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note
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3 groups have been refined as rigid groups with variable torsion angles (C-H=0.96Å, C-C-H and H-C-H 109.5°). The cyclopentadienyl ring is disordered (0.9/0.1). The temperature factors of carbon atoms of the less abundant orientation have been grouped together and refined isotropically. For hydrogen atoms idealized positions have been refined. Further details of the crystal structure investigation of 2 CCDC-815999 can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
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15
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53549102105
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One low-spin and one high-spin iron(II) alkylcyclopentadienyl complex as well as a third compound with both iron(II) high- and low-spin centers within the same molecule have been structurally characterized and exhibit 1.69 and 1.68Ålow-spin Fe-ring distances as well as 1.92 and 1.97Åhigh-spin Fe-ring distances and can be found in
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One low-spin and one high-spin iron(II) alkylcyclopentadienyl complex as well as a third compound with both iron(II) high- and low-spin centers within the same molecule have been structurally characterized and exhibit 1.69 and 1.68Ålow-spin Fe-ring distances as well as 1.92 and 1.97Åhigh-spin Fe-ring distances and can be found in:, M. W. Wallasch, G. Wolmershäuser, H. Sitzmann, Angew. Chem. 2005, 117, 2653
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0001748514
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2] may be another example of a high-spin cyclopentadienyl iron(II) complex based on the ring-Fe distance of 1.92Å.
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