Tunable Separations, Reactions, and Nanoparticle Synthesis in Functionalized Membranes

Responsive Membranes and Materials

Volumn , Issue , 2012, Pages 97-142

  Lewis, Scott R ^a   Smuleac, Vasile ^a   Xiao, Li ^a   Bhattacharyya, D ^a  

^a UNIVERSITY OF KENTUCKY   (United States)

Author keywords

Chemical modification; Cross linked hydrogel; Functionalized membranes; Tunable separations; Water flux tunability

Indexed keywords

EID: 84886189159     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9781118389553.ch5     Document Type: Chapter

References (163)

1. Klein, E. (2000) Affinity membranes: a 10-year review. Journal of Membrane Science, 179(1-2), 1-27.
2. Ulbricht, M. (2006) Advanced functional polymer membranes. Polymer, 47(7), 2217-2262.
3. Derwinska, K., Sauer, U., and Preininger, C. (2008) Adsorption versus covalent, statistically oriented and covalent, site-specific IgG immobilization on poly(vinyl alcohol)-based surfaces. Talanta, 77(2), 652-658.
4. Hestekin, J.A., Bachas, L.G., and Bhattacharyya, D. (2001) Poly(amino acid)-functionalized cellulosic membranes: Metal sorption mechanisms and results. Industrial & Engineering Chemistry Research, 40(12), 2668-2678.
5. Boi, C., Cattoli, F., Facchini, R. et al. (2006) Adsorption of lectins on affinity membranes. Journal of Membrane Science, 273(1-2), 12-19.
6. Shi,W., Zhang, F.B., and Zhang, G.L. (2005) Adsorption of bilirubin with polylysine carrying chitosan-coated nylon affinity membranes. Journal of Chromatography BAnalytical Technologies in the Biomedical and Life Sciences, 819(2), 301-306.
7. Liu, Y.C. Suen, S.Y., Huang, C.W., et al. (2005) Effects of spacer arm on penicillin G acylase purification using immobilized metal affinity membranes. Journal of Membrane Science, 251(1-2), 201-207.
8. Rebek, J. and Feitler, D. (1974) Mechanism of carbodiimide reaction. 2. Peptidesynthesis on solid-phase. Journal of the American Chemical Society, 96(5), 1606-1607.
9. Ulbricht, M. and Papra, A. (1997) Polyacrylonitrile enzyme ultrafiltration membranes prepared by adsorption, cross-linking, and covalent binding. Enzyme and Microbial Technology, 20(1), 61-68.
10. Neame, P.J. and Parikh, I. (1982) Sepharose-immobilized triazine dyes as adsorbants for human-lymphoblastoid interferon purification. Applied Biochemistry and Biotechnology, 7(4), 295-305.
11. Mcconway, M.G. and Chapman, R.S. (1986) Application of solid-phase antibodies to radioimmunoassay -evaluation of 2 polymeric microparticles, dynospheres and nylon, activated by carbonyldiimidazole or tresyl chloride. Journal of Immunological Methods, 95(2), 259-266.
12. Klein, E. (1991) Affinity Membranes: Their Chemistry and Performance in Adsorptive Separation Processes, Wiley, New York, x, 152 p.
13. Blitz, J.P., Murthy, R.S.S., and Leyden, D.E. (1987) Ammonia-catalyzed silylation reactions of Cab-O-Sil with methoxymethylsilanes. Journal of the American Chemical Society, 109(23), 7141-7145.
14. Sindorf, D.W. and Maciel, G.E. (1983) Solid-state Nmr-studies of the reactions of silica surfaces with polyfunctional chloromethylsilanes and ethoxymethylsilanes. Journal of the American Chemical Society, 105(12), 3767-3776.
15. Zeigler, R.C. and Maciel, G.E. (1991) A study of the structure and dynamics of dimethyloctadecylsilyl-modified silica using wide-line H-2-Nmr techniques. Journal of the American Chemical Society, 113(17), 6349-6358.
16. Tripp, C.P. and Hair, M.L. (1992) An infrared study of the reaction of octadecyltrichlorosilane with silica. Langmuir, 8(4), 1120-1126.
17. Silberzan, P. Léger, D., Ausserré, J. et al. (1991) Silanation of silica surfaces -a new method of constructing pure or mixed monolayers. Langmuir, 7(8), 1647-1651.
18. Ritchie, S.M.C. Kissick, K.E., Bachas, L.G., et al. (2001) Polycysteine and other polyamino acid functionalized microfiltration membranes for heavy metal capture. Environmental Science & Technology, 35(15), 3252-3258.
