An organic-inorganic hybrid dimeric arsenotungstate [enH2] 4{[Cu(en)2][(A-β-H2AsW9O 34)Cu(en)2]2}·8H2O established by t\wo trivacant Keggin [A-β-AsW9O 34]9- fragments in the opposite orientation

Inorganic Chemistry Communications

Volumn 14, Issue 7, 2011, Pages 1178-1182

  Liu, Yun ^a   Shi, Dongying ^a   Zhao, Junwei ^a   Chen, Lijuan ^a   Wang, Zhiqiao ^a   Ma, Pengtao ^a   Niu, Jingyang ^a  

^a HENAN UNIVERSITY   (China)

Author keywords

Arsenotungstate; Copper; Polyoxometalate; Trivacant Keggin structure

Indexed keywords

EID: 79957733040     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.04.021     Document Type: Article

References (50)

1. E. Coronado, C. Giménez-Saiz, C.J. Gómez-García, Recent advances in polyoxometalate-containing molecular conductors, Coord. Chem. Rev. 249 (2005) 1776-1796. (Pubitemid 41116323)
2. 26-, Angew. Chem. Int. Ed. 40 (2001) 3384-3386.
3. J.D. Compain, P. Mialane, A. Dolbecq, I.M. Mbomekallé, J. Marrot, F. Sécheresse, E. Rivière, G. Rogez, W. Wernsdorfer, Iron polyoxometalate single-molecule magnets, Angew. Chem. Int. Ed. 48 (2009) 3077-3081.
4. 14- building blocks, Chem. Commun. (2008) 1650-1652.
5. C.Y. Duan, M.L. Wei, D. Guo, C. He, Q.J. Meng, Crystal structures and properties of large protonated water clusters encapsulated by metal-organic frameworks, J. Am. Chem. Soc. 132 (2010) 3321-3330.
6. D.-J. Guo, S.-J. Fu, W. Tan, Z.-D. Dai, A highly porous nafion membrane templated from polyoxometalates -based supramolecule composite for ion-exchange polymer-metal composite actuator, J. Mater. Chem. 20 (2010) 10159-10168.
7. 76-, Angew. Chem. Int. Ed. Engl. 36 (1997) 1445-1448.
8. 2+), Inorg. Chem. 40 (2001) 4742-4749.
9. 8-, Inorg. Chem. 43 (2004) 144-154.
10. III) and its solution properties, Eur. J. Inorg. Chem. (2004) 2733-2738.
11. 3d-symmetric polyoxotungstates, Inorg. Chem. 45 (2006) 7698-7704.
12. W. Chen, Y. Li, Y. Wang, E. Wang, Z. Su, Building block approach to nanostructures: step-by-step assembly of large lanthanide-containing polytungstoarsenate aggregates, Dalton Trans. (2007) 4293-4301. (Pubitemid 47480510)
13. 60-, Angew. Chem. Int. Ed. 48 (2009) 9088-9091.
14. 10- heteropolyanions (M=Co or Zn, X=P or As), J. Chem. Soc. Dalton Trans. (1986) 2699-2705.
15. L.H. Bi, E.B. Wang, J. Peng, R.D. Huang, L. Xu, C.W. Hu, Crystal structure and replacement reaction of coordinated water molecules of the heteropoly compounds of sandwich-type tungstoarsenates, Inorg. Chem. 39 (2000) 671-679.
16. 10- (M=Cd, Co, Cu, Fe, Mn, Ni or Zn), J. Chem. Soc. Dalton Trans. (2001) 121-129.
17. 17-, Inorg. Chem. 42 (2003) 5143-5152.
18. 2+), Bull. Chem. Soc. Jpn. 80 (2007) 178-182.
19. 12-, J. Mol. Struct. 688 (2004) 33-39.
20. 36-,Angew. Chem. Int. Ed. 44 (2005) 3773-3777.
21. R. Khoshnavazi, H. Eshtiagh-hosseini, M.H. Alizadeh, M.T. Pope, Syntheses and structural determination of new bis(9-tungstoarsenato)tris(dioxouranate(VI) ) and its monooxovanadate(IV) derivative complexes, Inorg. Chim. Acta 360 (2007) 686-690.
22. 2O, J. Mol. Struct. 873 (2008) 29-34.
23. 11- (M=Y(III), Yb(III) and Sm(III)), Polyhedron 27 (2008) 1303-1309.
24. 12-, J. Coord. Chem. 62 (2009) 2067-2075.
25. II), Inorg. Chim. Acta 362 (2009) 1223-1228.
26. P.T. Ma, J.W. Zhao, J.P. Wang, Y. Shen, J.Y. Niu, Sandwich-type polyoxotungstate hybrids decorated by nickel-aromatic amine complexes, J. Solid State Chem. 183 (2010) 150-156.
27. J.W. Zhao, Q.X. Han, P.T. Ma, L.J. Chen, J.P. Wang, J.Y. Niu, A CdSO4-like 3-D framework constructed from monosodium substituted Keggin arsenotungstates and copper(II)-ethylenediamine complexes, Inorg. Chem. Commun. 12 (2009) 707-710.
