Chirality transfer in Brook rearrangement-mediated SE2′ solvolytic protonation and its use in estimation of the propensity for racemization of the α-lithiocarbanions of the substituents

Tetrahedron

Volumn 69, Issue 29, 2013, Pages 5823-5828

  Sasaki, Michiko ^a   Fujiwara, Misato ^a   Kotomori, Yuri ^a   Kawahata, Masatoshi ^b   Yamaguchi, Kentaro ^b   Takeda, Kei ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

^b TOKUSHIMA BUNRI UNIVERSITY   (Japan)

Author keywords

Carbanion; Chirality transfer; Electrophilic substitution; Rearrangement

Indexed keywords

ALCOHOL DERIVATIVE; ALPHA LITHIOCARBANION DERIVATIVE; ELECTROPHILE; LITHIUM DERIVATIVE; SILICATE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; BROOK REARRANGEMENT; CARBAMOYLATION; CHEMICAL REACTION; CHIRALITY; CONJUGATION; ENANTIOSELECTIVITY; HYPOTHESIS; LITHIATION; PRIORITY JOURNAL; PROTON TRANSPORT; QUANTITATIVE ANALYSIS; RACEMIZATION; SOLVENT EFFECT; SOLVOLYSIS; WITTIG REACTION;

EID: 84878839716     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2013.05.043     Document Type: Article

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