19. Smuleac, V., Buttereld, D.A., Sikdar, S.K. et al. (2005) Polythiol-functionalized alumina membranes for mercury capture. Journal of Membrane Science, 251(1-2), 169-178.
20. Hulteen, J.C., Jirage, K.B., and Martin, C.R. (1998) Introducing chemical transport selectivity into gold nanotubule membranes. Journal of the American Chemical Society, 120(26), 6603-6604.
21. Jirage, K.B., Hulteen, J.C., and Martin, C.R. (1999) Effect of thiol chemisorption on the transport properties of gold nanotubule membranes. Analytical Chemistry, 71(21), 4913-4918.
22. Martin, C.R. and Gasparac, R. (2001) Investigations of the transport properties of gold nanotubule membranes. Journal of Physical Chemistry B, 105(10), 1925-1934.
23. Chun, K.Y. and Stroeve, P. (2001) External control of ion transport in nanoporous membranes with surfaces modified with self-assembled monolayers. Langmuir, 17(17), 5271-5275.
24. Hou, Z.Z., Abbott, N.L., and Stroeve, P. (2000) Self-assembled monolayers on electroless gold impart pH-responsive transport of ions in porous membranes. Langmuir, 16(5), 2401-2404.
25. Kang, M.S. and Martin, C.R. (2001) Investigations of potential-dependent fluxes of ionic permeates in gold nanotubule membranes prepared via the template method. Langmuir, 17(9), 2753-2759.
26. Chun, K.Y. and Stroeve, P. (2002) Protein transport in nanoporous membranes modified with self-assembled monolayers of functionalized thiols. Langmuir, 18(12), 4653-4658.
27. Ku, J.R. and Stroeve, P. (2004) Protein diffusion in charged nanotubes: "On-Off" behavior of molecular transport. Langmuir, 20(5), 2030-2032.
28. Yu, S.F. Sang Bok, L., Kang, M. et al. (2001) Size-based protein separations in poly(ethylene glycol)-derivatized gold nanotubule membranes. Nano Letters, 1(9), 495-498.
29. Ito, Y., Park, Y.S., and Imanishi, Y. (2000) Nanometer-sized channel gating by a self-assembled polypeptide brush. Langmuir, 16(12), 5376-5381.
30. Smuleac, V., Butterfield, D.A., and Bhattacharyya, D. (2004) Permeability and separation characteristics of polypeptide-functionalized polycarbonate track-etched membranes. Chemistry of Materials, 16(14), 2762-2771.
31. Alvarez, S., Garcia, A., Manolache, S. et al. (2005) Plasma-enhanced modification of the pore size of ceramic membranes. Desalination, 184(1-3), 99-104.
32. Greene, G. and Tannenbaum, R. (2004) Adsorbtion of polyelectrolyte multilayers on plasma-modified porous polyethylene. Applied Surface Science, 238(1-4), 101-107.
33. Kull, K.R., Steen, M.L., and Fisher, E.R. (2005) Surface modification with nitrogencontaining plasmas to produce hydrophilic, low-fouling membranes. Journal of Membrane Science, 246(2), 203-215.
34. Steen, M.L., Hymas, L., Havey, E.D. et al. (2001) Low temperature plasma treatment of asymmetric polysulfone membranes for permanent hydrophilic surface modification. Journal of Membrane Science, 188(1), 97-114.
35. He, D.M., Susanto, H., and Ulbricht, M. (2009) Photo-irradiation for preparation, modification and stimulation of polymeric membranes. Progress in Polymer Science, 34(1), 62-98.
36. Freger, V., Gilron, J., and Belfer, S. (2002) TFC polyamide membranes modified by grafting of hydrophilic polymers: an FT-IR/AFM/TEM study. Journal of Membrane Science, 209(1), 283-292.
37. Himstedt, H.H., Marshall, K.M., and Wickramasinghe, S.R. (2011) pH-responsive nanofiltration membranes by surface modification. Journal of Membrane Science, 366(1-2), 373-381.
38. Meier-Haack, J., Booker, N.A., and Carroll, T. (2003) A permeability-controlled microfiltration membrane for reduced fouling in drinking water treatment. Water Research, 37(3), 585-588.
39. Ulbricht, M. and Yang, H. (2005) Porous polypropylene membranes with different carboxyl polymer brush layers for reversible protein binding via surface-initiated graft copolymerization. Chemistry of Materials, 17(10), 2622-2631.
40. Higa, M. and Yamakawa, T. (2004) Design and preparation of a novel temperatureresponsive ionic gel. 1. A fast and reversible temperature response in the charge density. Journal of Physical Chemistry B, 108(43), 16703-16707.
