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Volumn 17, Issue 17, 2011, Pages 4700-4704

High-spin cyclopentadienyl complexes: A single-molecule magnet based on the aryl-iron(II) cyclopentadienyl type

Author keywords

cyclopentadienyl ligands; high spin complexes; iron; magnetic properties; single molecule magnets; tunneling

Indexed keywords

ARYL GROUP; CYCLOPENTADIENYL COMPLEXES; CYCLOPENTADIENYL LIGANDS; CYCLOPENTADIENYLS; HIGH-SPIN COMPLEXES; IRON COMPLEX; MAGNETIC STUDIES; SINGLE-MOLECULE MAGNET; SINGLE-MOLECULE MAGNETS; TUNNELING;

EID: 79953885757     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003288     Document Type: Article
Times cited : (175)

References (26)
  • 14
    • 79953843036 scopus 로고    scopus 로고
    • note
    • 3 groups have been refined as rigid groups with variable torsion angles (C-H=0.96Å, C-C-H and H-C-H 109.5°). The cyclopentadienyl ring is disordered (0.9/0.1). The temperature factors of carbon atoms of the less abundant orientation have been grouped together and refined isotropically. For hydrogen atoms idealized positions have been refined. Further details of the crystal structure investigation of 2 CCDC-815999 can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
  • 15
    • 53549102105 scopus 로고    scopus 로고
    • One low-spin and one high-spin iron(II) alkylcyclopentadienyl complex as well as a third compound with both iron(II) high- and low-spin centers within the same molecule have been structurally characterized and exhibit 1.69 and 1.68Ålow-spin Fe-ring distances as well as 1.92 and 1.97Åhigh-spin Fe-ring distances and can be found in
    • One low-spin and one high-spin iron(II) alkylcyclopentadienyl complex as well as a third compound with both iron(II) high- and low-spin centers within the same molecule have been structurally characterized and exhibit 1.69 and 1.68Ålow-spin Fe-ring distances as well as 1.92 and 1.97Åhigh-spin Fe-ring distances and can be found in:, M. W. Wallasch, G. Wolmershäuser, H. Sitzmann, Angew. Chem. 2005, 117, 2653
    • (2005) Angew. Chem. , vol.117 , pp. 2653
    • Wallasch, M.W.1    Wolmershäuser, G.2    Sitzmann, H.3
  • 17
    • 0001748514 scopus 로고    scopus 로고
    • 2] may be another example of a high-spin cyclopentadienyl iron(II) complex based on the ring-Fe distance of 1.92Å.
    • 2] may be another example of a high-spin cyclopentadienyl iron(II) complex based on the ring-Fe distance of 1.92Å:, U. Siemeling, U. Vorfeld, B. Neumann, H.-G. Stammler, Organometallics 1998, 17, 483.
    • (1998) Organometallics , vol.17 , pp. 483
    • Siemeling, U.1    Vorfeld, U.2    Neumann, B.3    Stammler, H.-G.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.