Utility of experimental design in pre-column derivatization for the analysis of tobramycin by hplc fluorescence detection: Application to ophthalmic solution and human plasma

Analytical Chemistry Insights

Volumn 8, Issue 1, 2013, Pages 9-20

  El Zaher, Asmaa A ^a   Mahrouse, Marianne A ^a  

^a CAIRO UNIVERSITY   (Egypt)

Author keywords

Derivatization; Experimental design; Fluorescamine; HPLC; Plasma; Tobramycin

Indexed keywords

EID: 84885360580     PISSN: None     EISSN: 11773901     Source Type: Journal    
DOI: 10.4137/ACI.S11612     Document Type: Article

References (40)

1. Sweetman SC. Martindale, The Complete Drug Reference, 36th ed. London, Chicago: The Pharmaceutical Press; 2009:354.
2. Kalant H, Grant DM, Mitchell J. Principles of Medical Pharmacology, 7th ed. Elsevier Canada, a division of Reed Elsevier Canada, Ltd.; 2007:699-702.
3. Kumar P, Clark M. Clinical Medicine A Textbook for Medical Students and Doctors, 6th ed. Toronto, Tokyo: W.B. Saunders, Harcourt Brace and Company Limited; 2005;14.
4. Attema-de Jonge ME, Bekkers JM, Oudemans-van Straaten HM, Sparidans RW, Franssen EJF. Simple and sensitive method for quantification of low tobramycin concentrations in human plasma using HPLC-MS/MS. J Chromatogr B Analyt Technol Biom Life Sci. 2008;862(1-2):257-62.
5. Rang HP, Dale MM, Ritter JM, Flower RJ. Rang and Dale's Pharmacology, 7th ed. Churchill livingstone, Elsevier; 2012:670-1.
6. Abdel Ghany MF, El Kosasy AM, Ayad MF, Abdel Fattah LE. Spectrophotometric and spectrofluorimetric determination of gentamicin and tobramycin using 1,4-benzoquinone. Bull Fac Pharm Cairo Univ. 2003; 41(1):69-88.
7. El Kosasy AM, Abdel Ghany MF, Ayad MF, Abdel Fattah LE. Colorimetric and spectrofluorimetric determination of gentamicin and tobramycin in pure, dosage forms and in mixture with dexamethazone. Bull Fac Pharm Cairo Univ. 2003;41(1):89-108.
8. Li W, Wu F, Zhang S. Determination of tobramycin eye drops by acid dye colorimetry. Yaoxue Jinzhan. 2011;35(3):133-5.
9. Shantier SW, Gadkariem EA, Ibrahim KE, Hagga ME. Kinetic determination of tobramycin in drug formulations. Res J Pharm Biolog Chem Sci. 2012;3(1):566-73.
10. El-Shabrawy Y. Fluorometric determination of aminoglycoside antibiotics in pharmaceutical preparations and biological fluids. Spectrosc Lett. 2002;35(1):99-109.
11. El-Attug MN, Hoogmartens J, Adams E, Van Schepdael A. Optimization of capillary electrophoresis method with contactless conductivity detection for the analysis of tobramycin. J Pharm Biomed Anal. 2012;58:49-57.
12. El Kosasy AM Abdel Ghany MF, Ayad MF, Abdel Fattah LE. TLC and scanning densitometric method for determination of gentamicin and tobramycin in pure, dosage forms and in mixture with dexamethazone. Bull Fac Pharm Cairo Univ. 2003;41(2):169-77.
13. Hubicka U, Krzek J, Woltynska H, Stachacz B. Simultaneous identification and quantitative determination of selected aminoglycoside antibiotics by thin-layer chromatography and densitometry. J AOAC Int. 2009;92(4): 1068-75.
14. Megoulas NC, Koupparis MA. Development and validation of a novel HPLC/ELSD method for the direct determination of tobramycin in pharmaceuticals, plasma and urine. Anal Bioanal Chem. 2005;382(2):290-6.
15. Clarot I, Storme-Paris I, Chaminade P, Estevenon O, Nicolas A, Rieutord A. Simultaneous quantitation of tobramycin and colistin sulphate by HPLC with evaporative light scattering detection. J Pharm Biomed Anal. 2009; 50(1):64-7.
16. Hanko VP, Rohrer JS. Determination of tobramycin and impurities using hig-performance anion exchange chromatography with integrated pulsed amperometric detection. J Pharm Biomed Anal. 2006;40(4):1006-12.
17. Keevil BG, Lockhart SJ, Cooper DP. Determination of tobramycin in serum using liquid chromatography-tandem mass spectrometry and comparison with a fluorescence polarization assay. J Chromatogr B Analyt Technol Biom Life Sci. 2003;794(2):329-35.
18. Cheng C, Liu S, Xiao D, Hansel S. The application of trichloroacetic acid as an ion-pairing reagent in LC-MS-MS method development for highly polar aminoglycoside compounds. Chromatographia. 2010;72(1-2):133-9.