41. Higa, M. and Yamakawa, T. (2005) Design and preparation of a novel temperatureresponsive ionic gel. 2. Concentration modulation of specific ions in response to temperature changes. Journal of Physical Chemistry B, 109(22), 11373-11378.
42. Mika, A.M., Childs, R.F., and Dickson, J.M. (2002) Salt separation and hydrodynamic permeability of a porous membrane filled with pH-sensitive gel. Journal of Membrane Science, 206(1-2), 19-30.
43. Hu, K. and Dickson, J.M. (2007) Development and characterization of poly(vinylidene fluoride)-poly(acrylic acid) pore-filled pH-sensitive membranes. Journal of Membrane Science, 301(1-2), 19-28.
44. Lewis, S., Smuleac, V., Montague, A. et al. (2009) Iron-functionalized membranes for nanoparticle synthesis and reactions. Separation Science and Technology, 44(14), 3289-3311.
45. Smuleac, V., Bachas, L., and Bhattacharyya, D. (2010) Aqueous-phase synthesis of PAA in PVDF membrane pores for nanoparticle synthesis and dichlorobiphenyl degradation. Journal of Membrane Science, 346(2), 310-317.
46. Xu, J. and Bhattacharyya, D. (2007) Fe/Pd nanoparticle immobilization in microfiltration membrane pores: Synthesis, characterization, and application in the dechlorination of polychlorinated biphenyls. Industrial & Engineering Chemistry Research, 46(8), 2348-2359.
47. Ilmain, F., Tanaka, T., and Kokufuta, E. (1991), Volume transition in a gel driven by hydrogen-bonding. Nature, 349(6308), 400-401.
48. Lahann, J. and Yoshida, M. (2008) Smart nanomaterials. Acs Nano, 2(6), 1101-1107.
49. Fernandez-Barbero, A. et al. (2009) Gels and microgels for nanotechnological applications. Advances in Colloid and Interface Science, 147-148, 88-108.
50. Stuart, M.A.C., Huck, W., Genzer, J. et al. (2010) Emerging applications of stimuliresponsive polymer materials. Nature Materials, 9(2), 101-113.
51. Kuckling, D. (2009) Responsive hydrogel layers-from synthesis to applications. Colloid and Polymer Science, 287(8), 881-891.
52. Schueneman, S.M. and Chen, W. (2002), Environmentally responsive hydrogels. Journal of Chemical Education, 79(7), 860-862.
53. West, J.L. and Strong, L.E. (2011) Thermally responsive polymer-nanoparticle composites for biomedical applications. Wiley Interdisciplinary Reviews-Nanomedicine and Nanobiotechnology, 3(3), 307-317.
54. Milasinovic, N., Kalagasidis Krušić, M., Knežević-Jugović, Z. et al. (2010) Hydrogels of N-isopropylacrylamide copolymers with controlled release of a model protein. International Journal of Pharmaceutics, 383(1-2), 53-61.
55. Schild, H.G. (1992) Poly (N-isopropylacrylamide) -experiment, theory and application. Progress in Polymer Science, 17(2), 163-249.
56. Makino, K., Hiyoshi, J., and Ohshima, H. (2000) Kinetics of swelling and shrinking of poly (N-isopropylacrylamide) hydrogels at different temperatures. Colloids and Surfaces B-Biointerfaces, 19(2), 197-204.
57. Gupta, P., Vermani, K., and Garg, S. (2002) Hydrogels: from controlled release to pH-responsive drug delivery. Drug Discovery Today, 7(10), 569-579.
58. Dong, L.C. and Hoffman, A.S. (1986) Thermally reversible hydrogels: III. Immobilization of enzymes for feedback reaction control. Journal of Controlled Release, 4(3), 223-227.
59. Kanazawa, H. and Okano, T. (2011) Temperature-responsive chromatography for the separation of biomolecules. Journal of Chromatography A, 1218, (49), 8738-8747.
60. Gan, D.J. and Lyon, L.A. (2002) Synthesis and protein adsorption resistance of PEG-modified poly(N-isopropylacrylamide) core/shell microgels. Macromolecules, 35(26), 9634-9639.
61. Qiu, Y. and Park, K. (2001) Environment-sensitive hydrogels for drug delivery. Advanced Drug Delivery Reviews, 53(3), 321-339.
62. Decher, G. (1997) Fuzzy nanoassemblies: Toward layered polymeric multicomposites. Science, 277(5330), 1232-1237.
63. Decher, G., Hong, J.D., and Schmitt, J. (1992) Buildup of ultrathin multilayer films by a self-assembly process. 3. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films, 210(1-2), 831-835.
