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Volumn 117, Issue 40, 2013, Pages 20746-20761

Voltammetry can reveal differences between the potential energy curve (pec) and density of states (dos) models for heterogeneous electron transfer

Author keywords

[No Author keywords available]

Indexed keywords

BUTLER-VOLMER KINETICS; COUPLING STRENGTHS; CYCLIC VOLTAMMOGRAMS; ELECTRONIC COUPLING; HETEROGENEOUS ELECTRON TRANSFER; POTENTIAL ENERGY CURVES; REORGANIZATION ENERGIES; REVERSIBLE REDOX REACTIONS;

EID: 84885611864     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4071532     Document Type: Article
Times cited : (5)

References (38)
  • 1
    • 70449553656 scopus 로고    scopus 로고
    • A Unified Model for the Electrochemical Rate Constant That Incorporates Solvent Dynamics
    • Mishra, A. K.; Waldeck, D. H. A Unified Model for the Electrochemical Rate Constant That Incorporates Solvent Dynamics J. Phys. Chem. C 2009, 113, 17904-17914
    • (2009) J. Phys. Chem. C , vol.113 , pp. 17904-17914
    • Mishra, A.K.1    Waldeck, D.H.2
  • 2
    • 80054888810 scopus 로고    scopus 로고
    • Comparison of the Density of States (dos) and Potential Energy Curve (pec) Models for the Electrochemical Rate Constant
    • Mishra, A. K.; Waldeck, D. H. Comparison of the Density of States (dos) and Potential Energy Curve (pec) Models for the Electrochemical Rate Constant J. Phys. Chem. C 2011, 115, 20662-20673
    • (2011) J. Phys. Chem. C , vol.115 , pp. 20662-20673
    • Mishra, A.K.1    Waldeck, D.H.2
  • 3
    • 2342625026 scopus 로고
    • A Theory of Adiabatic Electron-Transfer Reactions
    • Schmickler, W. A Theory of Adiabatic Electron-Transfer Reactions J. Eletroanal. Chem. 1986, 204, 31-43
    • (1986) J. Eletroanal. Chem. , vol.204 , pp. 31-43
    • Schmickler, W.1
  • 4
    • 36549101202 scopus 로고
    • Electrochemical Electron Transfer: Accounting for Electron-Hole Excitations in the Metal Electrode
    • Sebastian, K. L. Electrochemical Electron Transfer: Accounting for Electron-Hole Excitations in the Metal Electrode J. Chem. Phys. 1989, 90, 5056-5067
    • (1989) J. Chem. Phys. , vol.90 , pp. 5056-5067
    • Sebastian, K.L.1
  • 5
    • 0037043942 scopus 로고    scopus 로고
    • The Rate of Electrochemical Electron-Transfer Reactions
    • Schmickler, W.; Mohr, J. The Rate of Electrochemical Electron-Transfer Reactions J. Chem. Phys. 2002, 117, 2867-2872
    • (2002) J. Chem. Phys. , vol.117 , pp. 2867-2872
    • Schmickler, W.1    Mohr, J.2
  • 6
    • 3242668981 scopus 로고    scopus 로고
    • Potential energy surface for an electron transfer reaction mediated by a metal adlayer
    • Mishra, A. K.; Schmickler, W. Potential energy surface for an electron transfer reaction mediated by a metal adlayer J. Chem. Phys. 2004, 121, 1020-1028
    • (2004) J. Chem. Phys. , vol.121 , pp. 1020-1028
    • Mishra, A.K.1    Schmickler, W.2
  • 7
    • 2842617037 scopus 로고
    • Localized Magnetic States in Metals
    • Anderson, P. W. Localized Magnetic States in Metals Phys. Rev. 1961, 124, 41-53
    • (1961) Phys. Rev. , vol.124 , pp. 41-53
    • Anderson, P.W.1
  • 8
    • 4243656226 scopus 로고
    • Self-Consistent Model of Hydrogen Chemisorption
    • Newns, D. M. Self-Consistent Model of Hydrogen Chemisorption Phys. Rev. 1969, 178, 1123-1135
    • (1969) Phys. Rev. , vol.178 , pp. 1123-1135
    • Newns, D.M.1
  • 11
    • 0000333276 scopus 로고
