOLS; ALLYL COMPOUNDS; CATIONS; COORDINATION COMPLEXES; CYCLIZATION; IRIDIUM; MOLECULAR STRUCTURE; OXAZOLONE; STEREOISOMERISM; SULFIDES; TERT-BUTYL ALCOHOL; THIAZOLES;

EID: 84892179484     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja410650e     Document Type: Article

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