64. Lvov, Y., Yamada, S., and Kunitake, T. (1997) Non-linear optical effects in layer-bylayer alternate films of polycations and an azobenzene-containing polyanion. Thin Solid Films, 300(1-2), 107-112.
65. Shimazaki, Y., Ito, S., and Tsutsumi, N. (2000) Adsorption-induced second harmonic generation from the layer-by-layer deposited ultrathin film based on the chargetransfer interaction. Langmuir, 16(24), 9478-9482.
66. Zheng, H.P., Lee, I., Rubner, M.F et al. (2002) Two component particle arrays on patterned polyelectrolyte multilayer templates. Advanced Materials, 14(8), 569-572.
67. Bruening, M.L., Dotzauer, D. M., Jain, P. et al. (2008) Creation of functional membranes using polyelectrolyte multilayers and polymer brushes. Langmuir, 24(15), 7663-7673.
68. Krasemann, L. and Tieke, B. (1998) Ultrathin self-assembled polyelectrolyte membranes for pervaporation. Journal of Membrane Science, 150(1), 23-30.
69. Liu, X.Y. and Bruening, M.L. (2004) Size-selective transport of uncharged solutes through multilayer polyelectrolyte membranes. Chemistry of Materials, 16(2), 351-357.
70. Malaisamy, R. and Bruening, M.L. (2005) High-flux nanofiltration membranes prepared by adsorption of multilayer polyelectrolyte membranes on polymeric supports. Langmuir, 21(23), 10587-10592.
71. Jin, W.Q., Toutianoush, A. and Tieke, B. (2003) Use of polyelectrolyte layer-bylayer assemblies as nanofiltration and reverse osmosis membranes. Langmuir, 19(7), 2550-2553.
72. Tarabara, V.V.,Wang, F., Davis, T.E. et al. (2010) Polyelectrolyte multilayer films as backflushable nanofiltration membranes with tunable hydrophilicity and surface charge. Journal of Membrane Science, 349(1-2), 268-278.
73. Wu, Z.Y., Guan, L., Shen, G. et al. (2002) Renewable urea sensor based on a selfassembled polyelectrolyte layer. Analyst, 127(3), 391-395.
74. Forzani, E.S., Solis, V.M., and Calvo, E.J. (2000) Electrochemical behavior of polyphenol oxidase immobilized in self-assembled structures layer by layer with cationic polyallylamine. Analytical Chemistry, 72(21), 5300-5307.
75. Dotzauer, D.M., Abusaloua, A., Miachon, S. et al. (2009)Wet air oxidation with tubular ceramic membranes modified with polyelectrolyte/Pt nanoparticle films. Applied Catalysis B: Environmental, 91(1-2), 180-188.
76. Zimnitsky, D., Shevchenko, V.V., and Tsukruk, V.V. (2008) Perforated, freely suspended layer-by-layer nanoscale membranes. Langmuir, 24(12), 5996-6006.
77. Wandera, D., Wickramasinghe, S.R., and Husson, S.M. (2010) Stimuli-responsive membranes. Journal of Membrane Science, 357(1-2), 6-35.
78. Zhang, H.J. and Ito, Y. (2001) pH control of transport through a porous membrane self-assembled with a poly(acrylic acid) loop brush. Langmuir, 17(26), 8336-8340.
79. Ito, Y., Park, Y.S., and Imanishi, Y. (1997) Visualization of critical pH-controlled gating of a porous membrane grafted with polyelectrolyte brushes. Journal of the American Chemical Society, 119(11), 2739-2740.
80. Hu, K. and Dickson, J.M. (2009) In vitro investigation of potential application of pH-sensitive poly(vinylidene fluoride)-poly(acrylic acid) pore-filled membranes for controlled drug release in ruminant animals. Journal of Membrane Science, 337(1-2), 9-16.
81. Ito, Y., Kotera, S., Inaba, M. et al. (1990) Control of pore-size of polycarbonate membrane with straight pores by poly(acrylic acid) grafts. Polymer, 31(11), 2157-2161.
82. Hollman, A.M., Scherrer, N.T., Cammers-Goodwin, A. et al. (2004) Separation of dilute electrolytes in poly(amino acid) functionalized microporous membranes: model evaluation and experimental results. Journal of Membrane Science, 239(1), 65-79.
83. Hollman, A.M. and Bhattacharyya, D. (2002) Controlled permeability and ion exclusion in microporous membranes functionalized with poly(L-glutamic acid). Langmuir, 18(15), 5946-5952.