    • Kinetics of Oxidation-Reduction Reactions on Metals and Semiconductors. I. General Remarks on the Electron Transition between a Solid Body and a Reduction-Oxidation Electrolyte
    • Gerischer, H. Kinetics of Oxidation-Reduction Reactions on Metals and Semiconductors. I. General Remarks on the Electron Transition between a Solid Body and a Reduction-Oxidation Electrolyte Z. Phys. Chem. NF 1960, 26, 233-247
    • (1960) Z. Phys. Chem. NF , vol.26 , pp. 233-247
    • Gerischer, H.1
  • 12
    • 33750115457 scopus 로고
    • Kinetics of Oxidation-Reduction Reactions on Metals and Semiconductors. II. Metal Electrodes
    • Gerischer, H. Kinetics of Oxidation-Reduction Reactions on Metals and Semiconductors. II. Metal Electrodes Z. Phys. Chem. NF 1960, 26, 325-338
    • (1960) Z. Phys. Chem. NF , vol.26 , pp. 325-338
    • Gerischer, H.1
  • 13
    • 4043050874 scopus 로고
    • Kinetics of Reduction-Oxidation Reaction on Metals and Semiconductors. III. Semiconductor Electrodes
    • Gerischer, H. Kinetics of Reduction-Oxidation Reaction on Metals and Semiconductors. III. Semiconductor Electrodes Z. Phys. Chem. NF 1961, 27, 48-79
    • (1961) Z. Phys. Chem. NF , vol.27 , pp. 48-79
    • Gerischer, H.1
  • 15
    • 23644447299 scopus 로고
    • Theory of Electron-Transfer Processes via Chemisorbed Intermediates
    • Mishra, A. K.; Rangarajan, S. K. Theory of Electron-Transfer Processes via Chemisorbed Intermediates J. Phys. Chem. 1987, 91, 3417-3425
    • (1987) J. Phys. Chem. , vol.91 , pp. 3417-3425
    • Mishra, A.K.1    Rangarajan, S.K.2
  • 16
    • 0007247040 scopus 로고
    • Electron Transfer through Film-Covered Surfaces. Case of Monolayer Submonolayer - A Coherent Potential Approximation Formalism
    • Mishra, A. K.; Rangarajan, S. K. Electron Transfer through Film-Covered Surfaces. Case of Monolayer Submonolayer-A Coherent Potential Approximation Formalism J. Phys. Chem. 1987, 91, 3425-3430
    • (1987) J. Phys. Chem. , vol.91 , pp. 3425-3430
    • Mishra, A.K.1    Rangarajan, S.K.2
  • 17
    • 5744249946 scopus 로고
    • Electron Transfer through Monolayers: Dependence of Current on Potential and Coverage
    • Mishra, A. K.; Bhattacharjee, B.; Rangarajan, S. K. Electron Transfer through Monolayers: Dependence of Current on Potential and Coverage J. Eletroanal. Chem. 1991, 318, 387-393
    • (1991) J. Eletroanal. Chem. , vol.318 , pp. 387-393
    • Mishra, A.K.1    Bhattacharjee, B.2    Rangarajan, S.K.3
  • 18
    • 5744237023 scopus 로고
    • Theory of Electron Transfer Processes via Chemisorbed Intermediates: Part II. Current-Potential Characteristics
    • Mishra, A. K.; Bhattacharjee, B.; Rangarajan, S. K. Theory of Electron Transfer Processes via Chemisorbed Intermediates: Part II. Current-Potential Characteristics J. Eletroanal. Chem. 1992, 331, 801-813
    • (1992) J. Eletroanal. Chem. , vol.331 , pp. 801-813
    • Mishra, A.K.1    Bhattacharjee, B.2    Rangarajan, S.K.3
  • 19
    • 0007184651 scopus 로고    scopus 로고
    • Scanning Tunnelling Microscopy Currents in the Presence of A Chemisorbate
    • Mishra, A. K.; Rangarajan, S. K. Scanning Tunnelling Microscopy Currents in the Presence of A Chemisorbate THEOCHEM 1996, 361, 101-109
    • (1996) THEOCHEM , vol.361 , pp. 101-109
    • Mishra, A.K.1    Rangarajan, S.K.2
  • 20
    • 0001281260 scopus 로고    scopus 로고
    • Exactly Solvable Quantum Model for Electrochemical Electron-Transfer Reactions