28. L.J. Chen, J.W. Zhao, P.T. Ma, Q.X. Han, J.P. Wang, J.Y. Niu, An organic-inorganic hybrid nickel-substituted arsenotungstate consisting of three types of polyoxotungstate units, Inorg. Chem. Commun. 13 (2010) 50-53.
29. L.J. Chen, Y.H. Fan, J.W. Zhao, P.T. Ma, D.Y. Shi, J.P. Wang, J.Y. Niu, Hydrothermal syntheses and structural characterization of two sandwich-type arsenotungstates, J. Coord. Chem. 63 (2010) 2042-2055.
30. J.W. Zhao, D.Y. Shi, L.J. Chen, P.T. Ma, J.P. Wang, J.Y. Niu, Two 1-D multi-nickel substituted arsenotungstate aggregates, CrystEngComm. 13 (2011) 3462-3469.
31. 18: C, 4.37; H, 1.98; N, 5.10; Cu, 3.47; As, 2.73; W, 60.22 (%); found: C, 4.48; H, 2.10; N, 5.04; Cu, 3.42; As, 2.77; W, 60.10 (%).
32. Z.M. Zhang, Y.G. Li, S. Yao, E.B. Wang, Y.H. Wang, R. Clérac, Enantiomerically pure chiral Fe28 wheels, Angew. Chem. Int. Ed. 48 (2009) 1581-1584.
33. 2bpdc=2,2′-bipyridyl-5,5′-dicarboxylic acid), Inorg. Chem. Commun. 13 (2010) 822-827.
34. 2 using the SHELXTL-97 program package. Intensity data were corrected for Lorentz and polarization effects as well as for multi-scan absorption. All of the non-hydrogen atoms were refined anisotropically. Positions of the hydrogen atoms attached to the carbon and nitrogen atoms were geometrically placed. All hydrogen atoms were refined isotropically as a riding mode using the default SHELXTL parameters.
35. B. Li, J.W. Zhao, S.T. Zheng, G.Y. Yang, Combination chemistry of hexa-coppersubstituted polyoxometalates driven by the Cu(II)-polyhedra distortion: from tetramer, 1D chain to 3D framework, Inorg. Chem. 48 (2009) 8294-8303.
36. II- organoamine complexes, J. Solid State Chem. 181 (2008) 2205-2216.
37. C. Pichon, A. Dolbecq, P. Mialane, J. Marrot, E. Rivièreb, F. Sécheresse, Square versus tetrahedral iron clusters with polyoxometalate ligands, Dalton Trans. (2008) 71-76. (Pubitemid 350264908)
38. C. Pichon, A. Dolbecq, P. Mialane, J. Marrot, E. Rivière, M. Goral, M. Zynek, T. McCormac, S.A. Borshch, E. Zueva, F. Sécheresse, Chem. Eur. J. 14 (2008) 3189-3199.
39. 2O, a microporous solid from Dawson anions and 1,6-diaminohexane, Angew. Chem. Int. Ed. Engl. 33 (1995) 2491-2493.
40. I.D. Brown, D. Altermatt, Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database, Acta Cryst. B41 (1985) 244-247.
41. J.W. Zhao, C.M. Wang, J. Zhang, S.T. Zheng, G.Y. Yang, Combination of lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: IX. a series of novel polyoxotungstates sandwiched by octa-copper clusters, Chem. Eur. J. 14 (2008) 9223-9239.
42. J.W. Zhao, H.P. Jia, J. Zhang, S.T. Zheng, G.Y. Yang, A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. Part II: from double cluster, dimer, and tetramer to three-dimensional frameworks, Chem. Eur. J. 13 (2007) 10030-10045.
43. 6-, a monocapped, trivacant Keggin species, J. Mol. Struct. 508 (1999) 217-221.
44. C.M. Wang, S.T. Zheng, G.Y. Yang, Novel copper-complex-substituted tungstogermanates, Inorg. Chem. 46 (2007) 616-618.
45. 2O, Inorg. Chem. Commun. 10 (2007) 1054-1057.
46. 2+ groups, Dalton Trans. (2005) 3913-3920.
47. R.R. Ozer, J.L. Ferry, Kinetic probes of the mechanism of polyoxometalate-mediated photocatalytic oxidation of chlorinated organics, J. Phys. Chem. B 104 (2000) 9444-9448.
48. I.A. Weinstock, Homogeneous-phase electron-transfer reactions of polyoxometalates, Chem. Rev. 98 (1998) 113-170.
49. Q. Wu, W.L. Chen, D. Liu, C. Liang, Y.G. Li, S.W. Lin, E.B. Wang, New class of organic-inorganic hybrid aggregates based on polyoxometalates and metal-Schiff-base, Dalton Trans. (2011) 56-61.
50. 2 dispersions under visible-light irradiation: mechanistic implications, Chem. Eur. J. 10 (2004) 1956-1965.