84. Castro, R.P., Monbouquette, H.G., and Cohen, Y. (2000) Shear-induced permeability changes in a polymer grafted silica membrane. Journal of Membrane Science, 179(1-2), 207-220.
85. Bowen, W.R. and Mukhtar, H. (1996) Characterisation and prediction of separation performance of nanofiltration membranes. Journal of Membrane Science, 112(2), 263-274.
86. Hollman, A.M. and Bhattacharyya, D. (2004) Pore-assembled multilayers of charged polypeptides in microporous membranes for ion separation. Langmuir, 20(13), 5418-5424.
87. Choi, S.H., Han Jeong, Y., Jeong Ryoo, J. et al. (2001) Desalination by electrodialysis with the ion-exchange membrane prepared by radiation-induced graft polymerization. Radiation Physics and Chemistry, 60(4-5), 503-511.
88. Ritchie, S.M.C., Bhattacharyya, D., Bachas, L.G. et al. (1999) Surface modification of silica-and cellulose-based microfiltration membranes with functional polyamino acids for heavy metal sorption. Langmuir, 15(19), 6346-6357.
89. Konishi, S., Saito, K., Furusaki S. et al. (1992) Sorption kinetics of cobalt in chelating porous membrane. Industrial & Engineering Chemistry Research, 31(12), 2722-2727.
90. Choi, S.H. and Nho, Y.C. (1999) Adsorption of Co2+ by stylene-g-polyethylene membrane bearing sulfonic acid groups modified by radiation-induced graft copolymerization. Journal of Applied Polymer Science, 71(13), 2227-2235.
91. Ritchie, S.M.C. and Bhattacharyya, D. (2001) Polymeric ligand-based functionalized materials and membranes for ion exchange, in Ion Exchange and Solvent Extraction: A Series of Advances (eds A.K. SenGupta, J.A. Marinsky and Y. Marcus), Marcel Dekker, Inc., New York, pp. 81-118.
92. Bhattacharyya, D., Hestekin, P., Brushaber, L. et al. (1998) Novel poly-glutamic acid functionalized microfiltration membranes for sorption of heavy metals at high capacity. Journal of Membrane Science, 141(1), 121-135.
93. Shah, T.N. and Ritchie, S.M.C. (2005) Esterification catalysis using functionalized membranes. Applied Catalysis a-General, 296(1), 12-20.
94. Lu, Y. Mei, Y., Drechsler, M. et al. (2006) Thermosensitive core-shell particles as carriers for Ag nanoparticles: Modulating the catalytic activity by a phase transition in networks. Angewandte Chemie-International Edition, 45(5), 813-816.
95. Lu, Y., Proch S., Schrinner, M. et al. (2009) Thermosensitive core-shell microgel as a "nanoreactor" for catalytic active metal nanoparticles. Journal of Materials Chemistry, 19(23), 3955-3961.
96. Haber, F. andWeiss, J. (1934) The catalytic decomposition of hydrogern peroxide by iron salts. Proceedings of the Royal Society, A147, 332-351.
97. Barb, W.G., Baxendale, J. H., George, Philip, et al. (1949) Reactions of ferrous and ferric ions with hydrogen peroxide. Nature, 163(4148), 692-694.
98. Watts, R.J. and Teel, A.L. (2005) Chemistry of modified Fenton's reagent (catalyzed H2O2 propagations-CHP) for in situ soil and groundwater remediation. Journal of Environmental Engineering-ASCE, 131(4), 612-622.
99. Lewis, S., Lynch, A., Bachas, L. et al. (2009) Chelate-modified Fenton reaction for the degradation of trichloroethylene in aqueous and two-phase systems. Environmental Engineering Science, 26(4), 849-859.
100. Li, Y.C., Bachas, L.G., and Bhattacharyya, D. (2007) Selected chloro-organic detoxifications by polychelate (Poly(acrylic acid)) and citrate-based Fenton reaction at neutral pH environment. Industrial & Engineering Chemistry Research, 46(24), 7984-7992.
101. Lin, S.S. and Gurol, M.D. (1998) Catalytic decomposition of hydrogen peroxide on iron oxide: Kinetics, mechanism, and implications. Environmental Science & Technology, 32(10), 1417-1423.
102. Benaglia, M., Puglisi, A., and Cozzi, F. (2003) Polymer-supported organic catalysts. Chemical Reviews, 103(9), 3401-3429.
103. Haag, R. and Roller, S. (2004) Polymeric supports for the immobilisation of catalysts. Immobilized Catalysts, 242, 1-42.