19. Block JH, Beale JM. Wilson and Gisvold's Textbook of Organic Medicinal and Pharmaceutical Chemistry, 11th ed. Philadelphia: Lippincott Williams & Wilkins, A Wolters Kluwer Company; 2004:345.
20. Dash AK. Analytical Profiles of Drug Substances and Excipients, 24, London, Toronto; Academic Press, Inc.; 1996:579-613.
21. Mashat M, Chrystyn H, Clark BJ, Assi KH. Development and validation of HPLC method for the determination of tobramycin in urine samples post-inhalation using pre-column derivatisation with fluorescein isothiocyanate. J Chromatogr B Analyt Technol Biom Life Sci. 2008;869(1-2):59-66.
22. Yang M, Tomellini SA. Non-derivatization approach to high-performance liquid chromatography-fluorescence detection for aminoglycoside antibiotics based on a ligand displacement reaction. J Chromatogr A. 2001; 939(1-2):59-67.
23. Dash AK, Suryanarayanan R. A liquid-chromatographic method for the determination of tobramycin. J Pharm Biomed Ana. 1991;9(3):237-45.
24. Barends DM, Brouwers JCAM, Hulschoof A. Fast pre-column derivatization of aminoglycosides with 1-fluoro-2,4-dinitrobenzene and its application to pharmaceutical analysis. J Pharm Biomed Anal. 1987;5(6):613-7.
25. The United States Pharmacopeia (USP 30). The National Formulary (NF 25), Asian Ed.; 2007:3367-74.
26. Lai F, Sheehan T. Enhancement of detection sensitivity and cleanup selectivity for tobramycin through pre-column derivatization. J Chromatogr. 1992;609(1-2):173-9.
27. Walash MI, Belal F, El-Enany N, El-Maghrabey MH. Simple and sensitive spectrofluorimetric method for the determination of pregabalin in capsules through derivatization with fluorescamine. Luminescence. 2011;26(5): 342-8.
28. Miller JN, Miller JC. Statistics and Chemometrics for Analytical Chemistry, 6th ed. England: Pearson education Limited; 2010:186-216.
29. Khamanga SM, Walker RB. The use of experimental design in the development of an HPLC-ECD method for the analysis of captopril. Talanta. 2011;83(3):1037-49.
30. Sampath S, Robinson DH. Comparison of new and existing spectrophotometric methods for the analysis of tobramycin and other aminoglycosides. J Pharm Sci. 1990;79(5):428-31.
31. Toro G, Ackermann PG. Practical Clinical Chemistry, 1st ed. Boston: Little, Brown and Company; 1975:740.
32. Deming SN, Morgan SL. Experimental Design: A Chemometric Approach, 2nd ed. Amsterdam, London, New York: Tokyo Elsevier Publishers; 1991: 151-69, 227-74.
33. Rose J. Advanced Physicochemical Experiments. London, Pitman; 1964:67.
34. Mascher HJ, Kikuta C. Determination of amoxicillin in human serum and plasma by high-performance liquid chromatography and on-line postcolumn derivatisation. J Chromatogr A. 1998;812(1-2):221-6.
35. Aydogmas Z. Simple and sensitive spectrofluorimetric method for the determination of oseltamivir phosphate in capsules through derivatization with fluorescamine. J fluoresce. 2009;19(4):673-9.
36. Udenfriend S, Stein S, Böhlen P, Dairman W, Leimgruber W, Weigele M. Fluorescamine A Reagent for Assay of Amino Acids, Peptides, Proteins, and Primary Amines in the Picomole Range, Science. 1972;178:871-2.
37. Awotwe-Otoo D, Agarabi C, Faustino PJ, et al. Application of quality by design elements for the development and optimization of an analytical method for protamine sulfate. J Pharm Biomed Anal. 2012;62:61-7.
38. Wang H, Tor Y. Electrostatic interactions in RNA aminoglycosides binding. J Am Chem Soc. 1997;119:8734-5.
39. [2Q] (R1) Validation of analytical procedures, Proceedings of the International Conference on Harmonisation (ICH), Geneva. Commission of the European Communities (1996).
40. Muchohi SN, Thuo N, Karisa J, Muturi A, Kokwaro GO, Maitland K. Determination of ciprofloxacin in human plasma using high-performance liquid chromatography coupled with fluorescence detection: application to a population pharmacokinetics study in children with severe malnutrition. J Chromatogr B. 2011;879(2):146-52.