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Volumn 30, Issue 8, 2011, Pages 2385-2393

Mapping palladium reduction by carbon monoxide in a catalytically relevant system. a novel palladium(I) dimer

Author keywords

[No Author keywords available]

Indexed keywords

CO ATMOSPHERE; METALLIC PALLADIUM; NITROGEN LIGAND; PALLADIUM COMPLEXES; PHENANTHROLINES; SINGLE CRYSTAL X-RAY DIFFRACTION;

EID: 79954509047     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200118v     Document Type: Article
Times cited : (31)

References (50)
  • 3
    • 79954530449 scopus 로고    scopus 로고
    • We have recently found that complexes 1a, 1c, and 1d exist in two different bond isomeric forms. These results will be described elsewhere, but the identity of the employed isomer is not influential to the present discussion, since both yielded the same products.
    • We have recently found that complexes 1a, 1c, and 1d exist in two different bond isomeric forms. These results will be described elsewhere, but the identity of the employed isomer is not influential to the present discussion, since both yielded the same products.
  • 10
    • 79954565619 scopus 로고    scopus 로고
    • For reviews on palladium carbonyl complexes see refs 8, 9, and 11
    • For reviews on palladium carbonyl complexes see refs 8, 9, and 11.
  • 29
    • 79954528736 scopus 로고    scopus 로고
    • Steric effects have also been generically proposed to affect the reactivity of the monomeric complex in a few cases, but the exact role of the steric hindrance has not been clarified. It is also possible that the presence of the ortho methyl groups inhibits the formation of electronically saturated and catalytically inactive monomeric complexes having two chelating ligands in the coordination sphere. However, to the best of our knowledge, this explanation has never been advanced in the literature for the ligands employed in the present study
    • Steric effects have also been generically proposed to affect the reactivity of the monomeric complex in a few cases, but the exact role of the steric hindrance has not been clarified. It is also possible that the presence of the ortho methyl groups inhibits the formation of electronically saturated and catalytically inactive monomeric complexes having two chelating ligands in the coordination sphere. However, to the best of our knowledge, this explanation has never been advanced in the literature for the ligands employed in the present study.
  • 47
    • 4644305984 scopus 로고    scopus 로고
    • v 2.10; University of Göttingen: Germany.
    • Sheldrick, G. M. SADABS v 2.10; University of Göttingen: Germany, 2003.
    • (2003) SADABS
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.