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Volumn 42, Issue 40, 2013, Pages 14583-14602

Catalyst activity or stability: The dilemma in Pd-catalyzed polyketone synthesis

Author keywords

[No Author keywords available]

Indexed keywords

BONDING PROPERTY; CATALYTIC SYSTEM; COPOLYMERIZATION REACTIONS; DIMERIC SPECIES; ELECTRON-WITHDRAWING SUBSTITUENTS; KINETIC INVESTIGATIONS; METALLIC PALLADIUM; REACTION PROFILE;

EID: 84884688117     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt51425k     Document Type: Article
Times cited : (35)

References (69)
  • 36
    • 79954509047 scopus 로고    scopus 로고
    • The possibility that the irreversible step of the decomposition is the reaction of two palladium(0) complexes should also be considered. However, palladium(0) complex concentrations should be very low at any moment and this process is quite unlikely to play a relevant role in the present system. From a kinetic point of view, a process of this kind would be distinguishable from that in path B only if the concentration/time profile for benzoquinone were also known, which is not the case, and so we will ignore it in the following
    • F. Ragaini H. Larici M. Rimoldi A. Caselli F. Ferretti P. Macchi N. Casati Organometallics 2011 30 2385
    • (2011) Organometallics , vol.30 , pp. 2385
    • Ragaini, F.1    Larici, H.2    Rimoldi, M.3    Caselli, A.4    Ferretti, F.5    Macchi, P.6    Casati, N.7
  • 37
    • 1542542362 scopus 로고    scopus 로고
    • W and molar volume of the methyl-substituted substrate, the molar concentration of the latter was actually a little lower than that of styrene during the reactions. However, the reactivity difference is much larger than that attributable to such a small dilution effect and must have a different origin
    • M. Gasperini F. Ragaini Organometallics 2004 23 995
    • (2004) Organometallics , vol.23 , pp. 995
    • Gasperini, M.1    Ragaini, F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.