Simultaneous monitoring of curing shrinkage and degree of cure of thermosets by attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy

Applied Spectroscopy

Volumn 67, Issue 12, 2013, Pages 1427-1436

  Fernàndez Francos, Xavier ^a   Kazarian, Sergei G ^b   Ramis, Xavier ^c   Serraa, Àngels ^a  

^a UNIVERSITAT ROVIRA I VIRGILI   (Spain)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

^c UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

Author keywords

ATR; Attenuated total reflection; Epoxy; Fourier transform infrared; FT IR; Methacrylate; Polymer; Shrinkage; Swelling; Thermosets

Indexed keywords

ATR; ATTENUATED TOTAL REFLECTIONS; EPOXY; FOURIER TRANSFORM INFRA REDS; FT-IR; METHACRYLATE;

CURING; ELECTROMAGNETIC WAVE REFLECTION; FUNCTIONAL GROUPS; INFRARED SPECTROSCOPY; LIGHT ABSORPTION; POLYMERS; REFRACTIVE INDEX; SHRINKAGE; SWELLING;

THERMOSETS;

EID: 84891811811     PISSN: 00037028     EISSN: 19433530     Source Type: Journal    
DOI: 10.1366/13-07169     Document Type: Article

References (56)

1. R.K. Sadhir, M.R. Luck, editors. Expanding Monomers: Synthesis, Characterization and Applications. Boca Raton, FL: CRC Press, 1992.
2. L. Gonzalez, X. Ramis, J.M. Salla, A. Mantecon, A. Serra. ''Reduction of the Shrinkage of Thermosets by the Cationic Curing of Mixtures of Diglycidyl Ether of Bisphenol A and 6,6-Dimethyl-(4,8-dioxaspiro[2.5]octane- 5,7-dione)''. J. Polym. Sci., Part A: Polym. Chem. 2006. 44(23): 6869-6879.
3. C. Li, K. Potter, M.R. Wisnom, G. Stringer. ''In-Situ Measurement of Chemical Shrinkage of MY750 Epoxy Resin by a Novel Gravimetric Method''. Compos. Sci. Technol. 2004. 64(1): 55-64.
4. H. Morikawa, A. Sudo, H. Nishida, T. Endo. ''Volume-Expandable Monomer 5,5-Dimethyl-1,3-dioxolan-2-one: Its Copolymerization Behavior with Epoxide and its Applications to Shrinkage-Controlled Epoxy- Curing Systems''. J. Appl. Polym. Sci. 2005. 96(2): 372-378.
5. M. Dewaele, D. Truffier-Boutry, J. Devaux, G.T. Leloup. ''Volume Contraction in Photocured Dental Resins: The Shrinkage-Conversion Relationship Revisited''. Dent. Mater. 2006. 22(4): 359-365.
6. D.U. Shah, P. J. Schubel. ''Evaluation of Cure Shrinkage Measurement Techniques for Thermosetting Resins''. Polym. Test. 29(6): 629-639.
7. J. Jose, K. Joseph, J. Pionteck, S. Thomas. ''PVT Behavior of Thermoplastic Poly(styrene-co-acrylonitrile)-Modified Epoxy Systems: Relating Polymerization-Induced Viscoelastic Phase Separation with the Cure Shrinkage Performance''. J. Phys. Chem. B. 2008. 112(47): 14793-14803.
8. M. Holst, K. Schanzlin, M. Wenzel, J. Xu, D. Lellinger, I. Alig. ''Time- Resolved Method for the Measurement of Volume Changes During Polymerization''. J. Polym. Sci., Part B: Polym. Phys. 2005. 43(17): 2314-2325.
9. L. Khoun, P. Hubert. ''Cure Shrinkage Characterization of an Epoxy Resin System by Two In Situ Measurement Methods''. Polym. Compos. 31(9): 1603-1610.
10. P.P. Parlevliet, H.E.N. Bersee, A. Beukers. ''Shrinkage Determination of a Reactive Polymer with Volumetric Dilatometry''. Polym. Test. 29(4): 433-439.
