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See supplementary material at http://dx.doi.org/10.1063/1.4819836 E-APPLAB-103-005336 for (a) Fig. S1 a setup employed for the fabrication of MOF thin films with the LPE spray method; for (b) Figs. S8a and S9 on SURMOF thin film morphology data; for (c) Figs. S6 and S7a-c on XRD data (out of plane) of HKSUT-1 and Cu-BDC SURMOF-2 thin films; for (d) Fig. S2 on the experimental heating equipment; for (e) Fig. S5 on IRRAS data of HKUST-1 and Cu-BDC SURMOFs; for (f) Figs. S4ab and Figs. S4c-e on Spectroscopy Ellipsometry (SE) measurements and for (g) Fig. S10 on the used organic linker lengths in the isoreticular series of MOF-2 (e.g., from 1.1 nm to 2.8 nm).
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