Synthesis and structural characterisation of a magnesium bisenolate: A tetrameric (Mg2O2)2 chain terminated by solvating ketone

Chemical Communications

Volumn , Issue 12, 2000, Pages 1059-1060

  Allan, John F ^a   Henderson, Kenneth W ^a   Kennedy, Alan R ^a   Teat, Simon J ^b  

^a UNIVERSITY OF STRATHCLYDE   (United Kingdom)

^b DARESBURY LABORATORY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

KETONE; MAGNESIUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; MOLECULAR INTERACTION; SOLVATION; SYNTHESIS; UNITED KINGDOM;

EID: 0034697842     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b002892o     Document Type: Article

References (15)

1. H. B. Mekelburger and C. S. Wilcox, in Comprehensive Organic Synthesis, ed. B. M. Trost and I. Fleming, Pergamon, Oxford, 1991, vol. 3, ch. 14.
2. (a) J. F. Allan, K. W. Henderson and A. R. Kennedy, Abstracts ACS, 1999, ORGN 126;
3. (b) J. F. Allan, K. W. Henderson and A. R. Kennedy, unpublished results;
4. (c) G. Lessène, R. Tripoli, P. Cazeau, C. Biran and M. Bordeau, Tetrahedron Lett., 1999, 40, 4037.
5. J. F. Allan, K. W. Henderson and A. R. Kennedy, Chem. Commun., 1999, 1325.
6. K. W. Henderson, W. J. Kerr and J. H. Moir, Chem. Commun., 2000, 479.
7. An aluminium enolate derived from 2 has been structurally characterised and its formation investigated by theoretical calculations: J. F. Allan, W. Clegg, M. R. J. Elsegood, K. W. Henderson, A. E. McKeown, P. H. Moran and I. M. Rakov, J. Organomet. Chem., 2000, in press.
8. For a review on the solid-state structures of organomagnesium compounds, see: P. R. Markies, O. S. Akkerman, F. Bickelhaupt, W. J. J. Smeets and A. L. Spek, Adv. Organomet. Chem., 1991, 32, 147.
9. P. R. Markies, G. Schat, O. S. Akkerman, F. Bickelhaupt, W. J. J. Smeets, P. van der Sluis and A. L. Spek, J. Organomet. Chem., 1990, 315, 393.
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13. A pinacolone-solvated lithium enolate derived from 2 has been reported but not fully characterised: R. Amstutz, W. B. Schweizer, D. Seebach and J. Dunitz, Helv. Chim. Acta, 1981, 64, 2617; a pinacolone solvated sodium pinacolate has been structurally characterised: P. G. Williard and G. B. Carpenter, J. Am. Chem. Soc., 1986, 108, 462.
14. A pinacolone-solvated lithium enolate derived from 2 has been reported but not fully characterised: R. Amstutz, W. B. Schweizer, D. Seebach and J. Dunitz, Helv. Chim. Acta, 1981, 64, 2617; a pinacolone solvated sodium pinacolate has been structurally characterised: P. G. Williard and G. B. Carpenter, J. Am. Chem. Soc., 1986, 108, 462.
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