104. Kirschning, A., Monenschein, H., and Wittenberg, R. (2001) Functionalized polymers - Emerging versatile tools for solution-phase chemistry and automated parallel synthesis. Angewandte Chemie-International Edition, 40(4), 650-679.
105. Feng, J.Y., Hu, X.J., and Yue, P.L. (2004) Degradation of salicylic acid by photoassisted Fenton reaction using Fe ions on strongly acidic ion exchange resin as catalyst. Chemical Engineering Journal, 100(1-3), 159-165.
106. Ma, W.H., Huang, Y., Li, J., et al. (2003) An efficient approach for the photodegradation of organic pollutants by immobilized iron ions at neutral pHs. Chemical Communications, (13), 1582-1583.
107. Ruda, T.A. and Dutta, P.K. (2005) Fenton chemistry of Fe-III-exchanged zeolitic minerals treated with antioxidants. Environmental Science & Technology, 39(16), 6147-6152.
108. Neamtu, M., Zaharia, C., Catrinescu, C. et al. (2004) Fe-exchanged Y zeolite as catalyst for wet peroxide oxidation of reactive azo dye Procion Marine H-EXL. Applied Catalysis B-Environmental, 48(4), 287-294.
109. Gonzalez-Bahamon, L.F., García, H., Gómez-Gaŕia, C.J. et al. (2011) Photo-Fenton degradation of resorcinol mediated by catalysts based on iron species supported on polymers. Journal of Photochemistry and Photobiology a-Chemistry, 217(1), 201-206.
110. Ramirez, J., Godínez, L., Méndez, M. et al. (2010) Heterogeneous photo-electro-Fenton process using different iron supporting materials. Journal of Applied Electrochemistry, 40(10), 1729-1736.
111. Fernandez, J., Nadtochenko V., Bozzi A. et al. (2003) Testing and performance of immobilized Fenton photoreactions via membranes, mats, and modified copolymers. International Journal of Photoenergy, 5(2), 107-113.
112. Parra, S., Henao L., Mielczarski E. et al. (2004) Synthesis, testing, and characterization of a novel Nafion membrane with superior performance in photoassisted immobilized Fenton catalysis. Langmuir, 20(13), 5621-5629.
113. Fernandez, J., Bandara, J., Kiwi, J. et al. (1998) Efficient photo-assisted Fenton catalysis mediated by Fe ions on Nafion membranes active in the abatement of non-biodegradable azo-dye. Chemical Communciations, (14), 1493-1494.
114. Lewis, S.R., Datta, S., Gui, M. et al. (2011) Reactive nanostructured membranes for water purification. Proceedings of the National Academy of Sciences of the United States of America, 108(21), 8577-8582.
115. Shi, F., Tse, M., Pohl, M-M. et al. (2008) Nano-iron oxide-catalyzed selective oxidations of alcohols and olefins with hydrogen peroxide. Journal of Molecular Catalysis a-Chemical, 292(1-2), 28-35.
116. Winnik, F.M., Morneau, A., Mika, A.M. et al. (1998) Polyacrylic acid pore-filled microporous membranes and their use in membrane-mediated synthesis of nanocrystalline ferrihydrite. Canadian Journal of Chemistry, 76(1), 10-17.
117. Zhang, W.X. (2003) Nanoscale iron particles for environmental remediation: An overview. Journal of Nanoparticle Research, 5(3-4), 323-332.
118. Li, X.Q., Elliott, D.W., and Zhang, W.X. (2006) Zero-valent iron nanoparticles for abatement of environmental pollutants: Materials and engineering aspects. Critical Reviews in Solid State and Materials Sciences, 31(4), 111-122.
119. Liu, Z.L., Ling, X.Y., Su, X. et al. (2004) Carbon-supported Pt and PtRu nanoparticles as catalysts for a direct methanol fuel cell. Journal of Physical Chemistry B, 108(24), 8234-8240.
120. Mallick, K. and Scurrell, M.S. (2003) CO oxidation over gold nanoparticles supported on TiO2 and TiO2-ZnO: catalytic activity effects due to surface modification of TiO2 with ZnO. Applied Catalysis a-General, 253(2), 527-536.
121. Sun, C.L., Peltre, M-J., Briend, M. et al. (2003) Catalysts for aromatics hydrogenation in presence of sulfur: reactivities of nanoparticles of ruthenium metal and sulfide dispersed in acidic Y zeolites. Applied Catalysis a-General, 245(2), 245-255.
122. Lu, A.H., Salabas, E.L., and Schuth, F. (2007) Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angewandte Chemie-International Edition, 46(8), 1222-1244.
