Importance of out-of-state spin-orbit coupling for slow magnetic relaxation in mononuclear FeII complexes

Journal of the American Chemical Society

Volumn 133, Issue 40, 2011, Pages 15806-15809

  Lin, Po Heng ^a,b   Smythe, Nathan C ^c   Gorelsky, Serge I ^a,b   Maguire, Steven ^a,b   Henson, Neil J ^d   Korobkov, Ilia ^a   Scott, Brian L ^e   Gordon, John C ^c   Baker, R Tom ^a,b   Murugesu, Muralee ^a,b  

^a UNIVERSITY OF OTTAWA   (Canada)

^b UNIVERSITY OF OTTAWA   (Canada)

^c Chemistry Division   (United States)

^d Theoretical Division   (United States)

^e LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEX 1; CYCLOHEXYL; DC FIELD; ELECTRONIC EXCITED STATE; ELECTRONIC GROUND STATE; GROUND ELECTRONIC STATE; LIGAND FIELD; ORBITAL ANGULAR MOMENTUM; SINGLE-MOLECULE MAGNET; SLOW RELAXATIONS; SPIN-ORBIT COUPLINGS; TETRAHEDRAL GEOMETRY; ZERO-FIELD SPLITTINGS;

ELECTRIC EXCITATION; ETHANE; FUNCTIONAL ELECTRIC STIMULATION; MAGNETIC PROPERTIES; MAGNETIC RELAXATION; MAGNETIZATION;

EXCITED STATES;

IRON COMPLEX;

ANISOTROPY; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON; ENERGY; GEOMETRY; IMAGE ANALYSIS; MAGNET; NUCLEAR MAGNETIC RESONANCE IMAGING; RADIOLOGICAL PARAMETERS; SLOW MAGNETIC RELAXATION; SPIN ORBIT COUPLING; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 80053476531     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja203845x     Document Type: Article

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