Catalytic decomposition of hydrogen peroxide on iron oxide: Kinetics, mechanism, and implications

Environmental Science and Technology

Volumn 32, Issue 10, 1998, Pages 1417-1423

  Lin, Shu Sung ^a   Gurol, Mirat D ^b  

^a INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE   (Taiwan)

^b UTC Aerospace Systems   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CATALYSIS; CONTAMINATION; DECOMPOSITION; GRANULAR MATERIALS; IRON OXIDES; MASS TRANSFER; PARTICLE SIZE ANALYSIS; REACTION KINETICS; SOLUTIONS; WATER POLLUTION;

GRANULAR SIZE GOETHITE PARTICLES; LANGMUIR-HINSHELWOOD RATE MODEL;

HYDROGEN PEROXIDE;

FERRIC HYDROXIDE; HYDROGEN PEROXIDE; IRON OXIDE;

AQUEOUS SOLUTION; ARTICLE; ATMOSPHERIC DISPERSION; CATALYSIS; DECOMPOSITION; OXIDATION; WATER CONTAMINATION; WATER POLLUTANT;

EID: 0032524509     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es970648k     Document Type: Article

References (45)

1. Weiss, J. Trans. Faraday Soc. 1935, 31, 1547.
2. Weiss, J. Adv. Catal. 1952, 4, 343.
3. Roy, C. B. J. Catal. 1968, 12, 129.
4. Ono, Y.; Matsumura, T.; Kitajima, N.; Fukuzumi, S.-I. J. Phys. Chem. 1977, 81, 1307.
5. Kitajima, N.; Fukuzumi, S.-I.; Ono, Y. J. Phys. Chem. 1978, 82, 1505.
6. McKee, D. W. J. Catal. 1969, 14, 355.
7. Abbot, J.; Brown, D. G. Int. J. Chem. Kinet. 1990, 22, 963.
8. Dore, M. Water Res. 1990, 24, 973.
9. Tyre, B. W.; Watts, R. J.; Miller, G. C. J. Environ. Qual. 1991, 20, 832.
10. Watts, R. J.; Udell, M. D.; Monsen, R. M. Water Environ. Res. 1993, 65 (7), 839.
11. Ravikumar, J. X.; Gurol, M. D. Environ. Sci. Technol. 1994, 28, 394.
12. Gates, D. D.; Siegrist, R. L. J. Environ. Eng. 1995, Sept, 639-644.
13. Lin, S. S.; Gurol, M. D. In Proceedings of 27th Mid-Atlantic Industrial Waste Conference, Bethlehem, PA; Technomic: Lancaster, PA, 1995; p 352.
14. Miller, C. M.; Valentine, R. L. Water Res. 1996, 29 (10), 2353.
15. Lin, S.-S. Ph.D. Dissertation, Drexel University, Philadelphia, PA, 1997.
16. Moffett, J. D.; Zika, R. G. Environ. Sci. Technol., 1987, 21, 804.
17. Cunningham, K. M.; Goldberg, M. C.; Winer, E. R. Environ. Sci. Technol. 1988, 22, 1090.
18. Gurol, M. D.; Lin, S. S.; Bhat, N.; Lin, S. Presented at the Advanced Chemical Oxidation Conference, San Francisco, CA, 1997.
19. Bolt, G. H.; van Riemdijk, W. H. In Aquatic Surface Chemistry; Stumm, W., Ed.; Wiley-Interscience: New York, 1987; p 127.
20. Stumm, W.; Morgan, J. J. Aquatic Chemistry, 3rd ed.; Wiley-Interscience: New York, 1996.
21. Levenspiel, O. Chemical Engineering Reaction; Wiley-Eastern Limited: New York, 1972.
22. Tatterson, G. B. Scale-up and Design of Industrial Mixing Processes; McGraw-Hill: New York, 1994; pp 134-145.
23. Sigg, L.; Stumm, W. Colloids Surf. 1980, 2, 101-117.
24. Standard Methods for the Examination of Water and Wastewater; APHA, AWWA, WEF: Washington, DC, 1992.
25. Sulzberger, B.; Laubscher, H. Mar. Chem. 1995, 50, 103-113.
26. Pehkonen, S. O.; Sieferet, R. L.; Webb, S.; Hoffmann, M. R. Environ. Sci. Technol. 1993, 27, 2056-2062.
27. Sieffert, C.; Sulzberger, B. Langmuir 1991, 7, 1627-1634.
28. Wang, A. H.; Valentine, R. L. In Proceedings of the Third International Symposium on Chemical Oxidation: Technology for the Nineties, Nashville, TN; Technomic: Lancaster, PA, 1993; p 74.
29. Sherwood, T. K.; Pigford, R. L.; Wilke, C. Mass Transfer; McGraw-Hill: New York, 1975; p 222.
30. Kung, K.-H.; McBride, M. B. Soil Sci. Soc. Am. J. 1989, 53, 1673.
31. Martin, L. R.; Easton, M.; Foster, J. W.; Hill, M. W. Atmos. Environ. 1989, 23, 563.
32. Eary, L. E. Metall. Trans. B. 1986, 16B, 181.
33. Barb, W. G.; Baxendale, J. H.; George, D.; and Hargrave, K. R. Faraday Soc. Trans. 1959, 47, 591.
34. Pignatello, J. J. Environ. Sci. Technol. 1992, 26, 944.
35. Walling, C.; Weil T. Int. J. Chem. Kinet. 1974, 5, 507.
36. Walling, C.; Cleary, M. Int. J. Chem. Kinet. 1977, 9, 595.
37. Haber, F.; Weiss, J. Proc. R. Soc. Ser. 1934, T27, 332-351.
38. Rush, J. D.; Bielski, B. H. J. Phys. Chem. 1985, 89, 5062.
39. Moffett, J. D.; Zika, R. G. Environ. Sci. Technol. 1987, 21, 804.
40. Buxton, G. V.; Greenstock, C. L.; Helman, W. P.; Ross, A. B. J. Phys. Chem. Ref. Data 1988, 17, 5T1.
41. Xue, Y.; Traina, S. J. Environ. Sci. Technol. 1996, 30, 1975-1981.
42. Singer, P. C.; Stumm, W. Science 1970, 167, 1121-1123.
43. Ollis, D. F.; Serpone, N.; Pelizzetti, E. In Photocatalysis Fundamentals and Applications; Serpone, N., Pelizzetti, E., Eds.; Wiley: New York, 1989; pp 603-638.
44. Stumm, W.; Sulzberger, B. Geochim. Cosmochim. Acta 1992, 56, 3233.
45. Behar, D.; Czapski, G.; Rabani, J.; Dorfman, L. M.; Schwarz, H. A. J. Phys. Chem. 1970, 74, 3209-3211.