Comparison of the Density of States (dos) and Potential Energy Curve (pec) models for the electrochemical rate constant

Journal of Physical Chemistry C

Volumn 115, Issue 42, 2011, Pages 20662-20673

  Mishra, A K ^a   Waldeck, David H ^b  

^a INSTITUTE OF MATHEMATICAL SCIENCES   (India)

^b UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COUPLING STRENGTHS; DENSITY OF STATE; ELECTROCHEMICAL ELECTRON; ELECTROCHEMICAL RATE CONSTANTS; ELECTRODE KINETICS; ELECTRON TRANSFER RATES; ELECTRONIC COUPLING; FERROCENES; GOLD ELECTRODES; METHYLENE GROUPS; NON-ADIABATIC; ORDERS OF MAGNITUDE; OVERPOTENTIAL; POTENTIAL ENERGY CURVES; RATE EXPRESSION; TRANSITION STATE THEORIES;

ELECTRON TRANSITIONS; ENERGY BARRIERS; IRON COMPOUNDS; POTENTIAL ENERGY; RATE CONSTANTS;

ACTIVATION ENERGY;

EID: 80054888810     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp204221g     Document Type: Article

References (30)

1. Mishra, A. K.; Waldeck, D. H. J. Phys. Chem. C 2009, 113, 17904
2. Miller, R. J. D.; McLendon, G. L.; Nozik, A. J.; Schmickler, W.; Willig, F. Surface Electron Transfer Processes; VCH Publishers, Inc.: Weinheim, Germany, 1995.
3. Kuznetsov, A. M. Charge Transfer in Physics, Chemistry and Biology; Gordon and Beach: Reading, MA, 1995.
4. Schmickler, W. J. Electroanal. Chem. 1986, 204, 31
5. Mishra, A. K.; Schmickler, W. J. Chem. Phys. 2004, 121, 1020
6. Schmickler, W.; Mohr, J. J. Chem. Phys. 2002, 117, 2867
7. Gerischer, H. Z. Phys. Chem. NF 1960, 26, 223
8. 1961, 27, 40.
9. 1961, 27, 48.
10. Miller, C. J. Heterogeneous Electron Transfer Kinetics at Metallic Electrodes. In Physical Electrochemistry, Principles, Methods and Applications; Rubinstein, I., Ed.; Marcel Dekker: New York, 1995; p 27.
11. Marcus, R. A. Annu. Rev. Phys. Chem. 1964, 15, 155
12. Dogonadze, R. R.; Kuznetsov, A. M. Prog. Surf. Sci. 1975, 6, 1
13. Schmickler, W. J. Electroanal. Chem. 1980, 113, 159
14. Mishra, A. K.; Rangarajan, S. K. J. Phys. Chem. 1987, 91, 3417
15. Mishra, A. K.; Bhattacharjee, B.; Rangarajan, S. K. J. Electroanal. Chem. 1992, 331, 801
16. Mishra, A. K.; Rangarajan, S. K. J. Phys. Chem. 1987, 91, 3425
17. Mishra, A. K.; Bhattacharjee, B.; Rangarajan, S. K. J. Electroanal. Chem. 1991, 318, 387
18. Mishra, A. K.; Rangarajan, S. K. THEOCHEM 1996, 361, 101
19. Mohr, J.; Schmickler Phys. Rev. Lett. 2000, 84, 1051
20. Mohr, J.; Schmickler, W.; Badiali, J. P. Chem. Phys. 2006, 324, 140
21. Galperin, M.; Ratner, M. A.; Nitzan, A. J. Phys.: Condens Matter 2007, 19, 103201
22. Schmidt, P. P. Spec. Period. Rep. (Electrochemistry); Chem. Soc., London 1978, 6, 128
23. Napper, A. M.; Liu, H.; Waldeck, D. H. J. Phys. Chem. B 2001, 105, 7699
24. Hall, L. E.; Reimers, J. R.; Hush, N. S.; Silverbrook, K. J. Chem. Phys. 2000, 112, 1510
25. Zimmt, M. B.; Waldeck, D. H. J. Phys. Chem. A 2003, 107, 3580
26. Smalley, J. F.; Finklea, H. O.; Chidsey, C. E. D.; Linford, M. R.; Creager, S. E.; Ferraris, J. P.; Chalfant, K.; Zawodzinsk, T.; Feldberg, S. W.; Newton, M. D. J. Am. Chem. Soc. 2003, 125, 2004
27. Waldeck, D. H.; Khoshtariya, D. E. Modern Aspects of Electrochemistry; Noam, E., Ed.; Springer: New York, 2011; Vol. 52, in press.
28. Khoshtariya, D. E.; Wei, J.; Liu, H.; Yue, H. J. J. Am. Chem. Soc. 2003, 125, 7704
29. Khoshtariya, D. E.; Dolidze, T. D.; Zusman, L. D.; Waldeck, D. H. J. Phys. Chem. 2001, 105, 1818
30. Mc Manis, G. E.; Mishra, A. K.; Weaver, M. J. J. Chem. Phys. 1987, 86, 5550