A chiral diphosphine as trans-chelate ligand and its relevance to catalysis

Chemical Communications

Volumn 46, Issue 11, 2010, Pages 1953-1955

  Nasser, Nasser ^a   Eisler, Dana J ^a   Puddephatt, Richard J ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATE; DIPHOSPHINE; GOLD; LIGAND; PALLADIUM; PHOSPHINE DERIVATIVE; SILVER; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CONFORMATION; ENANTIOSELECTIVITY; STEREOCHEMISTRY; SUBSTITUTION REACTION; TEMPERATURE;

EID: 77949357033     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b923911a     Document Type: Article

References (17)

1. B. M. Trost and D. L. van Vranken, Angew. Chem., Int. Ed. Engl., 1992, 31, 228;
2. B. M. Trost and F. D. Toste, J. Am. Chem. Soc., 1999, 121, 4545.
3. C. P. Butts, E. Filali, G. C. Lloyd-Jones, P.-O. Norrby, D. A. Sale and Y. Schramm, J. Am. Chem. Soc., 2009, 131, 9945;
4. C. P. Butts, J. Crosby, G. C. Lloyd-Jones and S. C. Stephen, Chem. Commun., 1999, 1707;
5. I. J. S. Fairlamb and G. C. Lloyd-Jones, Chem. Commun., 2000, 2447;
6. G. C. Lloyd-Jones, S. C. Stephen, I. J. S. Fairlamb, A. Martorell, B. Dominguez, P. M. Tomlin, M. Murray, J. M. Fernandez, J. C. Jeffery, T. Riis-Johannessen and T. Guerziz, Pure Appl. Chem., 2004, 76, 589.
7. R. A. Swanson, B. O. Patrick, M. J. Ferguson and C. J. A. Daley, Inorg. Chim. Acta, 2007, 360, 2455;
8. C. Amatore, A. Jutand, L. Mensah and L. Ricard, J. Organomet. Chem., 2007, 692, 1457.
9. For work with other chiral or wide bite-angle ligands: M. Sawamura, H. Hamashima, M. Sugawara, R. Kuwano and Y. Ito, Organometallics, 1995, 14, 4549;
10. C. Dieleman, S. Steyer, C. Jeunesse and D. Matt, J. Chem. Soc., Dalton Trans., 2001, 2508;
11. M.-N. Birkholz, Z. Freixa and P. W. N. M. van Leeuwen, Chem. Soc. Rev., 2009, 38, 1099.
12. Z. Freixa and P. W. N. M. van Leeuwen, Coord. Chem. Rev., 2008, 252, 1755.
13. 2(1)], the only other known structure in which ligand 1 is bidentate PP-chelating, ligand 1 acts as a cis-chelate: S. Burger, B. Therrien and G. Süss-Fink, Acta Crystallogr., Sect. E: Struct. Rep. Online, 2004, 60, m1163.
14. 31P NMR spectrum. Perhaps the weak outer peaks of the expected [AB] multiplet were too low in intensity to be detected: S. Burger, B. Therrien and G. Süss-Fink, Helv. Chim. Acta, 2005, 88, 478.
15. Gold: Progress in Chemistry Biochemistry and Technology, ed. H. Schmidbaur, Wiley, Chichester, 1999.
16. 2J(PP) is not observed. A. M. Gibson and G. Reid, J. Chem. Soc., Dalton Trans., 1996, 1267;
17. B. Heuer, S. J. A. Pope and G. Reid, Polyhedron, 2000, 19, 743.