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Volumn 43, Issue 4, 2014, Pages 1599-1608

Synthesis and structural characterisation of Pd(ii) and Pt(ii) complexes with a flexible, ferrocene-based P,S-donor amidophosphine ligand

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; LIGANDS; MIXTURES; ORGANOMETALLICS; PALLADIUM COMPOUNDS; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

EID: 84890808569     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt52760c     Document Type: Article
Times cited : (12)

References (66)
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    • The orientation of the C24-C25 bond is nearly the same in all three complexes. Compare the angles subtended by the vector of the C24-C25 bond and the Cp1 plane being 33.0(1)° in, 54.7(1)° in trans- 2, 55.4(2)° in trans- 3, and 56.3(2)° in cis- 3 Epa and Epc are anodic and cathodic peak potentials, respectively. Potentials determined at the scan rate 0.1 V s-1 are quoted for all irreversible processes The anodic peak current (ipa) was directly proportional to the square root of the scan rate (ipa ∝ ν1/2), which suggests the oxidation to be a standard diffusion-controlled redox transition Chemical reactions following an electron transfer process are well documented for phosphinoferrocenes. For examples, see
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    • See also ref. 11a Ferrocene itself showed practically identical response under the experiment conditions. The observed peak separations are higher than the theoretically predicted values (59 mV at 25 °C), presumably due to a high resistance of the analysed solution. No iR drop correction was applied to the data
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    • The process is controlled by diffusion (ip ∝ ν1/2); the separation of the peaks in cyclic voltammogram is 80 mV at a scan rate of 0.1 V s-1
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.