123. He, F. and Zhao, D.Y. (2005) Preparation and characterization of a new class of starch-stabilized bimetallic nanoparticles for degradation of chlorinated hydrocarbons in water. Environmental Science & Technology, 39(9), 3314-3320.
124. Meyer, D.E., Hampson, S., Ormsbee., L. et al. (2009) A study of groundwater matrix effects for the destruction of trichloroethylene using Fe/Pd nanoaggregates. Environmental Progress & Sustainable Energy, 28(4), 507-518.
125. Liu, Y.Q., Majetich, S. A., Tilton, R. D. et al. (2005) TCE dechlorination rates, pathways, and efficiency of nanoscale iron particles with different properties. Environmental Science & Technology, 39(5), 1338-1345.
126. Wang, X.Y., Li, J., Liu, H. et al. (2008) Preparation and characterization of PAA/PVDF membrane-immobilized Pd/Fe nanoparticles for dechlorination of trichloroacetic acid. Water Research, 42(18), 4656-4664.
127. Xu, J. and Bhattacharyya, D. (2008) Modeling of Fe/Pd nanoparticle-based functionalized membrane reactor for PCB dechlorination at room temperature. Journal of Physical Chemistry C, 112(25), 9133-9144.
128. Xu, J. and Bhattacharyya, D. (2005) Membrane-based bimetallic nanoparticles for environmental remediation: Synthesis and reactive properties. Environmental Progress, 24(4), 358-366.
129. Xu, J., Dozier, A., and Bhattacharyya, D. (2005) Synthesis of nanoscale bimetallic particles in polyelectrolyte membrane matrix for reductive transformation of halogenated organic compounds. Journal of Nanoparticle Research, 7(4-5), 449-467.
130. Smuleac, V., Varma, R., Sikdar, S. et al. (2011) Green synthesis of Fe and Fe/Pd bimetallic nanoparticles in membranes for reductive degradation of chlorinated organics. Journal of Membrane Science, 379, (1-2), 131-137.
131. He, F., Liu, J., Roberts, C.B. et al. (2009) One-step "green" synthesis of Pd nanoparticles of controlled size and their catalytic activity for trichloroethene hydrodechlorination. Industrial & Engineering Chemistry Research, 48(14), 6550-6557.
132. Nadagouda, M.N. and Varma, R.S. (2007) A greener synthesis of core (Fe, Cu)-shell (An, Pt, Pd, and Ag) nanocrystals using aqueous vitamin C. Crystal Growth & Design, 7(12), 2582-2587.
133. Nadagouda, M.N. and Varma, R.S. (2008) Green synthesis of silver and palladium nanoparticles at room temperature using coffee and tea extract. Green Chemistry, 10(8), 859-862.
134. Nadagouda, M.N. et al. (2010) In vitro biocompatibility of nanoscale zerovalent iron particles (NZVI) synthesized using tea polyphenols. Green Chemistry, 12(1), 114-122.
135. Baruwati, B. and Varma, R.S. (2009) High value products from waste: Grape pomace extract-A three-in-one package for the synthesis of metal nanoparticles. Chemsuschem, 2(11), 1041-1044.
136. Virkutyte, J. and Varma, R.S. (2011) Green synthesis of metal nanoparticles: Biodegradable polymers and enzymes in stabilization and surface functionalization. Chemical Science, 2(5), 837-846.
137. Ferry, J.D. (1936) Statistical evaluation of sieve constants in ultrafiltration. Journal of General Physiology, 20(1), 95-104.
138. Lindau, J., Jonsson, A.S., and Bottino, A. (1998) Flux reduction of ultrafiltration membranes with different cut-off due to adsorption of a low-molecular-weight hydrophobic solute-correlation between flux decline and pore size. Journal of Membrane Science, 149(1), 11-20.
139. van den Berg, G.B., Racz, I.G., and Smolders, C.A. (1989) Mass-transfer coefficients in cross-flow ultrafiltration. Journal of Membrane Science, 47(1-2), 25-51.
140. Tu, S.C., Ravindran, V., Den W., et al. (2001) Predictive membrane transport model for nanofiltration precesses in water treatment. Aiche Journal, 47(6), 1346-1362.
141. Tu, S.C., Ravindran, V., and Pirbazari, M. (2005) A pore diffusion transport model for forecasting the performance of membrane processes. Journal of Membrane Science, 265(1-2), 29-50.
142. Wiley, D.E., Fell, C.J.D., and Fane, A.G. (1985) Optimization of membrane module design for brackish water desalination. Desalination, 52(3), 249-265.
143. Lu, Y., Spyra, P., Mei, Y. et al. (2007) Composite hydrogels: Robust carriers for catalytic nanoparticles. Macromolecular Chemistry and Physics, 208(3), 254-261.
