Synthesis, electronic structure, and magnetism of [Ni(6-Mes) 2]+: A two-coordinate nickel(I) complex stabilized by bulky N-heterocyclic carbenes

Journal of the American Chemical Society

Volumn 135, Issue 37, 2013, Pages 13640-13643

  Poulten, Rebecca C ^a   Page, Michael J ^a   Algarra, Andrés G ^b   Le Roy, Jennifer J ^c   López, Isidoro ^d   Carter, Emma ^e   Llobet, Antoni ^d   Macgregor, Stuart A ^b   Mahon, Mary F ^a   Murphy, Damien M ^e   Murugesu, Muralee ^c   Whittlesey, Michael K ^a  

^a University of Bath   (United Kingdom)

^b HERIOT WATT UNIVERSITY   (United Kingdom)

^c UNIVERSITY OF OTTAWA   (Canada)

^d INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^e CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE COMPLEXES; LINEAR GEOMETRY; METAL-BASED ORBITALS; N-HETEROCYCLIC CARBENES; ORBITAL DEGENERACY; SINGLE-ION; TETRAHYDROPYRIMIDIN-2-YLIDENE;

ELECTRONIC STRUCTURE; ORGANIC COMPOUNDS;

NICKEL;

[NI[1,3 BIS(2,4,6 TRIMETHYLPHENYL) 3,4,5,6 TETRAHYDROPYRIMIDIN 2 YLIDENE]]; CARBENOID; NICKEL COMPLEX; UNCLASSIFIED DRUG;

ALTERNATING CURRENT; ANISOTROPY; ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DIRECT CURRENT; ELECTRON SPIN RESONANCE; MAGNETISM; SOLID STATE; SYNTHESIS; TEMPERATURE;

EID: 84884489874     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja407004y     Document Type: Article

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