    • Mohr, J.-H.; Schmickler, W. Exactly Solvable Quantum Model for Electrochemical Electron-Transfer Reactions Phys. Rev. Lett. 2000, 84, 1051-1054
    • (2000) Phys. Rev. Lett. , vol.84 , pp. 1051-1054
    • Mohr, J.-H.1    Schmickler, W.2
  • 21
    • 33646246391 scopus 로고    scopus 로고
    • A Model for Electrochemical Electron Transfer with Strong Electronic Coupling
    • Mohr, J.; Schmickler, W.; Badiali, J. P. A Model for Electrochemical Electron Transfer with Strong Electronic Coupling Chem. Phys. 2006, 324, 140-147
    • (2006) Chem. Phys. , vol.324 , pp. 140-147
    • Mohr, J.1    Schmickler, W.2    Badiali, J.P.3
  • 23
    • 79959288898 scopus 로고    scopus 로고
    • Electron Transfer Reaction through An Adsorbed Layer
    • Cruz, A. V. B.; Mishra, A. K. Electron Transfer Reaction through An Adsorbed Layer J. Electroanal. Chem. 2011, 659, 50-57
    • (2011) J. Electroanal. Chem. , vol.659 , pp. 50-57
    • Cruz, A.V.B.1    Mishra, A.K.2
  • 26
    • 84868587293 scopus 로고    scopus 로고
    • Probing the Effect of the Solution Environment around Redox-Active Moieties Using Rigid Anthraquinone Terminated Molecular Rulers
    • Darwish, N.; Eggers, P. K.; Ciampi, S.; Tong, Y.; Ye, S.; Paddon-Row, M. N.; Gooding, J. J. Probing the Effect of the Solution Environment around Redox-Active Moieties Using Rigid Anthraquinone Terminated Molecular Rulers J. Am. Chem. Soc. 2012, 134, 18401-18409
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 18401-18409
    • Darwish, N.1    Eggers, P.K.2    Ciampi, S.3    Tong, Y.4    Ye, S.5    Paddon-Row, M.N.6    Gooding, J.J.7
  • 27
    • 84864221204 scopus 로고    scopus 로고
    • Self-Assembled Monolayers of Aβ peptides on Au Electrodes: An Artificial Platform for Probing the Reactivity of Redox Active Metals and Cofactors Relevant to Alzheimer's Disease
    • Pramanik, D.; Sengupta, K.; Mukherjee, S.; Dey, S. G.; Dey, A. Self-Assembled Monolayers of Aβ peptides on Au Electrodes: An Artificial Platform for Probing the Reactivity of Redox Active Metals and Cofactors Relevant to Alzheimer's Disease J. Am. Chem. Soc. 2012, 134, 12180-12189
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 12180-12189
    • Pramanik, D.1    Sengupta, K.2    Mukherjee, S.3    Dey, S.G.4    Dey, A.5
  • 28
    • 84869392131 scopus 로고    scopus 로고
    • Polycation Induced Potential Dependent Structural Transitions of Oligonucleotide Monolayers on Au(111)-Surfaces
    • Salvatore, P.; Karlsen, K. K.; Hansen, A. G.; Zhang, J.; Nichols, R. J.; Ulstrup, J. Polycation Induced Potential Dependent Structural Transitions of Oligonucleotide Monolayers on Au(111)-Surfaces J. Am. Chem. Soc. 2012, 134, 19092-19098
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 19092-19098
    • Salvatore, P.1    Karlsen, K.K.2    Hansen, A.G.3    Zhang, J.4    Nichols, R.J.5    Ulstrup, J.6
  • 30
    • 49249148639 scopus 로고
    • General Expression of the Linear Potential Sweep Voltammogram in the Case of Diffusionless Electrochemical Systems
    • Laviron, E. General Expression of the Linear Potential Sweep Voltammogram in the Case of Diffusionless Electrochemical Systems J. Eletroanal. Chem. 1979, 101, 19-28
    • (1979) J. Eletroanal. Chem. , vol.101 , pp. 19-28
    • Laviron, E.1
  • 31
    • 0010884753 scopus 로고
    • On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. i