11. D.C. Watts, A.S. Marouf, A.M. Al-Hindi. ''Photo-Polymerization Shrinkage-Stress Kinetics in Resin-Composites: Methods Development''. Dent. Mater. 2003. 19(1): 1-11.
12. A. Amirouche-Korichi, M. Mouzali, D.C. Watts. ''Effects of Monomer Ratios and Highly Radiopaque Fillers on Degree of Conversion and Shrinkage-Strain of Dental Resin Composites''. Dent. Mater. 2009. 25(11): 1411-1418.
13. M. Atai, M. Ahmadi, S. Babanzadeh, D.C. Watts. ''Synthesis, Characterization, Shrinkage and Curing Kinetics of a New Low-Shrinkage Urethane Dimethacrylate Monomer for Dental Applications''. Dent. Mater. 2007. 23(8): 1030-1041.
14. J. Lange, S. Toll, J.A.E. Manson, A. Hult. ''Residual Stress Build-Up in Thermoset Films Cured Above Their Ultimate Glass Transition Temperature''. Polymer. 1995. 36(16): 3135-3141.
15. Y. Nawab, X. Tardif, N. Boyard, V. Sobotka, P. Casari, F. Jacquemin. ''Determination and Modelling of the Cure Shrinkage of Epoxy Vinylester Resin and Associated Composites by Considering Thermal Gradients''. Compos. Sci. Technol. 2012. 73: 81-87.
16. C. Mas, X. Ramis, J.M. Salla, A. Mantecon, A. Serra. ''Copolymerization of Diglycidyl Ether of Bisphenol A with c-Butyrolactone Catalyzed by Ytterbium Triflate: Shrinkage During Curing''. J. Polym. Sci., Part A: Polym. Chem. 2003. 41(18): 2794-2808.
17. X. Fernàndez, J.M. Salla, A. Serra, A. Mantecón, X. Ramis. ''Cationic Copolymerization of Cycloaliphatic Epoxy Resin with a Spirobislactone with Lanthanum Triflate as Initiator: I. Characterization and Shrinkage''. J. Polym. Sci., Part A: Polym. Chem. 2005. 43(15): 3421-3432.
18. R. Gimenez, X. Fernandez-Francos, J.M. Salla, A. Serra, A. Mantecon, X. Ramis. ''New Degradable Thermosets Obtained by Cationic Copolymerization of DGEBA with an s(c-Butyrolactone)''. Polymer. 2005. 46(24): 10637-10647.
19. M. Morell, X. Ramis, F. Ferrando, Y. Yu, A. Serra. ''New Improved Thermosets Obtained from DGEBA and a Hyperbranched Poly(esteramide)''. Polymer. 2009. 50(23): 5374-5383.
20. T.G. Nunes, S.G. Pereira, S. Kalachandra. ''Effect of Treated Filler Loading on the Photopolymerization Inhibition and Shrinkage of a Dimethacrylate Matrix''. J. Mater. Sci.: Mater. Med. 2008. 19(5): 1881-1889.
21. S.G. Pereira, T.G. Nunes, S. Kalachandra. ''Low Viscosity Dimethacrylate Comonomer Compositions [Bis-GMA and CH3Bis-GMA] for Novel Dental Composites; Analysis of the Network by Stray-Field MRI, Solid- State NMR and DSC FTIR''. Biomaterials. 2002. 23(18): 3799-3806.
22. S.V. Hoa, P. Ouellette, T.D. Ngo. ''Determination of Shrinkage and Modulus Development of Thermosetting Resins''. J. Compos. Mater. 2009. 43(7): 783-803.
23. T. Scherzer. ''Real-Time FTIR-ATR Spectroscopy of Photopolymerization Reactions''. Macromol. Symp. 2002. 184(1): 79-98.
24. T. Scherzer. ''Depth Profiling of the Degree of Cure During the Photopolymerization of Acrylates Studied by Real-Time FT-IR Attenuated Total Reflection Spectroscopy''. Appl. Spectrosc. 2002. 56(11): 1403-1412.
