Stereoselective Se2′ protonation of α- hydroxyallylsilanes mediated by a brook rearrangement

Chemistry - A European Journal

Volumn 15, Issue 14, 2009, Pages 3363-3366

  Sasaki, Michiko ^a   Shirakawa, Yuri ^a   Kawahata, Masatoshi ^b   Yamaguchi, Kentaro ^b   Takeda, Kei ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

^b TOKUSHIMA BUNRI UNIVERSITY   (Japan)

Author keywords

Asymmetric synthesis; Carbanions; Chixality; Enantioselectivity; Silicates

Indexed keywords

ALKOXIDE; ALLYLSILANES; ASYMMETRIC SYNTHESIS; BROOK REARRANGEMENTS; CARBANIONS; CHIXALITY; GAIN INFORMATIONS; INVERSION BARRIERS; RE ARRANGEMENTS; STEREO-SELECTIVE; STEREOCHEMICAL PATHWAYS;

CYANIDES; ELECTRON TRANSITIONS; ENANTIOSELECTIVITY; OXYGEN; PROTONATION; QUENCHING; SILANES; SILICATES;

IONS;

3 (TERT BUTYLDIMETHYLSILYL) 1 CYANO 3 HYDROXYPROP 1 ENYL CARBAMATE; 3 (TERT BUTYLDIMETHYLSILYLOXY) 1 CYANOALLYL DIISOPROPYLCARBAMATE; 3-(TERT-BUTYLDIMETHYLSILYL)-1-CYANO-3-HYDROXYPROP-1-ENYL CARBAMATE; 3-(TERT-BUTYLDIMETHYLSILYLOXY)-1-CYANOALLYL DIISOPROPYLCARBAMATE; CARBAMIC ACID DERIVATIVE; ORGANOSILICON DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

CARBAMATES; CATALYSIS; ORGANOSILICON COMPOUNDS; SILANES; STEREOISOMERISM;

EID: 63749085376     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200802499     Document Type: Article

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