A novel organic-inorganic hybrid sandwich-type germanotungstate with discrete [Fe4(en)2(α-GeW9O 34)2]8 - Polyoxoanions and 1-D [Fe 4(en)(α-GeW9O34)2] n8n - Polymeric chains

Inorganic Chemistry Communications

Volumn 33, Issue , 2013, Pages 99-104

  Tian, Shuanbao ^a,b   Li, Yanzhou ^a   Zhao, Junwei ^a   Ma, Pengtao ^a   Chen, Lijuan ^a  

^a HENAN UNIVERSITY   (China)

^b XINXIANG MEDICAL UNIVERSITY   (China)

Author keywords

1 D sandwich type germanotungstate; Germanotungstate; Polyoxometalate

Indexed keywords

EID: 84877636190     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2013.04.004     Document Type: Article

References (40)

1. P. Yin, P. Wu, Z. Xiao, D. Li, E. Bitterlich, J. Zhang, P. Cheng, D.V. Vezenov, T. Liu, and Y. Wei A double-tailed fluorescent surfactant with a hexavanadate cluster as the head group Angew. Chem. Int. Ed. 50 2011 2521 2525
2. J.D. Compain, P. Mialane, A. Dolbecq, I.M. Mbomekallé, J. Marrot, F. Sécheresse, E. Rivière, G. Rogez, and W. Wernsdorfer Iron polyoxometalate single-molecule magnets Angew. Chem. Int. Ed. 48 2009 3077 3081
3. S.G. Mitchell, C. Streb, H.N. Miras, T. Boyd, D.L. Long, and L. Cronin Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture Nat. Chem. 2 2010 308 312
4. C.Y. Duan, M.L. Wei, D. Guo, C. He, and Q.J. Meng Crystal structures and properties of large protonated water clusters encapsulated by metal-organic frameworks J. Am. Chem. Soc. 132 2010 3321 3330
5. L.J. Chen, D.Y. Shi, J.W. Zhao, Y.L. Wang, P.T. Ma, J.P. Wang, and J.Y. Niu Three transition-metal substituted polyoxotungstates containing Keggin fragments: from trimer to one-dimensional chain to two-dimensional sheet Cryst. Growth Des. 11 2011 1913 1923
6. E. Coronado, C. Giménez-Saiz, and C.J. Gómez-García Recent advances in polyoxometalate-containing molecular conductors Coord. Chem. Rev. 249 2005 1776 1796
7. J.W. Zhao, D.Y. Shi, L.J. Chen, Y.Z. Li, P.T. Ma, J.P. Wang, and J.Y. Niu Novel polyoxometalate hybrids consisting of copper-lanthanide heterometallic/lanthanide germanotungstate fragments Dalton Trans. 41 2012 10740 10751
8. G. Hervé, and A. Tézé Study of α-and β-enneatungstosilicates and germinates Inorg. Chem. 16 1977 2115 2117
9. 12 - Inorg. Chem. 46 2007 8763 8770
10. Z. Zhang, Y. Qi, C. Qin, Y. Li, E. Wang, X. Wang, Z. Su, and L. Xu Two multi-copper containing heteropolyoxotungstates constructed from the lacunary Keggin polyoxoanion and the high-nuclear spin cluster Inorg. Chem. 46 2007 8162 8169
11. II-organic cation bridges Cryst. Growth Des. 7 2007 2658 2664
12. X. Gan, Z. Zhang, S. Yao, W. Chen, E. Wang, and H. Zhang Two new one-dimensional chain-like compounds constructed from the sandwich-type polyoxotungstate clusters J. Clust. Sci. 19 2008 401 410
13. J.W. Zhao, C.M. Wang, J. Zhang, S.T. Zheng, and G.Y. Yang Combination of lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: IX. A series of novel polyoxotungstates sandwiched by octa-copper clusters Chem. Eur. J. 14 2008 9223 9239
14. 56 -: a polyoxometalate containing 20 cerium(III) atoms Angew. Chem. Int. Ed. 46 2007 6192 6195