25. Y.-M. Kim, L.K. Kostanski, J. F. MacGregor. ''Photopolymerization of 3,4-Epoxycyclohexylmethyl-30,40-Epoxycyclohexane Carboxylate and Tri (Ethylene Glycol) Methyl Vinyl Ether''. Polymer. 2003. 44(18): 5103-5109.
26. X. Fernández-Francos, A. Rybak, R. Sekula, X. Ramis, A. Serra. ''Modification of Epoxy-Anhydride Thermosets Using a Hyperbranched Poly(ester-Amide). I. Kinetics Study''. Polym. Int. 2012. 61(12): 1710-1725.
27. N.M.B. Flichy, S.G. Kazarian, C.J. Lawrence, B. J. Briscoe. ''An ATR-IR Study of Poly (Dimethylsiloxane) Under High-Pressure Carbon Dioxide: Simultaneous Measurement of Sorption and Swelling''. J. Phys. Chem. B. 2001. 106(4): 754-759.
28. F.J. Harris. ''On the Use of Windows for Harmonic Analysis with the Discrete Fourier Transform''. P. IEEE. 1978. 66(1): 51-83.
29. M.W. Urban. Attenuated Total Reflectance Spectroscopy of Polymers. Washington, D.C.: American Chemical Society, 1996.
30. S.J. Buggy, E. Chehura, S.W. James, R.P. Tatam. ''Optical Fibre Grating Refractometers for Resin Cure Monitoring''. J. Opt. A: Pure Appl. Opt. 2007. 9(6): S60-S65.
31. P.A. Crosby, G.R. Powell, G.F. Fernando, C.M. France, R.C. Spooncer, D.N. Waters. ''In Situ Cure Monitoring of Epoxy Resins Using Optical Fibre Sensors''. Smart Mater. Struct. 1996. 5(4): 415-428.
32. A. Dimopoulos, S.J. Buggy, A.A. Skordos, S.W. James, R.P. Tatam, K.I. Partridge. ''Monitoring Cure in Epoxies Containing Carbon Nanotubes with an Optical-Fiber Fresnel Refractometer''. J. Appl. Polym. Sci. 2009. 113(2): 730-735.
33. E. Chailleux, M. Salvia, N. Jaffrezic-Renault, V. Matejec, I. Kasik. ''In Situ Study of the Epoxy Cure Process Using a Fibre-Optic Sensor''. Smart Mater. Struct. 2001. 10(2): 194-202.
34. M.A. Hadis, P.H. Tomlins, A.C. Shortall, W.M. Palin. ''Dynamic Monitoring of Refractive Index Change Through Photoactive Resins''. Dent. Mater. 2010. 26(11): 1106-1112.
35. G.R. Powell, P.A. Crosby, D.N. Waters, C.M. France, R.C. Spooncer, G.F. Fernando. ''In-Situ Cure Monitoring Using Optical Fibre Sensors - A Comparative Study''. Smart Mater. Struct. 1998. 7(4): 557-568.
36. A. Cusano, G. Breglio, M. Giordano, A. Calabro, A. Cutolo, L. Nicolais. ''Optoelectronic Characterization of the Curing Process of Thermoset- Based Composites''. J. Opt. A: Pure Appl. Opt. 2001. 3(2): 126-130.
37. V. Antonucci, M. Giordano, A. Cusano, J. Nasser, L. Nicolais. ''Real Time Monitoring of Cure and Gelification of a Thermoset Matrix''. Compos. Sci. Technol. 2006. 66(16): 3273-3280.
38. R.J. Korniski, W.L. Wolfe. ''Infrared Refractometer Measurements of Adhesives ''. Appl. Opt. 1978. 17(19): 3138-3142.
39. T. Ruf, M. Cardona, C.S.J. Pickles, R. Sussmann. ''Temperature Dependence of the Refractive Index of Diamond up to 925 K''. Phys. Rev. B. 2000. 62(24): 16578-16581.
40. M. Podgó rski. ''Synthesis and Characterization of Acetyloxypropylene Dimethacrylate as a New Dental Monomer''. Dent. Mater. 2011. 27(8): 748-754.
41. S.K. Ooi, W.D. Cook, G.P. Simon, C.H. Such. ''DSC Studies of the Curing Mechanisms and Kinetics of DGEBA Using Imidazole Curing Agents''. Polymer. 2000. 41(10): 3639-3649.