144. Butterfield, D.A. (2008) An overview of biofunctional membranes for tunable separations, metal-ion capture, and enzyme catalysis based on research from the laboratories of Allan Butterfield and Dibakar Bhattacharyya. Separation Science and Technology, 43(16), 3942-3954.
145. Woodward, J. (1985) Immobilised Cells and Enzymes: A Practical Approach, Practical Approach Series, IRL Press, Oxford, England, Washington, DC, xiv, 177 p.
146. Cheryan, M. and Mehaia, M.A. (1986) Membrane bioreactors, in Membrane Separations in Biotechnology (ed. W.S. McGregor), Marcel Dekker, New York, pp. 255-295.
147. Liu, J.L.,Wang, J., Bachas, L.G. et al. (2001) Activity studies of immobilized subtilisin on functionalized pure cellulose-based membranes. Biotechnology Progress, 17(5), 866-871.
148. Nakamura, H. and Karube, I. (2003) Current research activity in biosensors. Analytical and Bioanalytical Chemistry, 377(3), 446-468.
149. Calvo, E.J., Danilowicz, C., Lagier, C. et al. (2004) Characterization of self-assembled redox polymer and antibody molecules on thiolated gold electrodes. Biosensors & Bioelectronics, 19(10), 1219-1228.
150. Harper, A. and Anderson, M.R. (2010) Electrochemical glucose sensorsdevelopments using electrostatic assembly and carbon nanotubes for biosensor construction. Sensors, 10(9), 8248-8274.
151. Yan, X.B., Chen, X.J., Tay, B.K. et al. (2007) Transparent and flexible glucose biosensor via layer-by-layer assembly of multi-wall carbon nanotubes and glucose oxidase. Electrochemistry Communications, 9(6), 1269-1275.
152. Datta, S., Cecil, C., and Bhattacharyya, D. (2008) Functionalized membranes by layer-by-layer assembly of polyelectrolytes and in situ polymerization of acrylic acid for applications in enzymatic catalysis. Industrial & Engineering Chemistry Research, 47(14), 4586-4597.
153. Smuleac, V., Butterfield, D.A., and Bhattacharyya, D. (2006) Layer-by-layerassembled microfiltration membranes for biomolecule immobilization and enzymatic catalysis. Langmuir, 22(24), 10118-10124.
154. Ying, L., Kang, E.T., and Neoh, K.G. (2002) Covalent immobilization of glucose oxidase on microporous membranes prepared from poly(vinylidene fluoride) with grafted poly(acrylic acid) side chains. Journal of Membrane Science, 208(1-2), 361-374.
155. Smuleac, V., Varma, R., Baruwati, B. et al. (2011) Nanostructured membranes for enzyme catalysis and green synthesis of nanoparticles, Chemsuschem, 4(12), 1773-1777.
156. Egueh, A.N.D., Lakard, B., Fievet, P. et al. (2010) Charge properties of membranes modified by multilayer polyelectrolyte adsorption. Journal of Colloid and Interface Science, 344(1), 221-227.
157. Khoo, X. and Grinstaff, M.W. (2011) Novel infection-resistant surface coatings: A bioengineering approach. MRS Bulletin, 36(05), 357-366.
158. Parton, R.F., Vankelecom, I.F.J., Casselman, M.J.A. et al. (1994) An efficient mimic of cytochrome-P-450 from a zeolite encaged iron complex in a polymer membrane. Nature, 370(6490), 541-544.
159. Shah, T.N., Goodwin, J.C., and Ritchie, S.M.C. (2005) Development and characterization of a microfiltration membrane catalyst containing sulfonated polystyrene grafts. Journal of Membrane Science, 251(1-2), 81-89.
160. Clark, L.C. and Lyons, C. (1962) Electrode systems for continuous monitoring in cardiovascular surgery. Annals of the New York Academy of Sciences, 102(1), 29-40.
161. Lu, P. and Hsieh, Y.L. (2010) Layer-by-layer self-assembly of Cibacron Blue F3GA and lipase on ultra-fine cellulose fibrous membrane. Journal of Membrane Science, 348(1-2), 21-27.
162. Dotzauer, D.A., Bhattacharjee, S., Wen Y. et al. (2009) Nanoparticle-containing membranes for the catalytic reduction of nitroaromatic compounds. Langmuir, 25(3), 1865-1871.
163. Pich, A., Karak, A., Lu,Y. et al. (2006) Preparation of hybrid microgels functionalized by silver nanoparticles. Macromolecular Rapid Communications, 27(5), 344-350.