Cooperative catalysis of metal and O-H⋯O/sp3-C-H⋯O two-point hydrogen bonds in alcoholic solvents: Cu-catalyzed enantioselective direct alkynylation of aldehydes with terminal alkynes

Chemistry - A European Journal

Volumn 19, Issue 40, 2013, Pages 13547-13553

  Ishii, Takaoki ^a   Watanabe, Ryo ^b   Moriya, Toshimitsu ^a   Ohmiya, Hirohisa ^a   Mori, Seiji ^b   Sawamura, Masaya ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

^b IBARAKI UNIVERSITY   (Japan)

Author keywords

asymmetric catalysis; cooperative catalysis; copper; density functional calculations; hydrogen bonds

Indexed keywords

ALCOHOLS; ALDEHYDES; CATALYSIS; CATALYSTS; COPPER; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; HYDROCARBONS; LIGANDS; SOLVENTS; SUBSTRATES;

ASYMMETRIC CATALYSIS; COOPERATIVE CATALYSIS; ENANTIOSELECTIVE CATALYSIS; HIGH ENANTIOSELECTIVITY; HYDROGEN BONDING INTERACTIONS; QUANTUM-MECHANICAL CALCULATION; SECONDARY INTERACTIONS; TRANSITION-METAL CENTERS;

HYDROGEN BONDS;

ALDEHYDE; ALKYNE; COPPER; SOLVENT;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; COOPERATIVE CATALYSIS; DENSITY FUNCTIONAL CALCULATIONS; HYDROGEN BOND; HYDROGEN BONDS; STEREOISOMERISM;

ASYMMETRIC CATALYSIS; COOPERATIVE CATALYSIS; COPPER; DENSITY FUNCTIONAL CALCULATIONS; HYDROGEN BONDS;

ALDEHYDES; ALKYNES; CATALYSIS; COPPER; HYDROGEN BONDING; MOLECULAR STRUCTURE; SOLVENTS; STEREOISOMERISM;

EID: 84884819280     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201301280     Document Type: Article

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