15. S. Reinoso, J.R. Galán-Mascarós, and L. Lezama New type of heterometallic 3d-4f rhomblike core in Weakley-like polyoxometalates Inorg. Chem. 50 2011 9587 9593
16. S. Reinoso, and J.R. Galán-Mascarós Heterometallic 3d-4f polyoxometalate derived from the Weakley-type dimeric structure Inorg. Chem. 49 2010 377 379
17. III- stabilized dilacunary Keggin fragments Angew. Chem. Int. Ed. 49 2010 8384 8388
18. 2O Inorg. Chem. Commun. 14 2011 1052 1056
19. II substituted sandwich-type arsenotungstate units CrystEngComm 14 2012 2797 2806
20. I.D. Brown, and D. Altermatt Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database Acta Crystallogr. B41 1985 244 247
21. 2S oxidation J. Mol. Catal. A Chem. 158 2000 251 255
22. C. Pichon, A. Dolbecq, P. Mialane, J. Marrot, E. Rivièreb, and F. Sécheresse Square versus tetrahedral iron clusters with polyoxometalate ligands Dalton Trans. 2008 71 76
23. 4 clusters encapsulated in vacant polyoxotungstates: hydrothermal synthesis, magnetic and electrochemical properties and DFT calculations Chem. Eur. J. 14 2008 3189 3199
24. 9 - fragments in the opposite orientation Inorg. Chem. Commun. 14 2011 1178 1182
25. 2O Inorg. Chem. Commun. 17 2012 79 83
26. 16 - (M = cobalt, copper, zinc) Inorg. Chem. 26 1987 3886 3896
27. 2O Inorg. Chem. 29 1990 1235 1241
28. 2O Inorg. Chem. 32 1993 3378 3381
29. J.W. Zhao, S.T. Zheng, and G.Y. Yang Hydrothermal synthesis and structural characterization of three inorganic-organic composite sandwich-type phosphotungstates J. Solid State Chem. 180 2007 3317 3324
30. 2O Chin. J. Struct. Chem. 29 2010 599 607
31. L.J. Chen, Y.H. Fan, J.W. Zhao, P.T. Ma, D.Y. Shi, J.P. Wang, and J.Y. Niu Hydrothermal syntheses and structural characterization of two sandwich-type arsenotungstates J. Coord. Chem. 63 2010 2042 2055
32. T.J.R. Weakley, H.T. Evans, J.S. Showell, G.F. Tourné, and C.M. Tourné 18-Tungstotetracobalto(II) diphosphate and related anions: a novel structural class of heteropolyanions J. Chem. Soc. Chem. Commun. 1973 139 140
33. 2+) Inorg. Chem. 39 2000 2915 2922
34. J.W. Zhao, D.Y. Shi, L.J. Chen, P.T. Ma, J.P. Wang, and J.Y. Niu Two 1-D multi-nickel substituted arsenotungstate aggregates CrystEngComm 13 2011 3462 3469
35. S.T. Zheng, J. Zhang, J.M. Clemente-Juan, D.Q. Yuan, and G.Y. Yang Poly(polyoxotungstate)s with 20 nickel centers: from nanoclusters to one-dimensional chains Angew. Chem. Int. Ed. 48 2009 7176 7179
36. II cluster with planar triangular topology exhibiting ferromagnetic pathways Chem. Commun. 2002 1478 1479
37. A. Dolbecq, J.D. Compain, P. Mialane, J. Marrot, E. Rivière, and F. Sécheresse Water substitution on iron centers: from 0D to 1D sandwich type polyoxotungstates Inorg. Chem. 47 2008 3371 3378
38. 22 - Inorg. Chem. 46 2007 10944 10946
39. J.W. Zhao, H.P. Jia, J. Zhang, S.T. Zheng, and G.Y. Yang A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. Part II: from double cluster, dimer, and tetramer to three-dimensional frameworks Chem. Eur. J. 13 2007 10030 10045
40. 11 - Inorg. Chem. 44 2005 896 903