    • Marcus, R. A. On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I J. Chem. Phys. 1956, 24, 966-978
    • (1956) J. Chem. Phys. , vol.24 , pp. 966-978
    • Marcus, R.A.1
  • 32
    • 0010047929 scopus 로고
    • Theory of Charge Transfer Kinetics at Solid-Polar Liquid Interfaces
    • Dogonadze, R. R.; Kuznetsov, A. M. Theory of Charge Transfer Kinetics at Solid-Polar Liquid Interfaces Prog. Surf. Sci. 1975, 6, 1-41
    • (1975) Prog. Surf. Sci. , vol.6 , pp. 1-41
    • Dogonadze, R.R.1    Kuznetsov, A.M.2
  • 33
    • 0000486126 scopus 로고
    • Cyclic Voltammetric Analysis of Ferrocene Alkanethiol Monolayer Electrode Kinetics Based on Marcus Theory
    • Tender, L.; Carter, M. T.; Murray, R. W. Cyclic Voltammetric Analysis of Ferrocene Alkanethiol Monolayer Electrode Kinetics Based on Marcus Theory Anal. Chem. 1994, 66, 3173-3181
    • (1994) Anal. Chem. , vol.66 , pp. 3173-3181
    • Tender, L.1    Carter, M.T.2    Murray, R.W.3
  • 34
    • 0001554306 scopus 로고
    • Voltammetry of Redox-Active Groups Irreversibly Adsorbed onto Electrodes. Treatment Using the Marcus Relation between Rate and Overpotential
    • Weber, K.; Creager, S. E. Voltammetry of Redox-Active Groups Irreversibly Adsorbed onto Electrodes. Treatment Using the Marcus Relation between Rate and Overpotential Anal. Chem. 1994, 66, 3164-3172
    • (1994) Anal. Chem. , vol.66 , pp. 3164-3172
    • Weber, K.1    Creager, S.E.2
  • 35
    • 0344339180 scopus 로고    scopus 로고
    • Effect of Electron-Transfer Rate and Reorganization Energy on the Cyclic Voltammetric Response of Redox Adsorbates
    • Honeychurch, M. J. Effect of Electron-Transfer Rate and Reorganization Energy on the Cyclic Voltammetric Response of Redox Adsorbates Langmuir 1999, 15, 5158-5163
    • (1999) Langmuir , vol.15 , pp. 5158-5163
    • Honeychurch, M.J.1
  • 36
    • 0022004980 scopus 로고
    • Electron Transfers in Chemistry and Biology
    • Marcus, R. A.; Sutin, N. Electron Transfers in Chemistry and Biology Biochim. Biophys. Acta 1985, 811, 265-322
    • (1985) Biochim. Biophys. Acta , vol.811 , pp. 265-322
    • Marcus, R.A.1    Sutin, N.2
  • 37
    • 0035899737 scopus 로고    scopus 로고
    • The Nature of Electronic Coupling between Ferrocene and Gold through Alkanethiolate Monolayers on Electrodes: The Importance of Chain Composition, Interchain Coupling, and Quantum Interference
    • Napper, A. M.; Liu, H.; Waldeck, D. H. The Nature of Electronic Coupling between Ferrocene and Gold through Alkanethiolate Monolayers on Electrodes: The Importance of Chain Composition, Interchain Coupling, and Quantum Interference J. Phys. Chem. B 2001, 105, 7699-7707
    • (2001) J. Phys. Chem. B , vol.105 , pp. 7699-7707
    • Napper, A.M.1    Liu, H.2    Waldeck, D.H.3
  • 38
    • 59449104089 scopus 로고    scopus 로고
    • Direct Monitoring of Ultrafast Redox Commutation at the Nanosecond and Nanometer Scales by Ultrafast Voltammetry: From Molecular Wires to Cation Releasing Systems
    • Amatore, C.; Maisonhaute, E.; Nierengarten, J.-F.; Schöllhorn, B. Direct Monitoring of Ultrafast Redox Commutation at the Nanosecond and Nanometer Scales by Ultrafast Voltammetry: From Molecular Wires to Cation Releasing Systems Isr. J. Chem. 2008, 48, 203-214
    • (2008) Isr. J. Chem. , vol.48 , pp. 203-214
    • Amatore, C.1    Maisonhaute, E.2    Nierengarten, J.-F.3    Schöllhorn, B.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.