Asymmetric Synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes

Synthesis (Germany)

Volumn 45, Issue 15, 2013, Pages 2079-2087

  Darses, Benjamin ^a   Jarvis, Amandag ^a   Mafroud, Abdel Kader ^a,b   Estenne Bouhtou, Geneviève ^b   Dargazanli, Gihad ^b   Dauban, Philippe ^a  

^a INSTITUT DE CHIMIE DES SUBSTANCES NATURELLES   (France)

^b SANOFI   (France)

Author keywords

amines; asymmetric catalysis; C H amination; nitrene; rhodium

Indexed keywords

ADAMANTANE DERIVATIVES; ALLYLIC SUBSTRATES; ASYMMETRIC CATALYSIS; ASYMMETRIC SYNTHESIS; C-H AMINATION; EXPERIMENTAL PROTOCOLS; NITRENE PRECURSORS; NITRENES;

AMINATION; AMINES; CATALYSIS; RHODIUM;

RHODIUM COMPOUNDS;

2 (1,3 DIOXO 1H BENZO[DE]ISOQUINOLIN 2(3H) YL)PROPANOIC ACID; 3,7 DIMETHYL 5 [[S (4 TOLYL) N TOSYLSULFONIMIDOYL]AMINO]OCTA 2,6 DIEN 1 YL TRICHLOROACETATE; [3 [[S (4 TOLYL) N (TOSYL)SULFONIMIDOYL]AMINO]1 ADAMANTYL]ACETIC ACID; ADAMANTANE; ALANINE DERIVATIVE; AMINE; CARBON; DIRHODIUM TETRAKIS 2 (1,3 DIOXO 1H BENZO[DE]ISOQUINOLIN 2(3H) YL)PROPANOIC ACID; HYDROGEN; N (2,3 DIHYDRO 1H INDEN 1 YL)ACETAMIDE; N (2,3 DIHYDRO 1H INDEN 1 YLAMINO)(4 TOLYL)OXIDO SULFANYLIDENETOSYLAMIDE; N [(2 AZIDO 2,3 DIHYDRO 1H INDEN 1 YLAMINO)(4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [(2 BROMO 2,3 DIHYDRO 1H INDEN 1 YLAMINO)(4 TOLYL)OXIDO SULFANYLIDENE]TOSYLAMIDE; N [(2 METHOXY 2,3 DIHYDRO 1H INDEN 1 YLAMINO)(4 TOLYL)OXIDO SULFANYLIDENE]TOSYLAMIDE; N [(4 TOLYL)(OXIDO)(5'H SPIRO[1,3 DIOXOLANE 2,2' TRICYTRICYCLO[3.3.1.13,7]DECAN] 5'YLAMINO)SULFANYLIDENE]TOSYLAMIDE; N [(4 TOLYL)(OXIDO)[(4,6,6 TRIMETHYLBICYCLO[3.1.1]HEPT 3 EN 2 YL)AMINO]SULFANYLIDENE]TOSYLAMIDE; N [(4 TOLYL)OXIDO SULFANYLIDENE]TOSYLAMIDE; N [[(1 ACETYL 1,2,3,4 TETRAHYDROQUINOLIN 4 YL)AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[(1,3 DIMETHYLBUT 2 EN 1 YL)AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[(3 BROMO 1 ADAMANTYL)AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[(3 METHYLCYCLOHEX 2 EN 1 YL)AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[(3,5 DIMETHYL 1 ADAMANTYL)AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[[1 (4 METHOXYPHENYL) 2 [4 (TRIFLUOROMETHYL)PHENYL]ETHYL]AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N [[[1 (4 METHOXYPHENYL) 2 PHENYLETHYL]AMINO](4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; N[(10,11DIHYDRO 5H DIBENZO[A,D][7]ANNULEN 10 YLAMINO)(4 TOLYL)OXIDOSULFANYLIDENE]TOSYLAMIDE; RHODIUM; TERT BUTYL 2,3 DIHYDRO 1H INDEN 1 YL[S (4 TOLYL) N (TOSYL)SULFONIMIDOYL]CARBAMATE; TERT BUTYL 2,3 DIHYDRO 1H INDEN 1 YLCARBAMATE; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; RACEMIZATION;

EID: 84880924267     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0033-1339280     Document Type: Article

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