Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted c-F bond cleavage

Angewandte Chemie - International Edition

Volumn 53, Issue 2, 2014, Pages 517-520

  Nishimine, Takayuki ^a   Fukushi, Kazunobu ^a   Shibata, Naoyuki ^a   Taira, Hiromi ^a   Tokunaga, Etsuko ^a   Yamano, Akihito ^b   Shiro, Motoo ^b   Shibata, Norio ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

^b RIGAKU CORPORATION   (Japan)

Author keywords

allyl fluorides; fluorine; kinetic resolution; organocatalysis; trifluoromethylation

Indexed keywords

ALLYL FLUORIDES; C-F BONDS; ENANTIOSELECTIVE; FLUORINATED COMPOUND; KINETIC RESOLUTION; ORGANOCATALYSIS; TRIFLUOROMETHYLATION;

ENANTIOSELECTIVITY; FLUORINE; FLUORINE COMPOUNDS; REACTION KINETICS;

KINETICS;

ALLYL COMPOUND; CARBON; FLUORIDE; FLUORINATED HYDROCARBON; FLUORINE; ORGANOSILICON DERIVATIVE;

ALLYL FLUORIDES; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; KINETIC RESOLUTION; KINETICS; METHYLATION; ORGANOCATALYSIS; STEREOISOMERISM; SYNTHESIS; TRIFLUOROMETHYLATION;

ALLYL FLUORIDES; FLUORINE; KINETIC RESOLUTION; ORGANOCATALYSIS; TRIFLUOROMETHYLATION;

ALLYL COMPOUNDS; CARBON; CATALYSIS; FLUORIDES; HYDROCARBONS, FLUORINATED; KINETICS; METHYLATION; MOLECULAR STRUCTURE; ORGANOSILICON COMPOUNDS; STEREOISOMERISM;

EID: 84891762919     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201308071     Document Type: Article

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