42. M.S. Heise, G.C. Martin. ''Curing Mechanism and Thermal Properties of Epoxy-Imidazole Systems''. Macromolecules. 1989. 22(1): 99-104.
43. M.S. Heise, G.C. Martin. ''Analysis of the Cure Kinetics of Epoxy/ Imidazole Resin Systems''. J. Appl. Polym. Sci. 1990. 39(3): 721-738.
44. J.M. Barton, I. Hamerton, B.J. Howlin, J.R. Jones, S. Liu. ''Studies of Cure Schedule and Final Property Relationships of a Commercial Epoxy Resin Using Modified Imidazole Curing Agents''. Polymer. 1998. 39(10): 1929-1937.
45. X. Fernandez-Francos, W.D. Cook, A. Serra, X. Ramis, G.G. Liang, J.M. Salla. ''Crosslinking of Mixtures of DGEBA with Bislactone Initiated by Tertiary Amines. IV. Effect of Hydroxyl Groups on Initiation and Curing Kinetics''. Polymer. 2010. 51(1): 26-34.
46. A.N. Mauri, N. Galego, C.C. Riccardi, R.J.J. Williams. ''Kinetic Model for Gelation in the Diepoxide-Cyclic Anhydride Copolymerization Initiated by Tertiary Amines''. Macromolecules. 1997. 30(6): 1616-1620.
47. K. Dušek, S. Luňák, L. Matějka. ''Gelation in the Curing of Epoxy Resins with Anhydrides''. Polym. Bull. 1982. 7(2-3): 145-152.
48. J. Rocks, L. Rintoul, F. Vohwinkel, G. George. ''The Kinetics and Mechanism of Cure of an Amino-Glycidyl Epoxy Resin by a Co- Anhydride as Studied by FT-Raman Spectroscopy''. Polymer. 2004. 45(20): 6799-6811.
49. C. Decker, T. Nguyen, T. Viet, H.P. Thi. ''Photoinitiated Cationic Polymerization of Epoxides''. Polym. Int. 2001. 50(9): 986-997.
50. J.V. Crivello, U. Varlemann. ''Structure and Reactivity Relationships in the Photoinitiated Cationic Polymerization of 3,4-Epoxycyclohexylmethyl- 30,40-Epoxycyclohexane Carboxylate''. ACS Symposium Series. 1997. 673: 82-94.
51. M. Sangermano, A. Priola, G. Malucelli, R. Bongiovanni, A. Quaglia, B. Voit, A. Ziemer. ''Phenolic Hyperbranched Polymers as Additives in Cationic Photopolymerization of Epoxy Systems''. Macromol. Mater. Eng. 2004. 289(5): 442-446.
52. D.A. Tilbrook, R.L. Clarke, N.E. Howle, M. Braden. ''Photocurable Epoxy-Polyol Matrices for Use in Dental Composites I''. Biomaterials. 2000. 21(17): 1743-1753.
53. M. Sangermano, R.A. Ortiz, B.A.P. Urbina, L.B. Duarte, A.E.G. Valdez, R.G. Santos. ''Synthesis of an Epoxy Functionalized Spiroorthocarbonate Used as Low Shrinkage Additive in Cationic UV Curing of an Epoxy Resin''. Eur. Polym. J. 2008. 44(4): 1046-1052.
54. Y.-M. Kim, L.K. Kostanski, J.F. MacGregor. ''Kinetic Studies of Cationic Photopolymerizations of Cycloaliphatic Epoxide, Triethyleneglycol Methyl Vinyl Ether, and Cyclohexene Oxide''. Polym. Eng. Sci. 2005. 45(11): 1546-1555.
55. A.R.C. Duarte, L.E. Anderson, C.M.M. Duarte, S.G. Kazarian. ''A Comparison Between Gravimetric and In Situ Spectroscopic Methods to Measure the Sorption of CO2 in a Biocompatible Polymer''. J. Supercrit. Fluids. 2005. 36(2): 160-165.
56. S.G. Kazarian. ''Polymers and Supercritical Fluids: Opportunities for Vibrational Spectroscopy''. Macromol. Symp. 2002. 184(1): 215-228.