Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture

Nature Chemistry

Volumn 2, Issue 4, 2010, Pages 308-312

  Mitchell, Scott G ^a   Streb, Carsten ^a   Miras, Haralampos N ^a   Boyd, Thomas ^a   Long, De Liang ^a   Cronin, Leroy ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77950207643     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.581     Document Type: Article

References (34)

1. Takeda, N., Umemoto, K., Tamaguchi, K. & Fujita, M. A nanometre-sized hexahedral coordination capsule assembled from 24 components. Nature 398, 794-796 (1999).
2. Pluth, M. D., Bergman, R. G. & Raymond, K. N. Acid catalysis in basic solution: a supramolecular host promotes orthoformate hydrolysis. Science 316, 85-88 (2007).
3. Ziv, A. et al. Flexible pores of a metal oxide-based capsule permit entry of comparatively larger organic guests. J. Am. Chem. Soc. 131, 6380-6382 (2009).
4. Mal, P., Breiner, B., Rissanen, K. & Nitschke, J. R. White phosphorus is air-stable within a self-assembled tetrahedral capsule. Science 324, 1697-1699 (2009).
5. Dinolfo, P. H. & Hupp, J. T. Supramolecular coordination chemistry and functional microporous molecular materials. Chem. Mater. 13, 3113-3125 (2001).
6. Sato, S. et al. Fluorous nanodroplets structurally confined in an organopalladium sphere. Science 313, 1273-1276 (2006).
7. Yaghi, O. M. et al. Reticular synthesis and the design of new materials. Nature 423, 705-714 (2003).
8. Olenyuk, B., Whiteford, J. A., Fechtenkötter, A. & Stang, P. J. Self-assembly of nanoscale cuboctahedra by coordination chemistry. Nature 398, 796-799 (1999).
9. Li, Q. et al. Docking in metal-organic frameworks. Science 325, 855-859 (2009).
10. Rowsell, J. & Yaghi, O. M. Metal-organic frameworks: a new class of porous materials. Microporous Mesoporous Mater. 73, 3-14 (2004).
11. Perry, J. J., Perman, P. A. & Zaworotko, M. J. Design and synthesis of metal- organic frameworks using metal-organic polyhedra as supermolecular building blocks. Chem. Soc. Rev. 38, 1400-1417 (2009).
12. Kitagawa, S., Kitaura, R. & Noro, S.-I. Functional porous coordination polymers. Angew. Chem. Int. Ed. 43, 2334-2375 (2004).
13. Tao, Y., Kanoh, H., Abrams, L. & Kaneko, K. Mesopore-modified zeolites: preparation, characterization and applications. Chem. Rev. 106, 896-910 (2006).
14. Long, D.-L., Burkholder, E. & Cronin, L. Polyoxometalate clusters, nanostructures and materials: from self assembly to designer materials and devices. Chem. Soc. Rev. 36, 105-121 (2007).
15. Müller, A. et al. Artificial cells: temperature-dependent, reversible Li+-ion uptake/release equilibrium at metal oxide nanocontainer pores. Angew. Chem. Int. Ed. 43, 4466-4470 (2004).
16. Geletii, Y. V. et al. An all-inorganic, stable and highly active tetraruthenium homogeneous catalyst for water oxidation. Angew. Chem. Int. Ed. 47, 3896-3899 (2008).
17. Dolbecq, A. et al. Hybrid 2D and 3D frameworks based on 1-Keggin polyoxometalates: experimental and simulation. Eur. J. Inorg. Chem. 3009-3018 (2005).
18. Rodriguez-Albelo, L. M. et al. Zeolitic polyoxometalate-based metal-organic frameworks (Z-POMOFs): computational evaluation of hypothetical polymorphs and the successful targeted synthesis of the redox-active Z-POMOF1. J. Am. Chem. Soc. 131, 16078-16087 (2009).
19. Müller, A., Shah, S. Q. N., Bögge, H. & Schmidtmann, M. Molecular growth from a Mo176 to a Mo248 cluster. Nature 397, 47-50 (1999).
20. Schemberg, J. et al. Towards biological supramolecular chemistry: a variety of pocket-templated, individual metal oxide cluster nucleations in the cavity of a Mo/W-storage protein. Angew. Chem. Int. Ed. 46, 2408-2413 (2007).
21. AlDamen, M. A. et al. Mononuclear lanthanide single-molecule magnets based on polyoxometalates. J. Am. Chem. Soc. 130, 8874-8875 (2008).
22. Pope, M. T. & Müller, A. Polyoxometalate Chemistry: From Topology via Self- Assembly to Applications (Kluwer, 2001).
23. 29-. Chem. Commun. 4254-4256 (2007).
24. Ritchie, C. et al. Reversible redox reactions in an extended polyoxometalate framework solid. Angew. Chem. Int. Ed. 47, 6881-6884 (2008).
25. 2O. Angew. Chem. Int. Ed. 42, 2814-2817 (2002).
26. Van Bekkum, H., Flanigen, E. M., Jacobs, P. A. & Jansen, J. C. (eds) Introduction to Zeolite Science and Practice (Elsevier, 2001).
27. van Bekkum, H. & Cejka, J. Zeolites and ordered mesoporous materials: progress and prospects, in Studies in Surface Science Vol. 157 (Elsevier, 2005).
28. 2O: synthesis, structure and properties. Inorg. Chem. 24, 4610-4614 (1985).
29. Müller, A. et al. Metal-oxide-based nucleation process under confined conditions: two mixed-valence V6-type aggregates closing the W48 wheel-type cluster cavities. Angew Chem. Int. Ed. 46, 4477-4480 (2007).
30. 25- ion. Angew. Chem. Int. Ed. 44, 3777-3870 (2005).
31. Sheldrick, G. M. Phase annealing in SHELX-90: direct methods for larger structures. Acta Crystallogr. A 46, 467-473 (1990).
32. Sheldrick, G. M. A short history of SHELX. Acta Cryst. A 64, 112-122 (2008).
33. Farrugia, L. J. WinGX suite for small-molecule single-crystal crystallography. J. Appl. Cryst. 32, 837-838 (1999).
34. Clark, R. C. & Reid, J. S. The analytical calculation of absorption in multifaceted crystals. Acta Cryst. A 51, 887-897 (1995)